• Title/Summary/Keyword: Electrolyte treatment

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Cellmembrane Electrolyte Flow Research Using Electromagnetic Characteristics of Needle and Magnet (침과 자석의 전자기적 특성을 이용한 세포막 전해질 흐름 연구)

  • Lee, Y.J.;Park, M.
    • Proceedings of the KIEE Conference
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    • 2002.11c
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    • pp.3-6
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    • 2002
  • In this paper, the electrolyte flow treatment is suggested using together with needle and magnet. On account of Lorentz force law, we can not only induce the circulation of body fluids at specific hurt but also apply on the treatment of cell membrane voltage control controlling the electrolyte flow. If electric field is added to human body fluid, electrolyte and then magnetic field is taken by magnet, we can induce local region flow through needle, global region flow with artificial electrical field and magnetic field. Electrolyte flow is excellent treatment in clinical treatment.

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Investigation About Surface Microstructure of Aluminum with Change of Voltage, a Period of Treatment and Density of Electrolyte in Micro-Arc Oxidation Treatment (MAO(Micro-Arc Oxidation) 공정 중 인가 전압, 반응 시간, 전해액 농도에 따른 알루미늄의 표면 미세조직 평가)

  • Yeo, In-Chul;Kang, In-Cheol
    • Journal of Powder Materials
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    • v.18 no.6
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    • pp.575-582
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    • 2011
  • MAO(Micro-Arc Oxidation) method was used to make $Al_2O_3$ surface on 6063 Al specimen. This study was focused on an influence of voltage, density of electrolyte and a period of treatment on the change of surface microstructure by using SEM(Scanning Electron Microscope), EDS(Energy Dispersive X-ray Spectroscopy). The microstructure shows higher roughness and thicker oxidized layer with increase of voltage and maintaining period of treatment. The density of electrolyte affected a formation of more dense surface and increase of a oxidized layer.

A Study on the Mechanical Properties of Polymer Electrolyte Membrane according to Temperature (온도에 따른 고분자전해질막의 기계적 특성에 관한 연구)

  • EO, JUNWOO;KIM, SEUNGHWAN;SEO, YOUNGJIN;KO, HYUNGJONG;HWANG, CHULMIN;JUNG, YOUNGGUAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.5
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    • pp.566-573
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    • 2022
  • In this study, the mechanical properties of the polymer electrolyte membrane according to the temperature were studied. The test specimens of polymer electrolyte membrane were heat treated at 40℃, 60℃, 80℃, 100℃, and 120℃, and then the tensile tests were performed. As results of this study, the residual stress of the polymer electrolyte membrane was removes by the heat treatment and the elastic modulus decreased due to the decrease in internal energy. In addition, in the plastic region, the mechanical properties and crystallization rate of the polymer electrolyte membrane increased in proportion according to increase of the heat treatment temperature.

Effect of Sodium Aluminate Concentration in Electrolyte on the Properties of Anodic Films Formed on AZ31 Mg Alloy by Plasma Electrolytic Oxidation (AZ31 마그네슘 합금의 플라즈마 전해 산화에서 Sodium Aluminate 농도가 산화막 특성에 미치는 영향)

  • Lee, Jong-Seok;Baek, Hong-Gu;Kim, Sung-Wan
    • Journal of the Korean Society for Heat Treatment
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    • v.25 no.5
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    • pp.227-232
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    • 2012
  • Magnesium alloy have good physical properties such as good castability, good vibration absorption, high strength/weight ratios. Despite the desirable properties, the poor resistance of Mg alloy impedes their use in many various applications. Therefore, magnesium alloy require surface treatment to improve hardness, corrosion and wear resistance. Plasma Electrolytic Oxidation (PEO) is one the surface treatment methods to form oxide layer on Mg alloy in alkali electrolyte. In comparison with Anodizing, there is environmental process having higher hardness and faster deposition rate. In this study, the characteristics of oxide film were examined after coating the AZ31 Mg alloy through the PEO process. We changed concentration of sodium aluminate into $K_2ZrF_6$, KF base electrolyte. The morphologies of the coating layer were characterized by using scanning electron microscopy (SEM). Corrosion resistance also investigated by potentiodynamic polarization analysis. As a result, propertiy of oxide layer were changed by concentration of sodium aluminate. Increasing with concentration of sodium aluminate in electrolyte, the oxidation layer was denser and the pore size was smaller on the surface.

Bi-electrolyte Carbon Dioxide Gas Sensor Based on Paste Sodium-Beta Alumina and Yttria-stabilized Zirconia

  • Han, Hyeuk Jin;Park, Chong Ook
    • Journal of Sensor Science and Technology
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    • v.23 no.3
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    • pp.170-172
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    • 2014
  • $CO_2$ sensor was used only one solid electrolyte in many cases. To improve the sensing characteristics of $CO_2$ sensors, solid electrolyte $CO_2$ sensor has been developed by bi-electrolyte type sensor using Na-Beta-alumina and YSZ. However, in many further studies, bi-electrolyte type sensor was made by pellet pressed by press machine and additional treatment for formation of interface. In the aspect of mass production, using thick film and additional treatment is not suitable. In this study, $CO_2$ sensor was fabricated by bi-electrolyte structure which was made by an NBA paste layer deposited on YSZ pellet and fired at $1650^{\circ}C$ for 2 hour. The formation of stable interface between YSZ and NBA were confirmed by SEM image. When the type IV electrochemical cell arrangement represented by $CO_2,O_2,Pt{\mid}Li_2CO_3-CaCO_3{\parallel}NBA{\parallel}YSZ{\mid}O_2,Pt$ is used to measure the $CO_2$ concentration in air. This sensor EMF should depend only on the concentration of $CO_2$ by logarithmic. Also, sensor shows $P_{CO_2}$ and EMF relationship like nerstian reaction at a temperature of $450^{\circ}C$.

