• 폴리머
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• 제25권2호
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• pp.302-310
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• 2001

무전해도금법을 이용하여 구리/PET 필름 복합재료를 제조하였으며 에칭방법과 촉매액의 조성 및 acceleration 방법을 달리하여 PET 필름과 무전해도금된 구리 피막간의 접착력을 향상시키고자 하였다. HCl 용액으로 에칭된 PET 필름은 NaOH에 의한 것보다 더욱 세밀하게 에칭되어져 구리와 PET 필름간의 접착력은 향상되었으나 전자파 차폐효과는 유사한 경향을 보였다. 촉매액의 조성변화에 따른 영향을 살펴본 결과 PdCl$_2$:SnCl$_2$의 몰비가 1:4에서 1:16으로 증가할수록 PET 필름 위에 적층된 Pd/Sn 콜로이드 입자들의 크기가 감소하며 고르게 분포되는 경향을 보였다. 따라서 이들의 몰비가 증가할수록 구리도금이 균일하고 조밀하게 이루어져 접착력 및 차폐효과가 증가하였다. 또한 NaOH보다 HCl로 acceleration한 경우 촉매 입자의 크기가 작고 더 균일하게 분포되어 우수한 접착력과 도금물성을 나타내었다.

• 접착 및 계면
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• 제18권2호
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• pp.59-67
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• 2017

스마트 모바일 산업의 성장에 따라 부품의 집적화가 가속화 되고 있다. 이러한 부품의 집적화는 부품간의 간섭현상문제를 야기했으며, 이를 해결하기 위한 전자파 차폐 기술의 중요성이 부각되고 있다. 전자파 차폐 기술은 전자파를 반사하거나 흡수하는 방식으로 구현되며, 일반적으로 전도성물질이 전자파 차폐에 활용된다. 최근 산업의 변화에 따라 투명 차폐기술이 요구되고 있으며, 본 연구에서는 임프린팅 기술을 활용한 음각 구조 패턴에 전도성 복합 바인더를 충진 하여 투명 차폐소재를 제안하고자 하였다. 전도성 복합 바인더를 제조하기 위하여 UV 중합 아크릴 바인더를 활용하고 전도성 부여를 위해 구상, 판상 및 적층상의 은 입자를 활용하였다. 은 입자의 구조적인 특징에 따라 경화특성, 전도성 그리고 접착력의 변화를 확인하였다. 경화과정에서는 구상 입자의 활용이 가장 효율적이었으며, UV에 취약한 구조를 보완할 추가적인 경화 시스템이 요구되었다. 전도성평가에서는 적층상 구조가 우수한 특성을 보였다. 접착력은 구상이 가장 우수한 특성을 보였으며, 표면에서의 불규칙성에 따른 결과로 평가된다. 최종적으로 이를 활용한 패턴필름은 우수한 투명특성을 보여주었다.

• Carbon letters
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• 제22권
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• pp.36-41
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• 2017

Biodegradable epoxy (B-epoxy) was prepared from diglycidyl ether of bisphenol A and epoxidized linseed oil. The mechanical properties of B-epoxy composites reinforced with multi-walled carbon nanotubes (MWCNTs/B-epoxy) were examined by employing dynamic mechanical analysis, critical stress intensity factor ($K_{IC}$) tests, and impact strength tests. The electromagnetic interference shielding effectiveness (EMI-SE) of the composites was evaluated using reflection and absorption methods. Mechanical properties of MWCNTs/B-epoxy were enhanced with an increase in the MWCNT content, whereas they deteriorated when the MWCNT content was >5 parts per hundred resin (phr). This can likely be attributed to the entanglement of MWCNTs with each other in the B-epoxy due to the presence of an excess amount of MWCNTs. The highest EMI-SE obtained was ~16 dB for the MWCNTs/B-epoxy composites with a MWCNT content of 13 phr at 1.4 GHz. The composites (13 phr) exhibited the minimum EMI-SE (90%) when used as shielding materials at 1.4 GHz. The EMI-SE of the MWCNTs/B-epoxy also increased with an increase in the MWCNT content, which is a key factor affecting the EMI-SE.

• Bulletin of the Korean Chemical Society
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• 제34권1호
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• pp.99-106
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• 2013

Polyaniline-yttrium trioxide (PAni-$Y_2O_3$) composites were synthesized by the in-situ polymerization of aniline in the presence of $Y_2O_3$ The composite formation and structural changes in these composites were investigated by X-ray diffraction (XRD), Fourier transform infra red spectroscopy (FTIR), scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). The direct current (DC) electrical conductivity of the order of $0.51{\times}10^{-2}\;S\;cm^{-1}-0.283\;S\;cm^{-1}$ in the temperature range 300 K-473 K indicates semiconducting behavior of the composites. Room temperature AC conductivity and dielectric response of the composites were studied in the frequency range of 10 Hz to 1 MHz. The variation of AC conductivity with frequency obeyed the power law, which decreased with increasing weight percentage (wt %) of $Y_2O_3$. Studies on dielectric properties shows the relaxation contribution coupled by electrode polarization effect. The dielectric constant and dielectric loss in these composites depend on the content of $Y_2O_3$ with a percolation threshold at 20 wt % of $Y_2O_3$ in PAni. Electromagnetic interference shielding effectiveness (EMI SE) of the composites in the frequency range 100 Hz to 2 GHz was in the practically useful range of -12.2 dB to -17.2 dB. The observed electrical and shielding properties were attributed to the interaction of $Y_2O_3$ particles with the PAni molecular chains.

