• 한국전기전자재료학회논문지
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• 제25권7호
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• pp.506-510
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• 2012

In this study, lead-free $(Na_{0.465}K_{0.465}Bi_{0.07})(Nb_{0.93}Ti_{0.07})O_3-0.08MnO_2$ ceramics were fabricated by conventional mixed oxide method. Structural and electrical properties of lead-free $(Na_{0.465}K_{0.465}Bi_{0.07})(Nb_{0.93}Ti_{0.07})O_3-0.08MnO_2$ ceramics with the variation of sintering temperature were investigated. As results of x-ray diffraction analysis, all specimens showed a typical polycrystalline perovskite structure without presence of the second phase. Sintered density increased with an increases of sintering temperature and the specimen sintered at $1,020^{\circ}C$ showed the maximum value of 4.5 $g/cm^3$. The average grain size of the $(Na_{0.465}K_{0.465}Bi_{0.07})(Nb_{0.93}Ti_{0.07})O_3-0.08MnO_2$ specimen sintered at $1,020^{\circ}C$ is about 0.83 ${\mu}m$. Electromechanical coupling factor, relative dielectric constant and dielectric loss of $(Na_{0.465}K_{0.465}Bi_{0.07})(Nb_{0.93}Ti_{0.07})O_3-0.08MnO_2$ specimens sintered at $1,020^{\circ}C$ were 0.252, 741 and 0.043% respectively.

• 한국전기전자재료학회논문지
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• 제18권3호
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• pp.243-247
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• 2005

In this study, in order to develop low temperature sintering ceramics for ultrasonic vibrator application, PNW-PMN-PZT system ceramics were manufactured according to the amount of CaCO$_3$ addition, and their piezoelectric, dielectric and microstructural characteristics were investigated. The ceramic specimens could be sintered at sintering temperature below 1000 $^{\circ}C$ due to the effect of Li$_2$CO$_3$-CaCO$_3$ liquid phase produced by the reaction of Li$_2$CO$_3$ and CaCO$_3$. At 0.2 wt% Li$_2$CO$_3$ and 0.25 wt％ CaCO$_3$ added specimen sintered at 920 $^{\circ}C$, the density, electromechanical coupling factor(k$_{p}$), mechanical quality factor(Q$_{m}$) and dielectric constant showed the optimal value of 7.78 g/㎤, 0.49, 1396, and 1300, respectively, for ultrasonic vibrator application.ion.

• 한국전기전자재료학회논문지
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• 제17권5호
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• pp.492-496
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• 2004

In this study, (0.96 －x)(PSN-PZT)－xBF－0.04 PNW＋0.3wt%MnO$_2$＋0.6wt%CuO ceramics were fabricated with the variations of the amount of BiFeO$_3$substitution and sintering temperature for the development of modified ceramics which can be sintered in the low temperature($\leq$100$0^{\circ}C$ ), and their microstructural, dielectric and piezoelectric characteristics were investigated. As the amount of BiFeO$_3$ substitution was increased, the density, mechanical quality factor(Q$_{m}$) and electromechanical coupling factor(k$_{p}$) showed the maximum value at each of sintering temperature. At sintering temperature of 98$0^{\circ}C$ and BiFeO$_3$substitution of 2 mol%, the density, dielectric constant and electromechanical coupling factor(k$_{p}$) showed the maximum value of 7.84 g/㎤, 1415 and 0.49, respectively. And at sintering temperature of 95$0^{\circ}C$ and BiFeO$_3$substitution of 3mol%, mechanical quality factor showed the maximum value of 1062. 1062.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 하계학술대회 논문집
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• pp.391-395
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• 2000

In this study, the temperature coefficient of resonant frequency(TC $F_{r}$), dielectric and piezoelectric properties of Pb[(S $b_{1}$2/N $b_{1}$2/)$_{0.0035}$-(M $n_{1}$3/N $b_{2}$3/)$_{0.0065}$-(Z $r_{x}$ $Ti_{1-x}$ )$_{0.90}$] $O_3$ceramics is investigated with Zr/Ti ratio. The dielectric constant and electromechanical coupling factor( $k_{p}$) showed the highest values of 1257, 0.562 respectively when the Zr/Ti ratio is 49.5/50.5. The mechanical quality factor( $Q_{m}$) is the lowest value of 713 when the Zr/Ti ratio is 49.5/50.5, and increased with the decrease of the Zr/Ti ratio. The temperature coefficient of resonant frequency(TC $F_{r}$) change abruptly at the morphotropic phase boundary(MPB), which is between the rhombohedral phase with highly negative TC $F_{r}$ of -106ppm/$^{\circ}C$ and the tetragonal phase with highly positive TC $F_{r}$ of +64pp $m^{\circ}C$ as Zr/Ti ratio changes from 50/50 to 49.5/50.5.50.5..5.50.5.5.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 춘계학술대회 논문집 반도체 재료 센서 박막재료 전자세라믹스
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• pp.161-164
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• 2004

In this study, to develop the composition ceramics for the Ultrasonic vibrator, $Pb(Mn_{1/3}Nb_{2/3})O_3Pb(Zr.Ti)O_3$ system ceramics were manufactured as a function of PCN substitution. Its dielectric and piezoelectric characteristics were investigated. With increasing the amount of PCN substitution, electromechanical coupling factor(kp) were increased until 3mol% PCN and that after decreased. mechanical quality factor(Qm) showed the maxinum value at 2mol% PCN. Eletromechanical coupling factor, mechanical quality factor and dielectric constant were showed optimum value at PCN 2mol% as 0.58, 1630 and 1407, respectively for ultrasonic vibrator applications.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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• pp.421-424
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• 2004

