• 제목/요약/키워드: Electrolytic process

검색결과 321건 처리시간 0.024초

Surface and Corrosion Properties of Electrolytic Polished 316L Stainless Steel by Double Melting (VIM and VAR)

  • Hyunseung Lee;Gangsan Kim;Seungho Han;Man-Sik Kong;Jung-Yeul Yun;Si Young Chang
    • 한국주조공학회지
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    • 제43권5호
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    • pp.223-229
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    • 2023
  • In this study, STS316L produced by a double-melting process involving vacuum induction melting (VIM) and vacuum arc remelting (VAR) was subjected to extrusion and drawing to form a tube and was subsequently electrolytic polished (EP). The grain size of the obtained STS316L without EP was approximately 55 ㎛, with no difference found after EP. The thickness of the EP layer was measured by AES and TEM, showing values of approximately 10 nm and 15 nm, respectively. After EP, the Cr/Fe and CrO/FeO ratios of the passive layer increased from 1.48 to 1.62 and from 2.15 to 2.26, respectively, while the surface roughness decreased significantly from 0.255 to 0.024 ㎛. Consequently, the corrosion rate decreased in both NaCl and HCl solutions after the EP process. Additionally, the amounts of eluted Cr and Fe ions were reduced from 1.2 to 0.8 ppb and 10.3 to 0.8 ppb, respectively. Furthermore, polarization tests revealed that STS316L treated with EP required a lower current density to reach a passive state, indicating that corrosion behavior was retarded.

피스톤 핀의 자기전해 경면연마 시스템 개발 (Development of Magneto-Electrolytic-Abrasive Polishing System for Piston Pin)

  • 김정두
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 1998년도 춘계학술대회 논문집
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    • pp.59-64
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    • 1998
  • We need to achieve th mass product through methods of higher efficient, higher precise manufacturing process than those of existing precision abrasive machining. Thus, this study is to develop mirror-like surface machining technique of outer diameter of the piston pin by the compound magneto-electrolytic abrasive polishing system. The procedure of machining is followed as first, fulfill the pre-processing by cylindrical grinder, second, complete mirror-like surface by the method of magneto-electrolytic abrasive polishing used CBN non-woven abrasive pads. In this study, it was found that the best suitable conditions of mirror-like surface polishing were that the electrode density was 0.1A/$\textrm{cm}^2$, the applied pressure 1.5kgf/$\textrm{cm}^2$, the feed rate 0.5mm/rev, and the rotoation velocity of workpiece 80rpm, and that the surface roughness was reduced in this conditions.

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고등어육 단백질 가열겔 물성에 대한 알카리 전해수세수 효과 (Effects of Electrolytic Alkali Water Washing on Mackerel (Scomber japonicus) Muscle Protein Heat Gel Rheology)

  • 이남걸
    • 한국환경과학회지
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    • 제21권2호
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    • pp.233-240
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    • 2012
  • In this study, the alkiline water washing condition of mackerel(Scomber japonicus) dark meat was investigated to improve processing conditions of red muscle fish meat paste heating gel. Chemical alkaline water(CWM) and electrolytic alkiline water(EWM, pH 12) were used for washing the mackerel raw meat. Washed meats were minced with 2.5% salt and heated at $90^{\circ}C$/15 min to testing texture profile analysis. Moisture of CWM and EWM was increased with both washing times(p<0.05). Crude lipids and protiens were decreased with washing times. Lightness of chemical alkaline water washed mackerel heated paste gel(CWHPG) was higher than electrolytic alkaline water washed mackerel heated paste gel(EWHPG). Redness and yellowness were more decreased than control meats. Jelly strength of CWHPG and EWHPG was not increased more than 2 times wased meat and was increased with protein decrease. Texture profile analysis, max force1 of CWHPG and EWHPG was higher hardeness than the control meat except gel strains. From these results, it could be suggested that electric alkialine water washing is also effective in advance the red meat paste heating gel process of kamaboko industry.

사용후핵연료 시험시설에서 전기 금속 전환반응기의 내열 방안 분석 (Analysis on the heat-resisting method of the electrolytic metal reduction reactor in the test facility for the spent fuel waste)

  • 김영환;윤지섭;정재후;홍동희;박기용;진재현
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2003년도 춘계학술대회 논문집
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    • pp.776-779
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    • 2003
  • To reduce the storage space of spent fuel used at the atomic power plants in the over the world, the uranium elements contained in the spent fuel is being extracted and effectively stored. For this, the spent fuel are oxidized and deoxidized. In this study, it is produced the heat-resisting methods about the spent fuel management technology research and test facility for the spent fuel waste for spent fuel minimized. The first considered processes in the facility are the electrolytic metal reduction reactor process. Since the electrolytic metal reduction reactor is operated at the high temperature range, we have to consider the heat-resisting methods for the devices. For the heat-resisting methods, we have searched and analyzed technical reference for the heat-resisting methods. We have calculated thermal stress and strain of each devices by the commercial analysis software, ANSYS. D.S. It is experimented for inspecting confidence rate of analysis results. By using the results, we have analyzed the problems of parts and determined the heat-resisting material, commercial parts, and the size of parts and O-ring. Based on these results, it is produced the heat-resisting methods of magnesia filter, cathode, and reactor for the electrolytic metal reduction reactor.

