• Title/Summary/Keyword: Electrode density

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Fundamental Study on Cathodic Protection and Material Development as Erosion-Control Methods of Oceanic Centrifugal Pump(1) (해상용 원심펌프 임펠러의 침식억제법으로 음극방식 및 재료개발에 관한 기초연구 1)

  • 이진열;임우조
    • Journal of Advanced Marine Engineering and Technology
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    • v.19 no.2
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    • pp.56-66
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    • 1995
  • Recently, with theraped advancement in th oceanology such an ocean-going vessel and oceanic structures, there is a need to study the cavitation erosion-corrosion control of pump impeller, the partial element of ocean machinery, for more effective operation. Especially, the cathodic protection (impressed current method & Al-sacrificial anode method) was applied to sea water, and Cu-alloy material mixed Zn & Al was used as a control method of cavitation erosion-corrosion. In this study, used the piezoelectric vibrator with 20KHz, 24.mu.m to cavity generation apparatus, and investigated the weight loss, weight loss rate, electrode potential & current density etc. under this condition. According to test result, thos describes how to indentify an influence of the cathodic protection and Al & Zn addition in material development for the control of cavitation erosion-corrosion, and those will serve as fundamental data on the cavitation erosion-corrosion control of oceanic centrifugal pump.

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In situ Synchrotron X-ray Techniques for Structural Investigation of Electrode Materials for Li-ion Battery (방사광 X-선을 이용한 리튬이온전지 소재의 실시간 구조 분석 연구)

  • Han, Daseul;Nam, Kyung-Wan
    • Ceramist
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    • v.22 no.4
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    • pp.402-416
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    • 2019
  • The development of next-generation secondary batteries, including lithium-ion batteries (LIB), requires performance enhancements such as high energy/high power density, low cost, long life, and excellent safety. The discovery of new materials with such requirements is a challenging and time-consuming process with great difficulty. To pursue this challenging endeavor, it is pivotal to understand the structure and interface of electrode materials in a multiscale level at the atomic, molecular, macro-scale during charging / discharging. In this regard, various advanced material characterization tools, including the first-principle calculation, high-resolution electron microscopy, and synchrotron-based X-ray techniques, have been actively employed to understand the charge storage- and degradation-mechanisms of various electrode materials. In this article, we introduce and review recent advances in in-situ synchrotron-based x-ray techniques to study electrode materials for LIBs during thermal degradation and charging/discharging. We show that the fundamental understanding of the structure and interface of the battery materials gained through these advanced in-situ investigations provides valuable insight into designing next-generation electrode materials with significantly improved performance in terms of high energy/high power density, low cost, long life, and excellent safety.

Electrochemical Performance of Carbon-PTFE Electrode with High Capacitance and Density for EDLC (EDLC용 고용량, 고밀도 Carbon-PTFE 전극의 전기화학적 특성)

  • Kim, Ick-Jun;Jeon, Min-Je;Yang, Sun-Hye;Moon, Seong-In;Kim, Hyun-Soo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.541-542
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    • 2006
  • This work describes the effect of the number of roll pressing and the composition of carbon black on the electric and mechanical properties of carbon-PTFE electrode, in which composition is MSP 20 : carbon black : PTFE = 95-X : X : 5 wt.%. It was found that the best electric and mechanical properties were obtained for sheet electrode roll pressed about 15 times and for sheet electrode, in which composition is MSP 20 : carbon black : PTFE = 80 : 15 : 5 wt.%. These behaviors could be explained by the network structure of PTFE fibrils and conducting paths linked with carbon blacks, respectively. On the other hand, cell capacitor using the sheet electrode with 15 wt.% of carbon black attached on aluminum current collector with the electric conductive adhesive, in composition is carbon black : CMC = 70 : 30 wt.%, has exhibited the best rate capability between $0.5mA/cm^2{\sim}100mA/cm^2$ current density and the lowest ESR.

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Simulation of electromagnetic Phenomena in Vacuum interrupter with axial magnetic field type by Arc (아크 발생에 의한 축자계형 진공인터럽터의 전자계 현상 시뮬레이션)

  • Seo, Sang-Hyun;Ha, Sung-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05e
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    • pp.19-22
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    • 2003
  • In this paper, we performed analysis of electric field, magnetic field, current density in AMF electrode using the Maxwell 3D simulation. The current distribution and magnetic field in simple models are analyzed to verify its efficiency and accuracy. In the vicinity of the slits of axial magnetic field type electrode a comparatively high axial magnetic flux density existsIn addition the validity of FEM is confirmed by performing the analyses of distribution in current density and magnetic flux density.

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Volume Reduction of Waste Water Sludge using Electrolysis (전기분해를 이용한 하수 슬러지 감량)

  • Lee, Byungheon;Bang, Myunghwan;Kim, Geonha
    • Journal of Korean Society on Water Environment
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    • v.22 no.2
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    • pp.264-270
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    • 2006
  • In this research, volume reduction of activated sludge using electrolysis was studied to find an optimum condition using lab scale experiments. Wasted sludge was treated by electrolysis with controlling current density, chloride concentration, electrode distance, and reaction time. Volume of return sludge was reduced by 9.79% in average while maximum was 16.7%. Sludge volume reduction efficiency was affected by current density and reaction time. It was reversely proportional to the electrode distance. Especially current density was effective on the system performance significantly. Electric conductivity, salinity and COD were increased by electrolysis implying sludge disintegrated and converted to COD in part. An empirical equation for total solid removal efficiency by electrolysis was proposed by multiple linear regression analysis as: $TS_{rem}$(%) = 5.534 ${\times}$ current density (A/l) + 0.178 ${\times}$ reaction time (m) + 2.758.