Electrolyte Addition for Enhanced Wastewater Treatment by Electrolysis using Cu Electrode

  • Kim, Woo-Yeol;Yun, Chan-Young;Son, Dong-Jin;Chang, Duk;Kim, Dae-Gun;Hong, Ki-Ho
    • Journal of Electrochemical Science and Technology
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    • v.8 no.1
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    • pp.35-42
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    • 2017
  • In this study, the effect of electrolyte addition on the removal of organics and nutrients in electrochemical wastewater using a copper electrode, and the characteristics of the by-product of electrolysis were investigated. The removal of organics increased significantly as shorter reaction times upon the addition of chloride ion, and most of the electrolysis reaction was completed within 20 min. The reaction rate gradually increased in proportion to the $Cl^-$/COD ratio, whereas the highest removed mass of organic matter per mass of added electrolyte was observed at a $Cl^-$/COD ratio of 1. After the addition of electrolyte, significant removal of ammoniacal nitrogen was observed as a result of the enhanced generation of oxidizers such as hypochlorite. Excellent phosphorus removal was also achieved in a very short reaction time (within 2 min) by electro-coagulation. As the electrolysis progressed, the amount of by-product increased gradually, whereas a decrease of sludge volume index was observed after the addition of electrolyte. This indicated that the settling performance of the by-products was better, and their removal would be easily achieved.

Room Temperature Na/S Batteries Using a Thick Film of Na β"-Alumina Composite Electrolyte and Gel-Type Sulfur Cathode (후막 Na β"-Alumina 복합 고체 전해질 및 Gel-Type 유황 양극을 활용한 상온형 Na-S 전지의 특성 평가)

  • Lee, Jinsil;Yu, Hakgyoon;Lee, Younki;Kim, Jae-Kwang;Joo, Jong Hoon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.5
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    • pp.411-417
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    • 2020
  • In this study, we introduce a Na β"-alumina composite thick film as a solid electrolyte, to reduce the resistance of electrolyte for a Na/S battery. An alumina/zirconia composite material was used to enhance the mechanical properties of the electrolyte. A solid electrolyte of about 40 ㎛ thick was successfully fabricated through the conversion and tape-casting methods. In order to investigate the effect of the surface treatment process of the solid electrolyte on the battery performance, the electrolyte was polished by dry and wet processes, respectively, and then the Na/S batteries were prepared for analyzing the battery characteristics. The battery with the dry process performed much better than the battery made with the wet process. As a result, the battery manufactured by the dry process showed excellent performance. Therefore, it is confirmed that the surface treatment process of the solid electrolyte has an important effect on the battery capacity and coulombic efficiency, as well as the interface reaction.

The Characteristic in Mg Alloy with Burning and Plasma Electrolyte Oxidation Surface Treatment (Mg Alloy의 Burning과 Plasma Electrolyte Oxidation 표면처리에 대한 연구)

  • Yu, Jae-In;Choi, Soon-Don;Jang, Ho-Kyeoung
    • Journal of the Korean Vacuum Society
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    • v.19 no.5
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    • pp.326-330
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    • 2010
  • The surface oxidation of magnesium was performed by burning and PEO treatment method. The scanning electron microscopy (SEM), EDS, and I-V characteristics have been applied to the study of the oxidation status. The sample formed by buring method shows weaker corrosion-resistant property than that by PEO method, but this shows more conducting property.

Solution-based fabrication of germanium sulphide doped with or without Li ions for solid electrolyte applications

  • Jin, Byeong Kyou;Cho, Yun Gu;Shin, Dong Wook;Choi, Yong Gyu
    • Journal of Ceramic Processing Research
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    • v.13 no.spc1
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    • pp.110-113
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    • 2012
  • Ge-S and Li-Ge-S powders were synthesized via solution-based process in order to employ chalcogenide-based solid electrolyte for use in Li secondary batteries. GeCl4 and thioacetamide in combination result in Ge-S powders of which major crystalline phase becomes GeS2 where the tetragonal and orthorhombic phases coexist after heat treatment. A chemical treatment using NaOH brings about the reduction of chlorine in the powders obtained. However, the heat treatment at 300 ℃ is more effective in minimizing the chlorine content. When lithium chloride is used as the precursor of Li ions, the LiCl powders are agglomerated with an inhomogeneous distribution. When Li2S is used, the Li-Ge-S powders are distributed more uniformly and the orthorhombic GeS2 phase dominates in the powders.

Operational conditions of electrochemical oxidation process for removal of cyanide (CN-) in real plating wastewater

  • Zhao, Xin;Jang, Minsik;Cho, Jin Woo;Lee, Jae Woo
    • Membrane and Water Treatment
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    • v.11 no.3
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    • pp.217-222
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    • 2020
  • An electrochemical oxidation process was applied to remove cyanide (CN-) from real plating wastewater. CN- removal efficiencies were investigated under various operating factors: current density and electrolyte concentration. Electrolyte concentration positively affected the removal of both CN- and Chemical Oxygen Demand (COD). As the electrolyte concentration increased from 302 to 2,077 mg Cl-/L, removal efficiency of CN- and COD increased from 49.07% to 98.30% and from 23.53% to 49.50%, respectively, at 10 mA/㎠. Current density affected the removal efficiency in a different way. As current density increased at a fixed electrolyte concentration, CN- removal efficiency increased while COD removal efficiency decreased, this is probably due to lowered current efficiency caused by water electrolysis.