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전해수의 특성에 관한 연구 (The Study of Characteristics of Electrolytic Water)

  • 이찬우;배기서
    • 한국염색가공학회지
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    • 제18권6호
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    • pp.43-48
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    • 2006
  • Electrolytic water(EW), studied in recent decades in the Japan, Russia and United State of America, have shown promise as a method of disinfection whereby low levels of free chlorine, sodium hypochlorite, or hypochlorous acid may be produced in situ in Nacl-containing solution. These methods have shown promise in destruction of microorganisms in medical, dental environment, and in the agriculture and food industry. A recently EW treatment system was evaluated for reducing scouring agent and other surfactants in the washing and scouring process of textile industry Unfortunately, there is, to my knowledge, no serious studies of the properties of EW for textile industry In order to study the characteristics of EW and confirm the possibility of applications in textile industry processes, the pH, surface activity, penetration force, surface tension, and contact angle of EW was measured under various conditions. In general terms, What all this shows is that there is fundamental difference between the properties of EW and that of distilled water.

전해 산화제에 의한 악취 원인 VOCs 제거 특성 (Characteristics of odorous VOCs removal by using electrolytic oxidant)

  • 이태호;류희욱
    • 실내환경 및 냄새 학회지
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    • 제17권4호
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    • pp.381-388
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    • 2018
  • In this study, various conditions and phenomena that occur in the process of removing odorous VOCs by using electrolyzed oxidant were examined. The formation of hypochlorous acid, which is an oxidant produced by electrolysis, was investigated and the properties of the oxidizing agent used to decompose toluene, xylene, and cyclohexane were investigated. As a result, it was found that the production rate and the final concentration of the oxidizing agent increased with the current density. It was found that the degree of removal varies depending on the property of each pollutant. Interestingly, in the batch experiments in which the pH of the produced oxidant was controlled, it was found that the degree of elimination varied depending on the pH of the substance. These results suggest that the difference in the concentration and distribution of hypochlorous acid (HOCl) and hypochlorite ($OCl^-$) due to the pH change leads to the difference in oxidizing power on the oxidation characteristics of each substance. Styrene and terpineol showed better degradation characteristics than toluene and xylene in odorous VOC removal experiments by spraying electrolytic oxidant using a lab-scale continuous reactor. In conclusion, the removal of odorous VOCs by the electrolytic oxidant can have various applications in that it can oxidize pollutants of various spectra.

전해 이온화와 자외선광을 이용한 사파이어 화학기계적 연마의 재료제거 효율 향상에 관한 기초 연구 (Basic Study on the Improvement of Material Removal Efficiency of Sapphire CMP Using Electrolytic Ionization and Ultraviolet Light)

  • 박성현;이현섭
    • Tribology and Lubricants
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    • 제37권6호
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    • pp.208-212
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    • 2021
  • Chemical mechanical polishing (CMP) is a key technology used for the global planarization of thin films in semiconductor production and smoothing the surface of substrate materials. CMP is a type of hybrid process using a material removal mechanism that forms a chemically reacted layer on the surface of a material owing to chemical elements included in a slurry and mechanically removes the chemically reacted layer using abrasive particles. Sapphire is known as a material that requires considerable time to remove materials through CMP owing to its high hardness and chemical stability. This study introduces a technology using electrolytic ionization and ultraviolet (UV) light in sapphire CMP and compares it with the existing CMP method from the perspective of the material removal rate (MRR). The technology proposed in the study experimentally confirms that the MRR of sapphire CMP can be increased by approximately 29.9, which is judged as a result of the generation of hydroxyl radicals (·OH) in the slurry. In the future, studies from various perspectives, such as the material removal mechanism and surface chemical reaction analysis of CMP technology using electrolytic ionization and UV, are required, and a tribological approach is also required to understand the mechanical removal of chemically reacted layers.

고규소 알루미늄 합금의 표면에 PEO 공정에 의하여 형성된 산화물 층의 부식 거동 (Corrosion behavior of oxide layer formed on surface of high silicon aluminum alloy by PEO process)

  • 박덕용
    • 한국표면공학회지
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    • 제56권4호
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    • pp.250-258
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    • 2023
  • Ceramic oxide layer was formed on the surface of high silicon aluminum alloy by using PEO (plasma electrolytic oxidation) process. The microstructure of the oxide layer was analyzed using scanning electron microscopy (SEM) and x-ray diffraction patterns (XRD). The high silicon aluminum alloy prior to PEO process consists of Al, Si and Al2Cu phases in XRD analysis, whereas Al2Cu phase selectively disappeared after PEO treatment. Considerable decrease of relative intensity in most of peaks in XRD results of the high silicon aluminum alloy treated by PEO process was observed. It may be attributed to the formation of amorphous phases after PEO treatment. The corrosion behavior of the high silicon aluminum alloy treated by PEO process was investigated using electrochemical impedance spectroscopy (EIS) and other electrochemical techniques (i.e., open circuit potential and polarization curve). Electroanalytical studies indicated that the high silicon aluminum alloy treated by PEO process shows greater corrosion resistance than that untreated by PEO process.