Development of Inexpensive High Energetic Electrodes Ni-Cu and Ni-CeO2-Cu for Renewable Energy through Direct Ethanol Fuel Cell

  • Guchhait, Sujit Kumar;Paul, Subir
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.190-198
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    • 2016
  • Application of fuel cell to produce renewable energy for commercial purpose is limited by the high cost of Pt based electrode materials. Development of inexpensive, high energetic electrode is the need of the hour to produce pollution free energy using bio-fuel through a fuel cell. Ni-Cu and Ni-CeO2-Cu electrode materials, electro synthesized by pulse current have been developed. The surface morphology of the electrode materials is controlled by different deposition parameters in order to produce a high current from the electro-oxidation of the fuel, the ethanol. The developed materials are electrochemically characterized by Cyclic Voltammetry (CV), Chronoamperometry (CA) and Potentiodynamic polarization tests. The results confirm that the high current is due to their enhanced catalytic properties viz. high exchange current density (i0), low polarization resistance (Rp) and low impedance. It is worthwhile to mention here that the addition of CeO2 to Ni-Cu has outperformed Pt as far as the high electro catalytic properties are concerned; the exchange current density is about eight times higher than the same on Pt surface. The morphology of the electrode surface examined by SEM and FESEM exhibits that the grains are narrow and sub spherical with 3D surface, containing vacancies in between the elongated grains. The fact has enhanced more surface area for electro oxidation of the fuel, giving rise to an increase in current. Presence of Ni, CeO2, and Cu is confirmed by the XRD and EDXS. Fuel cell fabricated with Ni-CeO2-Cu material electrode is expected to produce clean electrical energy at cheaper rates than conventional one, using bio fuel the derived from biomass.

Charge Injection by Needle Electrode and Reduction Properties of Streaming Electrification (침 전극을 이용한 전하 주입과 유동대전 감소 특성)

  • Kim, Yong-Woon;Lee, Duck-Chool;Kang, Chang-Won
    • Proceedings of the KIEE Conference
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    • 2000.07e
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    • pp.108-112
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    • 2000
  • The electric charge generated by flowing insulation liquid can create hazardous spark in transfer line and receiving tank etc. These electrification has generally been measured by current measurement with a ammeter connected to the receiving tank. This paper reports on the experimental result obtained by this method. As a experimental results: The injected charge value for unit volume increased in the following condition, the edge of the needle electrode was sharp, the number of needle electrode was fewer, the edge of the needle electrode was located close to the inside wall. When the charge density in the charge reducer is constant, electrode current and electrode potential by the charge injection from outside increase with increasing of oil velocity and streaming current. The electrode potential in charge reducer is made maximum value at edge point of reducer inside and minimum value at center line of charge reducer.

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Electrical Propeties of Supercapacitor using Polyaniline and Polythiophene (Polyaniline과 Polythiophene을 사용한 Supercapacitor의 전기적 특성)

  • 강광우;김명산;김종욱;구할본
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.9
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    • pp.764-769
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    • 2000
  • The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Supercapactior cell of CP composite electrode with 1M LiClO$_4$/PC brings out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding 15Wt% SP270(PAnS15) and PT composite electrode adding 50%wt% SP270(PTS50) was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PTS50(+)/PAnS15(-) in 1st and 20th cycles was 38F/g and 28F/g at current density of 1mA/$\textrm{cm}^2$, respectively.

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Electrochemical Properties of Conducting Polymer for Supercapacitor (Supercapacitor용 도전성 고분자의 전기화학적 특성)

  • 강광우;김종욱;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.11a
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    • pp.332-334
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    • 2000
  • The purpose of this study is to research and develop conducting polymer(CP) composite electrode for supercapacitor. Supercapacitor cell of CP composite electrode with 1M LiClO$_4$/ PC bring out good capacitor performance below 4V. The radius of semicircle of CP composite cell with PAn composite electrode adding 30wt% acetylene black was absolutely small. The total resistance of supercapacitor cell mainly depended on internal resistance of the electrode. The discharge capacitance of supercapacitor cell with PAn composite electrode adding 30wt% acetylene black in 1st and 50th cycles was 27F/g and 31F/g at current density of 1mA/$\textrm{cm}^2$. Supercapacitor cell with PAn composite electrode adding 30wt% acetylene black performed a good cycliability.

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Electric Conduction Properties of NaCl Electrolyte as a Function of Electrode Materials (전극재료에 따른 NaCl 전해질의 전기전도특성)

  • Kim, Yong-Hyuk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.11
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    • pp.2026-2031
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    • 2010
  • The electrical characteristics of galvanic cell which is composed of the cathode electrode(graphite, carbon and copper) and the anode electrode(Zn and Mg) were investigated. For this research as electrolyte 2~12 wt% NaCl aqueous solution were used. At graphite cathode electrodes which use Zn and Mg with the anode electrode, the open circuit voltage was 1.3V most highly. The maximum output power increased as the electrolyte concentration increased, due to a increase in ion density. When Zn and Mg with the anode electrode, the maximum output power respectively was evaluated as 2.2mW and 5.5mW about the graphite cathode electrode in the NaCl 4wt%. The research results indicated that the output power of cell which is composed with graphite with the cathode and Mg with the anode was most excellent and the efficiency of the cell could be enhanced by increasing the electrolyte concentration.