• Title/Summary/Keyword: Electronic and thermal properties

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Son Conduction Properties of PVDF/PAN based for Lithium Polymer Battery (리튬 폴리머전지용 PVDF/PAN계 전해질의 이온 전도 특성)

  • 이재안;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1999.11a
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    • pp.374-377
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    • 1999
  • The purpose of this study is to research and develop solid polymer electrolyte(SPE) for Li polymer battery. This paper describes temperature dependence of conductivity, impedance spectroscopy, electrochemical properties of PVDF/PAN electrolytes as a function of a mixed ratio. PVDF/PAN based polymer electrolyte films were prepared by thermal gellification method of preweighed PVDF/PAN, plasticizer and Li salt. The conductivity of PVDF/PAN electrolytes was 10-3S/cm. 20PVDF5PANLiCIO$_4$PC$\sub$10//EC$\sub$10/ electrolyte shows the better conductivity of the others. 20P7DF5PANLiCI$_4$PC$\sub$10//EC$\sub$10/ electrolyte remains stable up to 5V vs. Li/Li$\^$+/. Steady state current method and ac impedance used for the determination of transference numbers in PVDF/PAN electrolyte film. The transference number of 20PVDF5ANLICIO$_4$/PC $\sub$10//EC$\sub$10/ electrolyte is 0.48

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Effect of Electrical Properties on the EPDM- $Al(OH)_3$ Composite by UV Accelerated weathering (Al(OH)3가 EPDM의 자외선 촉진열화에 미치는 전기적 특성평가)

  • Shim, Dae-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.11a
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    • pp.243-247
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    • 2003
  • The effect of accelerated weathering(UV) on three type of ethylene propylene diene monomer(EPDM) composite used for higher voltage insulator were investigated by weather-emoter. For weatherability of EPDM composite, surface resistance, dielectric breakdown strength, change of contact angle, surface composition were measured according to UV accelerated weathering time. From the resort of the measurement of surface resistivity, contact angle of EPDM composite decreased and showed chalking and cracking phenomenon when UV weathweing time was for 1500 h and 2000 h. The analysis of surface atomic composition indicated that surface aluminiu(Al) content was detected due to chalking phenomenon after 1500 h of UV weathering, Oxygen content of all composite increased due to the oxidation.

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Design and Fabrication of a Thermoelectric Generator Based on BiTe Legs to power Wearable Device

  • Moon, S.E.;Kim, J.;Lee, S.M.;Lee, J.;Im, J.P.;Kim, J.H.;Im, S.Y.;Jeon, E.B.;Kwon, B.;Kim, H.;Kim, J.S.
    • Journal of the Korean Physical Society
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    • v.73 no.11
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    • pp.1760-1763
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    • 2018
  • To attain power generation with body heat, the thermal resistance matched design of the thermoelectric generator was the principal factor which was not critical in the case of thermoelectric generator for the waste heat generation. The dimension of thermoelectric legs and the number of thermoelectric leg-pairs dependent output power performances of the thermoelectric generator on the human wrist condition was simulated using 1-dimensional approximated heat flow equations with the temperature dependent material coefficients of the constituent materials and the dimension of the substrate. With the optimum thermoelectric generator design, thermoelectric generator modules were fabricated by using newly developed fabrication processes, which is mass production possible. The electrical properties and the output power characteristics of the fabricated thermoelectric modules were characterized by using a home-made test set-up. The output voltage of the designed thermoelectric generator were a few tens of millivolts and its output power was several hundreds of microwatts under the conditions at the human wrist. The measured output voltage and power of the fabricated thermoelectric generator were slightly lower than those of the designed thermoelectric generator due to several reasons.

Electrochemical Performance of Tricredyl Phosphate and Trispentafluorophenly Phosphine as Flame Retardant Additives for Lithium-ion Batteries (리튬이온전지용 난연성 첨가제(TCP, TFPP)의 전기화학적 특성)

  • Ahn, Se-Young;Kim, Ke-Tack;Kim, Hyun-Soo;Nam, Sang-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.9
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    • pp.756-760
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    • 2007
  • Flame retardant(FR) properties were investigated with tricredyl phosphate(TCP) and tris(pentafluorophenyl)phosphine(TFPP) as additives for lithium-ion batteries. Thermal stability was improved with additives in $Li/LiNi\frac{1}{3}Mn\frac{1}{3}Co\frac{1}{3}O_2$ cells comparing to non-additive electrolytes. Oxygen evolution reaction of the cathode material was delayed to up $55^{\circ}C$, from $275^{\circ}C\;to\;330^{\circ}C$. Electrolytes with the 1 wt.% additives provided good FR properties while the resonable battery performance is maintained.

Properties of Composite Bushing with Filament Winding Tension (필라멘트 와인딩 장력에 따른 Composite Bushing의 특성에 관한 연구)

  • Cho, Han-Goo;Kim, Kwang-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.03b
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    • pp.34-34
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    • 2010
  • This paper describes effect of the bending deformation of high voltage composite bushing with winding tension. The composite bushing can be formed, by adding silicone rubber sheds to a tube of composite materials. The FRP tube is internal insulating part of a composite bushing and is designed to ensure the mechanical characteristics. Generally the properties of FRP tube can be influenced by the winding angle, wall thickness and winding tension. As winding tension is increased glass contents was increased in the range of 70.4~76.6%. In the bending test, winding tension is increased residual deflection was decreased in the range of 14.0~12.2 mm.