• 한국광학회:학술대회논문집
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• 한국광학회 2002년도 하계학술발표회
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• pp.194-195
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• 2002

투명 전도성 박막은 저방출 코팅, 평판디스플레이의 투명전극, 플라즈마 디스플레이 패널(PDP)의 전자파 장해 차폐 둥의 넓은 영역에서 사용되고 있다 특히 PDP의 전자파 장해(electromagnetic interference; EMI)를 막기 위한 필터는 광학적으로 가시광선영역의 높은 투과율과 전도성이 우수한 전기적 특성을 갖고 있어야 한다 이러한 고 효율의 투명전도성 박막은 일반적으로 (산화물-금속-산화물) 형태로 제작된다(1). (중략)

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2003년도 추계학술발표대회 논문집
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• pp.234-237
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• 2003

The absorption and the interference shielding of the electromagnetic wave problem have been a very important issue for commercial and military purposes. This study dealt with the simulation reflection loss for electromagnetic absorbing sandwich type structures in X-band(8.2Ghz~12.4GHz). Glass/epoxy composites containing conductive carbon blacks were used for the face sheets and styrofoams were used for the core. Their permittivities in X-band were measured using the transmission line technique. Simulation results of 3-1ayered sandwich type structures showed the reflection loss using the theory about transmission and reflection in a multi-layered medium.

• 한국표면공학회지
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• 제38권6호
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• pp.212-215
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• 2005

Novel continuous electroforming process equipped with a rotating patterned mandrel, soluble/insoluble anode and multiple stage of rolling wheels was proposed to produce precision nickel mesh, which is known as a very efficient electromagnetic interference (EMI) shielding material. Continuously electroformed nickel deposits showed a tendency to form small-sized particles as the plating solution temperature increased and mandrel rotation speeded up and the applied current density decreased. Along the honeycomb patterns of mandrel, nickel was accurately electrodeposited on the surface of rotating mandrel, but quite different visual/structural characteristics were measured on both sides.

• 한국세라믹학회지
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• 제37권9호
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• pp.921-926
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• 2000

에틸렌과 프로판가스로부터 Ni 및 Ni-Cu의 합금촉매를 사용하는 화학증착반응에 의해 제조한 나노탄소섬유에 충전재로 하고, 환경 친화적인 폴리비닐알코올을 매트릭스로 이용하여 복합재를 제조하여 전자파 차폐효능을 조사해 보았다. 전자파 차폐용 충전재의 중요한 물성치인 전기전도도는 나노탄소섬유의 반응조건에 따라 매우 민감하게 변했는데, 전체적으로 10000 psi 압력에서 4.2~29 S/cm 사이에 분포하였고 합금촉매보다도 순수한 Ni로 제조된 나노탄소섬유의 전기전도도 값이 높았다. 한편, 나노탄소섬유/폴리비닐알코올 복합재의 전기전도도는 Ni:Cu(7:3) 합금촉매에서 제조된 나노탄소섬유를 충전시켰을 때, 가장 높게 얻어져서 충전재의 전기전도도 외에도 비표면적이 중요한 변수임을 알 수 있었다. PVA 양에 대한 나노탄소섬유의 함량이 증가할수록 나노탄소섬유 복합재의 전기전도도는 기하급수적으로 증가했고, 110$0^{\circ}C$에서 1시간 동안 나노탄소섬유의 열처리를 통하여 복합재의 전기전도도는 5~7배 증가하였으며, 전자파 차폐율은 2~3 dB 정도 향상시킬 수 있었다.

• 한국표면공학회지
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• 제47권5호
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• pp.269-274
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• 2014

Electroless plating process as a solution deposition method is a viable means of preparing conductive metal films on non-conducting substrates through chemical reactions. In the present study, the preparation and properties of electroless Ni-plating on flexible silicone rubber are described. The process has been performed using a conventional Ni(P) chemical bath. Additives and complexing agents such as ammonium chloride and glycine were added and the reaction pH was controlled by NaOH aqueous solution. Ni deposition rate and crystallinity have been found to vary with pH and temperature of the plating bath. It was shown that Ni-films having the high crystallinity, enhanced adhesion and optimum electric conductivity were formed uniformly on silicone rubber substrates under pH 7 at $70^{\circ}C$. The conductive Ni-plated silicone rubber showed a high electromagnetic interference shielding effect in the 400 MHz-1 GHz range.

• Advanced Composite Materials
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• 제16권1호
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• pp.1-10
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• 2007

Composite materials consisting of crushed carbon fiber reinforced plastics (CFRP) pieces and acrylonitrile-butadiene-styrene (ABS) resin were prepared by an injection mold method to solve the problem of recycling of CFRP. The electrical properties, such as electrical resistivity, alternating current impedance and electromagnetic interference (EMI) shielding effect, were measured for the composites. The electrical resistivity of the composites showed a percolation type of conduction behavior and no difference between parallel and perpendicular to the injection direction was observed for CFRP content higher than the critical value. Measurement of alternating current impedance revealed that the conduction mechanism is attributed to the direct conductive paths generated by distributed carbon fibers; however, strong frequency dependence of the impedance was observed for the CFRP content near the critical one. The frequency dependence of the impedance is caused by the inter-fiber connection and can be expressed as a simple equivalent circuit. The absorption component of shielding effect (SE) was smaller than the expected value estimated from its resistivity. The decline of SE is thought to be caused by the decrease in effective thickness due to fiber orientation.