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Piezoelectric and Dielectric Characteristics of Low Temperature Sintering PNW-PMN-PZT Ceramics according to CaCO3Addition

CaCO3 첨가에 따른 저온소결 PNW-PMN-PZT 세라믹스의 압전 및 유전특성

  • Published : 2005.03.01

Abstract

In this study, in order to develop low temperature sintering ceramics for ultrasonic vibrator application, PNW-PMN-PZT system ceramics were manufactured according to the amount of CaCO$_3$ addition, and their piezoelectric, dielectric and microstructural characteristics were investigated. The ceramic specimens could be sintered at sintering temperature below 1000 $^{\circ}C$ due to the effect of Li$_2$CO$_3$-CaCO$_3$ liquid phase produced by the reaction of Li$_2$CO$_3$ and CaCO$_3$. At 0.2 wt% Li$_2$CO$_3$ and 0.25 wt% CaCO$_3$ added specimen sintered at 920 $^{\circ}C$, the density, electromechanical coupling factor(k$_{p}$), mechanical quality factor(Q$_{m}$) and dielectric constant showed the optimal value of 7.78 g/㎤, 0.49, 1396, and 1300, respectively, for ultrasonic vibrator application.ion.

Keywords

References

  1. 이수호, 박정학, 사공건, '압전진동자 재료와 응용기술;초음파 발진용 압전진동자와 응용기술', 전기전자재료학회지, 14권, 4호, p. 1, 2001
  2. K. Murakami, D. Mabuchi, T. Kurita, Y. Niwa, and S. Kaneko, 'Effects of adding various metal oxides on low-temperature sintered $Pb(Zr,Ti)O_3$ ceramics', Jpn. J. Appl. Phys., Vol. 35, No. 9B, p. 5188, 1996
  3. D. Dong, K. Murakami, Kaneko, and S, Xiong, M, 'Piezoelectric properties of ceramics sintered at low temperature with complexoxide additives', J. Ceramic Society. Jpn., Vol. 101, No. 10, p. 1090, 1993
  4. 류주현, 우원희, 오동언, 정영호, 정광현, 정문영, 정희승, 'CuO가 PSN PZT세라믹스의 저온 소결 특성에 미치는 영향', 한국전기전자재료학회논문지, 16권, 123호, p. 1200, 2003
  5. 정광현, 이덕출, 류주현, '소결조제 변화에 따른 PCW-PMN-PZT세라믹스의 저온소결 및 압전 특성', 전기전자재료학회논문지, 17권, 12호, 2004
  6. Ernest M. Levin and Carl R. Robbins, 'Phase diagrams for ceramists', The American Ceramic Society, Vol. 1, p. 323, 1979
  7. B. Jaffe, W. R. Cook, and H. Jaffe, 'Piezoelectric Ceramics', Academic Press London, p. 148, 1971
  8. Yuhuan Xu, 'Ferroelectric Materials and Their Application', Elsevier Science Publishers, p. 140, 1991
  9. 류주현, 황락훈, 김선희, 오동언, 장은성, 정영호, 홍재일, 'PDA CCFL 구동을 위한 압전 트랜스포머용 PNW PMN PZT 세라믹스의 $Nb_2O_5$첨가에 따른 미세구조 및 압전특성', 한국전기전자재료학회논문지, 17권, 3호, p. 289, 2004