• 제목/요약/키워드: Electrode life

검색결과 294건 처리시간 0.027초

Porous Electrodes with Lower Impedance for Vanadium Redox Flow Batteries

  • Park, Su Mi;Kim, Haekyoung
    • Korean Chemical Engineering Research
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    • 제53권5호
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    • pp.638-645
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    • 2015
  • Vanadium redox flow batteries (VRFBs) have been investigated for their potential utility as large energy storage systems due to their advantageous performances in terms of long cycle life, high energy efficiency, low cost, and flexible design. Carbon materials are typically used as electrodes in redox reactions and as a liquid electrolyte support. The activities, surface areas, and surface morphologies of porous carbon materials must be optimized to increase the redox flow battery performance. Here, to reduce the resistance in VRFBs, surface-modified carbon felt electrodes were fabricated, and their structural, morphological, and chemical properties were characterized. The surface-modified carbon felt electrode improved the cycling energy efficiencies in the VRFBs, from 65% to 73%, due to the improved wettability with electrolyte. From the results of impedances analysis with proposed fitting model, the electrolyte-coupled polarization in VRFB dramatically decreased upon modification of carbon felt electrode surface. It is also demonstrated that the compressibility of carbon felt electrodes was important to the VRFB polarization, which are concerned with mass transfer polarization. The impedance analysis will be helpful for obtaining better and longer-lived VRFB performances.

이종재료(알루미늄합금-강판)의 저항 점용접에 관한 연구 (A Study on Resistance Spot Welding of Dissimilar Sheet Metals(Aluminum Alloy - Steel Sheets))

  • 손병천;우승엽;이재범;최용범;장희석
    • Journal of Welding and Joining
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    • 제15권4호
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    • pp.42-62
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    • 1997
  • Resistance spot welding has been widely used in the sheet metal joining processes because of its high productivity and convenience. Recently, automobile industries are trying to replace partly steel sheets with aluminum alloy sheets. Among currently produced aluminum alloys, Al alloy sheets of Al-Mg-Si(6000 series) are being tested. Especially, 6000 series are the most probable substitute in view of strength and weldability. In this paper, an attempt was made to apply resistance spot welding to joining of dissimilar sheet metals (KS6383+SCPZn or KS6383+SHCP). An effort was made to balance heating rate in the Al alloy with that in the steel sheets by increasing electrode tip diameter. Although resistance spot welding of Al alloy sheet and sheet metals does not produce desirable nugget, it proved to have reasonable strength if optimal weld condition is found by tensile-shear strength and fatigue life test. Since spot weld joints in automobile are always experiencing repeated load, spot welding methodology proposed in this paper is found to be not suitable to automobile body manufacturing.

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심전도와 맥파 신호 검출을 위한 일체형 센서 시스템의 구현 (The Development of Integrated Sensor System for Measuring Simultaneously ECG, PPG and PPW)

  • 전계록;정동근;김기련;신범주
    • 한국산학기술학회논문지
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    • 제10권5호
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    • pp.992-999
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    • 2009
  • 심전도와 맥파를 측정함으로써 구해질 수 있는 맥파전달시간은 심혈관계의 상태를 진단하기 위한 의미 있는 지표가 된다. 그러나 맥파를 측정하는 동안 움직이거나, 측정 시에 가해지는 압력이 부정확할 경우, 잘못된 측정 결과를 얻을 수 있다. 이를 해결하기 위하여 본 논문에서는 심전도, 압력맥파 및 광전용적맥파를 동시에 측정할 수 있는 일체형 센서 시스템과 심전도를 지속적으로 측정할 수 있는 금속 전극을 개발하였으며, 실험을 통해 일체형 센서시스템 및 금속 전극의 유용성을 입증하였다.

Ni-MH 2차 전지용 고용량, 고성능 Zr-Ti-Mn-V-Ni계 수소저장합금의 개발에 관한 연구 (A Study on the Development of Zr-Ti-Mn-V-Ni Hydrogen Storage Alloy for Ni-MH Rechargeable Battery)

  • 김동명;정재한;이상민;이재영
    • 한국수소및신에너지학회논문집
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    • 제7권2호
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    • pp.137-145
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    • 1996
  • The Zr-based $AB_2$ type Laves phase hydrogen storage alloys have some promising properties, long cycle life, high discharge capacity, as electrode materials in reversible metal hydride batteries. However, when these alloys are used as negative electrode for battery, there is a problem that their rate capabilities are worse than those of commercialized $AB_5$ type hydrogen storage alloys. In this work, we tried to develop the Zr-based $AB_2$ type Laves phase hydrogen storage alloys which have high capacity and, especially, high rate capability.

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양극 활물질의 표면 코팅처리가 Ni-MH 2차 전지의 전기화학적 특성에 미치는 영향 (Effects of the Surface Coating Treatment of Cathode Materials on the Electrochemical Characteristics of Ni-MH Secondary Batteries)

  • 김병섭;양동철;박봉기;박충년;박찬진
    • 한국수소및신에너지학회논문집
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    • 제22권4호
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    • pp.495-503
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    • 2011
  • The sealed nickel-metal hydride (Ni-MH) secondary battery are primarily used as energy storage for the HEV. But, the research on Ni-MH battery has focused on anode materials. In the present study, we investigate to improve the electrochemical characteristics of Ni-MH batteries using the surface treatment of $Ni(OH)_2$ cathode by CoOOH. Surface treated $Ni(OH)_2$ cathode showed significant improvement in the activation behavior, rate capability, charge retention, and cycle life of the batteries were significantly improved. In addition, the surface treated electrode exhibited the higher overvoltage for oxygen evolution than the untreated electrode. This phenomenon indicates that the charge efficiency can be improved by suppressing the oxygen evolution on cathode.