In this study, in order to develop low temperature sintering ceramics for ultrasonic vibrator, PNW-PMN-PZT system ceramics were manufactured with the amount of $CaCO_3$ addition and their piezoelectric, dielectric and microstructural characteristics were investigated. $CaCO_3$ addition to PNW-PMN-PZT basic composition was proved to be capable of sintering the ceramics at temperature below $1000^{\circ}C$ due to the effect of $Li_2CO_3-CaCO_3$ liquid phase. However, with increasing the amount of $CaCO_3$ addition, the second phase was appeared. As the results, electromechanical coupling coefficient (kp) and dielectric constant $(\epsilon_r)$ decreased. Taking into consideration electromechanical coupling coefficient (kp) of 0.49, mechanical quality factor (Qm) of 1396, dielectric constant $(\epsilon_r)$ of 1300 and density of $7.78[g/cm^2]$, it was concluded that the 0.25wt% $CaCO_3$ addition composition ceramics sintered at $920^{\circ}C$ was suitable for ultrasonic vibrator application.

• 한국전기전자재료학회논문지
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• 제21권2호
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• pp.126-130
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• 2008

In this study, in order to develop low loss multilayer piezoelectric actuator, PZN-PZT ceramics were fabricated using $Li_2CO_3,\;Bi_2O_3$, CuO and ZnO as sintering aids, their structural, piezoelectric and dielectric characteristics were investigated according to the amount of ZnO addition, At the sintering temperature of $870^{\circ}C$, the density, electromechanical coupling factor(kp), mechanical quality factor(Qm), dielectric constant(${\epsilon}_r$) and piezoelectric constant($d_{33}$) of 0.4 wt% ZnO added specimen (sintered at $870^{\circ}C$) showed the optimum value of $7.812g/cm^3$, 0.535, 916, 1399, 335 pC/N respectively. Taking into consideration above piezoelectric properties of the specimen sintered at low temperature, it was concluded that PZN-PZT ceramics using 0.4 wt% ZnO as additive showed the optimum characteristics as the composition ceramics for low loss multilayer piezoelectric actuator application.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1999년도 추계학술대회 논문집
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• pp.297-299
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• 1999

Effects of additives on the ceramic and electrical properties of Pb(Y$_{1}$2/Ta$_{1}$2/)O$_3$-PbZrO$_3$-PbTiO$_3$ceramics in a perovskite type structure were investigated. The dielectric and piezoelectric properties of the base composition were improved markedly through selection of Fe$_2$O$_3$ additives in proper amounts. The composition Pb(Y$_{1}$2/Ta$_{1}$2/)O$_3$-PbZrO$_3$-PbTiO$_3$ obtained the dielectric constant ($\varepsilon$$_{r}$=1,425). Also, electromechanical couping factors for planar(k$_{p}$) and piezoelectric constant(d$_{33}$) were obtained 0.50 and 294[pC/N] at the additives 0wt% Fe$_2$O$_3$ respectively. The mechanical quality facor(Q$_{m}$) of Pb(Y$_{1}$2/Ta$_{1}$2/)O$_3$-PbZrO$_3$-PbTiO$_3$+Fe$_2$O$_3$(0.3 wt%) is about 510.510.510.

• 한국전기전자재료학회논문지
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• 제13권3호
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• pp.214-219
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• 2000

In this paper the structural dielectric and piezoelectric properties of Pb［(M $g_{1}$2// $W_{1}$2/)$_{x}$-(N $i_{1}$3//N $b_{2}$3/)$_{0.15-x-(Zr_{0.5})}$ $Ti_{0.5}$)$_{0.85}$］ $O_3$ (x=0.0~0.10) ceramic were investigated with the substitution of Pb(M $g_{1}$2// $W_{1}$2/) $O_3$. According to the substitution of Pb(M $g_{1}$2//W/1/2/) $O_3$ curie temperatures were slightly decrease due to the decrease of the tetrag-onality of crystal structure and coercive fields were decreased. Up to the substitution of Pb(M $g_{1}$2// $W_{1}$2/) $O_3$ 3mol%,remnant polarization dielectric constant piezoelectric constant were increased. Dielectric constant and electro-mechanical coupling factor( $k_{p}$, $k_{31}$ ) were appeared the highest value of 2230, 0.64, and 0.38 and piezoelectric constant( $d_{33}$ , $d_{31}$ ) was the largest value of 418, 202($\times$10$^{-12}$ /C/N), respectively, when the substitution amount of Pb(M $g_{1}$2// $W_{1}$2/N) respectively, when the substitution amount of Pb(M $g_{1}$2// $W_{1}$2/) $O_3$ was 3mol%.s 3mol%.%.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
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• pp.172-173
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• 2008

In this study, $0.95(K_{0.5}Na_{0.5})NbO_3$-0.05Li$(Sb_{0.8}Nb_{0.2})O_3$ + $Ag_2O$ + x wt% $MnO_2$ were investigated as a function of the amount of $MnO_2$ addition in order to improve dielectric and piezoelectric properties of Lead-free piezoelectric ceramics. With increasing the amount of $MnO_2$ addition, density and electromechanical coupling factor $(k_p)$ increased up to 0.3wt.% $MnO_2$ and decreased above 0.3wt.% $MnO_2$. At the sintering temperature of 1020 $^{\circ}C$, Electromechanical coupling factor $(k_p)$, density, dielectric constant $({\varepsilon}r)$ and mechanical quality factor $(Q_m)$ of composition ceramics with 0.4wt% $Ag_2O$ addition showed the optimal value of 0.431, 4.33 g/$cm^3$, 820 and 119, respectively.