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Structural Changes in $^{60}Co\;\gamma-Ray$ Irradiated Poly(vinylidene fluoride) ($^{60}Co\;\gamma$-선 조사에 의한 Poly(Vinylidene fluoride)의 구조적 변화)

  • Lee, Chung;Kim, Ki-Yup;Kim, Pyeong-Jong;Kim, Jin-Ah;Ryu, Boo-Hyung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.437-440
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    • 2004
  • The radiation-induced changes taking place in poly(vinylidene fluoride)(PVDF) exposed to $^{60}Co\;\gamma-ray$ irradiation were investigated in correlation with the applied doses. Samples were irradiated in air at room temperature by $^{60}Co\;\gamma-ray$ to doses in the range of 200 to 1000 kGy. Various properties of the irradiated PVDF were studied using nm, differential scanning calorimetry(DSC) and gel fraction. $^{60}Co\;\gamma-ray$ irradiation was found to induce changes in chemical, thermal, structural properties of PVDF and such changes vary depending on the radiation dose.

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High Thermal Conductivity h-BN/PVA Composite Films for High Power Electronic Packaging Substrate (고출력 전자 패키지 기판용 고열전도 h-BN/PVA 복합필름)

  • Lee, Seong Tae;Kim, Chi Heon;Kim, Hyo Tae
    • Journal of the Microelectronics and Packaging Society
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    • v.25 no.4
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    • pp.95-99
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    • 2018
  • High thermal conductivity films with electrically insulating properties have a great potential for the effective heat transfer as substrate and thermal interface materials in high density and high power electronic packages. There have been lots of studies to achieve high thermal conductivity composites using high thermal conductivity fillers such alumina, aluminum nitride, boron nitride, CNT and graphene, recently. Among them, hexagonal-boron nitride (h-BN) nano-sheet is a promising candidate for high thermal conductivity with electrically insulating filler material. This work presents an enhanced heat transfer properties of ceramic/polymer composite films using h-BN nano-sheets and PVA polymer resins. The h-BN nano-sheets were prepared by a mechanical exfoliation of h-BN flakes using organic media and subsequent ultrasonic treatment. High thermal conductivities over $2.8W/m{\cdot}K$ for transverse and $10W/m{\cdot}K$ for in-plane direction of the cast films were achieved for casted h-BN/PVA composite films. Further improvement of thermal conductivity up to $13.5W/m{\cdot}K$ at in-plane mode was achieved by applying uniaxial compression at the temperature above glass transition of PVA to enhance the alignment of the h-BN nano-sheets.

Electromagnetic Properties of Bulk High-Tc Superconductor (벌크형 초전도체의 전기자기적 특성)

  • Lee, Sang-Heon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.2
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    • pp.111-114
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    • 2017
  • In this research, the development of fabrication technique of bulk YBaCuO superconductors for application was studied. In fluence of $BaZrO_3$ addition on magnetization characteristics of thermal pyrolysis textured YBaCuO superconductor was investigated. Fine $BaZrO_3$ particle were dispersed within the textured YBaCuO matrix by means of the thermal pyrolysis processing. Magnetic levitation force for YBaCuO superconductors were obtained using Nd-B-Fe permanent magnet, at 77 K and at the magnetic field from 0 to 5.3 K gauss. In the unadded superconductor and 5 wt% $BaZrO_3$ addition, anomalous magnetization behavior, which is characterized by the intermediate magnetic field, was observed at 77 K. Critical current density was about few hundreds $A/cm^2$ and the magnetic characteristics increased slightly by addition of $BaZrO_3$ powder. Maximum magnetic force was obtained in the YBaCuO superconducting bulk with 3 wt.% $BaZrO_3$ addition.

P-type transport characteristics of copper-oxide thin films deposited by vacuum thermal evaporation (진공열증착으로 성막된 산화구리 박막의 p-형 전도특성)

  • Lee, Ho-Nyeon;Song, Byeong-Jun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.5
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    • pp.2267-2271
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    • 2011
  • This study was focused on getting p-type copper-oxide thin-film semiconductors suitable for p-channel thin-film transistors. Vacuum thermal evaporation and thermal annealing were used to get copper-oxide thin-film semiconductor having properties adoptable as an active layer of thin-film transistors. n-type thin films having electron carrier density of about $10^{22}\;cm^{-3}$ before thermal annealing was converted to p-type thin films having hole carrier density of about $10^{16}\;cm^{-3}$ as the thermal annealing conditions were optimized.

Synthesis, Characterization, and Properties of Fully Aliphatic Polyimides and Their Derivatives for Microelectronics and Optoelectronics Applications

  • Mathews Anu Stella;Kim Il;Ha Chang-Sik
    • Macromolecular Research
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    • v.15 no.2
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    • pp.114-128
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    • 2007
  • Polyimides are one of the most important classes of polymers used in the microelectronics and photoelectronics industries. Because of their high thermal stability, chemical resistance, and good mechanical and electric properties, polyimides are often applied in photoresists, passivation and dielectric films, soft print circuit boards, and alignment films within displays. Recently, fully aliphatic and alicyclic polyimides have found applications as optoelectronics and inter layer dielectric materials, due to their good transparencies and low dielectric constants $(\varepsilon)$. The low molecular density, polarity and rare probability of forming inter- or intra-molecular charge transfers, resulting in lowering of the dielectric constant and high transparency, are the most striking characteristics of aliphatic polyimide. However, the ultimate end use of polyimides derived from aliphatic monomers is in their targeted applications that need less stringent thermal requirements. Much research effort has been exerted in the development of aliphatic polyimide with increased thermal and mechanical stabilities, while maintaining their transparencies and low dielectric constants, by the incorporation of rigid moieties. In this article, the recent research process in synthesizing fully aliphatic polyimides, with improved dimensional stability, high transparency and low $\delta$values, as well as the characterizations and future scope for their application in micro electric and photo-electronic industries, is reviewed.