신생아에서 발생한 다소성심방빈맥 (Multifocal Atrial Tachycardia in a Newborn)

  • 조혜정;손동우;심소연;최덕영;이지성;배은정
    • Neonatal Medicine
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    • 제16권2호
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    • pp.239-243
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    • 2009
  • 다소성 심방 빈맥은 신생아에서 드물게 발생하며 진단하기에 어려워 심방 조동으로 오인되기도 한다. 치료가 어려우나 생후 1년 안에 자연적으로 사라지는 경우도 있다. 불규칙한 심방 빈맥을 가진 신생아에게 직접 제작한 경식도 전극을 이용한 심전도를 시행하여 다소성 심방 빈맥을 진단하였다. Propranolol은 치료에 효과적이지 않았으나 digoxin과 sotalol 투여 후 환자는 점차 동리듬으로 회복되었다. 신생아에서 경식도 전극을 이용하여 다소성 심방 빈맥을 진단하였던 1례를 보고한다.

Polycarprolactone Ultrafine Fiber Membrane Fabricated Using a Charge-reduced Electrohydrodynamic Process

  • Kim, Geun-Hyung;Yoon, Hyeon;Lee, Haeng-Nam;Park, Gil-Moon;Koh, Young-Ho
    • Macromolecular Research
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    • 제17권7호
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    • pp.533-537
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    • 2009
  • This paper introduces a modified electro spinning system for biomedical wound-healing applications. The conventional electrospinning process requires a grounded electrode on which highly charged electro spun ultrafine fibers are deposited. Biomedical wound-healing membranes, however, require a very low charge and a low level of remnant solvent on the electrospun membrane, which the conventional process cannot provide. An electrohydrodynamic process complemented with field-controllable electrodes (an auxiliary electrode and guiding electrodes) and an air blowing system was used to produce a membrane, with a considerably reduced charge and low remnant solvent concentration compared to one fabricated using the conventional method. The membrane had a small average pore size (102 nm) and high porosity (85.1%) for prevention of bacterial contamination. In vivo tests on rats showed that these directly electro spun fibrous membranes produced using the modified electro spinning process supported the good healing of skin bums.

$FeS_2$ 양극에 미치는 전도성 첨가제의 영향 (Effect of Conductive Additives on $FeS_2$ Cathode)

  • 최유송;정해원;김기열;조성백
    • 한국군사과학기술학회지
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    • 제15권2호
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    • pp.224-230
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    • 2012
  • Thermal batteries have excellent mechanical robustness, reliability, and long shelf life. Due to these characteristics as well as their unique activation mechanism, thermal batteries are widely adopted as military power sources. Li(Si)/$FeS_2$ thermal batteries, which are used mostly in these days, use LiCl-KCl and LiBr-LiCl-LiF as molten salt electrolyte. However, it is known that Li(Si)/$FeS_2$ thermal batteries have high internal resistance. Especially, $FeS_2$ cathode accounts for the greater part of internal resistance in unit cell. Many efforts have been put into to decrease the internal resistance of thermal batteries, which result in the development of new electrode material and new electrode manufacturing processes. But the applications of these new materials and processes are in some cases very expensive and need complicated additional processes. In this study, internal resistance study was conducted by adding carbon black and carbon nano-tube, which has high electron conductivity, into the $FeS_2$ cathode. As a results, it was found that the decrease of internal resistance of $FeS_2$ cathode by the addition of carbon black and carbon nano-tube.

국내 연료전지 분야 연구동향 분석: 전극, 전해질, 분리판, 스택, 시스템, BOP, 진단분석 분야 (Review of Research Trend in Fuel Cell: Analysis on Fuel-Cell-Related Technologies in Electrode, Electrolyte, Separator Plate, Stack, System, Balance of Plant, and Diagnosis Areas)

  • 이영덕;김재엽;유동진;주현철;김한상
    • 한국수소및신에너지학회논문집
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    • 제31권6호
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    • pp.530-545
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    • 2020
  • This paper reviews and summarizes the fuel-cell-related studies those have been recently published in major Korean Citation Index journals, aiming at analyzing the research trend in fuel cell technologies. Six major journals are selected for the literature survey; 57 papers are chosen for the detailed analysis through a screening examination on the total 1,040 papers published during between 2018 and 2020. Papers are classified into six technical categories, such as i) electrode, ii) electrolyte, iii) bipolar plate and stack, iv) fuel cell system, v) balance of plant, and vi) diagnosis-related studies, and summarized by the experts in the relevant area. Through this paper, we provide a comprehensive review on the recent trends and progress in fuel-cell-related research work in Korea.

Recent advances in 2-D nanostructured metal nitrides, carbides, and phosphides electrodes for electrochemical supercapacitors - A brief review

  • Theerthagiri, Jayaraman;Durai, Govindarajan;Karuppasamy, K.;Arunachalam, Prabhakarn;Elakkiya, Venugopal;Kuppusami, Parasuraman;Maiyalagan, Thandavarayan;Kim, Hyun-Seok
    • Journal of Industrial and Engineering Chemistry
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    • 제67권
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    • pp.12-27
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    • 2018
  • Supercapacitors (SCs) has gained an impressive concentration by the researchers due to its advantages such as high energy and power densities, long cyclic life, rapid charge-discharge rates, low maintenance and desirable safety. Hence it has been widely utilized in energy storage and conversion devices. Among the different components of SC, electrodes play a vital role in the performances of SCs. In this review, we present the recent advances in 2-D nanostructured metal nitrides, carbides, and phosphides based materials for SC electrodes. Finally, the electrochemical stability and designing approach for the future advancement of the electrode materials are also highlighted.