• Title/Summary/Keyword: Electrode density

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Effects of anode surface area and methylene blue dye treatment on the power density of microbial fuel cell with sponge and carbon nano tube electrode (음극 전극 표면적과 메틸렌블루 염색이 스펀지 탄소나노 튜브 전극 미생물 연료전지의 전력수율에 미치는 영향)

  • Lee, Chae-Young;Park, Su-Hee;Song, Young-Chae;Woo, Jung-Hui;Yoo, Kyu-Seon;Chung, Jae-Woo;Han, Sun-Kee
    • Journal of Korean Society of Water and Wastewater
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    • v.26 no.6
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    • pp.883-888
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    • 2012
  • Anode electrode is one of the most important factors in microbial fuel cell (MFC). This study was conducted to investigate the effects of mediator as methylene blue (MB) and electrode surface area on the power density of MFC with sponge and carbon nano tube (CNT) electrode (SC). The SC electrode with MB (MC) showed the maximum power density increased from 74.0 $mW/m^2$ to 143.1 $mW/m^2$. The grid shaped sponge and CNT (GSC) electrode showed the maximum power density of 209.2 $mW/m^2$ due to the increase of surface area from 88.0 to 152.0 $cm^2$. The GSC electrode with MB (GMC) revealed the maximum power density of 384.9 $mW/m^2$ which was 5.2 times higher than that obtained from the MFC with SC. Therefore MB and increase of surface area led to enhance the performance of microbial fuel cell such as power density.

Evaluation of power density in microbial fuel cells using expanded graphite/carbon nanotube (CNT) composite cathode and CNT anode (팽창흑연·소나노튜브 복합 음극과 탄소나노튜브 양극으로 이루어진 미생물 연료전지의 전력수율 평가)

  • Han, Sun-Kee;Lee, Chae-Young
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.4
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    • pp.503-509
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    • 2013
  • Electrochemical redox capacity of a microbial fuel cell (MFC) electrode is an important factor in the power density. This study was conducted to investigate the redox capacity of surface modified anode and cathode electrodes by measuring their conductivities. An anode electrode was modified with nitric acid and a cathode electrode was modified with heat treatment. The anode electrode modified with 20 % of the nitric acid concentration showed the highest conductivity of $6.2{\mu}S/cm/g$ and the maximum power density of $306.0mW/m^2$ when used in a MFC. The cathode electrode modified at $472^{\circ}C$ for 18 min showed the highest conductivity of $5.2{\mu}S/cm/g$ and the maximum power density of $276.20mW/m^2$ when used in a MFC. On the other hand, an MFC using both the electrodes showed the highest maximum power density of $408.2mW/m^2$. Meanwhile, a control MFC without modified electrodes generated very small voltage (0.014 mV), so the power density could not be measured.

Composited Conductive Materials for Enhancing the Ultrafast Performance for Anode in Lithium-Ion Battery (리튬이온전지 음극의 고속 성능 향상을 위한 도전재 복합화)

  • Ki-Wook, Sung;Hyo-Jin, Ahn
    • Korean Journal of Materials Research
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    • v.32 no.11
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    • pp.474-480
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    • 2022
  • Lithium-ion batteries (LIBs) are powerful energy storage devices with several advantages, including high energy density, large voltage window, high cycling stability, and eco-friendliness. However, demand for ultrafast charge/discharge performance is increasing, and many improvements are needed in the electrode which contains the carbon-based active material. Among LIB electrode components, the conductive additive plays an important role, connecting the active materials and enhancing charge transfer within the electrode. This impacts electrical and ionic conductivity, electrical resistance, and the density of the electrode. Therefore, to increase ultrafast cycling performance by enhancing the electrical conductivity and density of the electrode, we complexed Ketjen black and graphene and applied conductive agents. This electrode, with the composite conductive additives, exhibited high electrical conductivity (12.11 S/cm), excellent high-rate performance (28.6 mAh/g at current density of 3,000 mA/g), and great long-term cycling stability at high current density (88.7 % after 500 cycles at current density of 3,000 mA/g). This excellent high-rate performance with cycling stability is attributed to the increased electrical conductivity, due to the increased amount of graphene, which has high intrinsic electrical conductivity, and the high density of the electrode.

A Study on the Effect of the Contact Electrode Slits in the Vacuum Interrupter with Axial Magnetic Field Type (종자계형 진공 인터럽터에서 접점전극 슬릿의 영향에 관한 연구)

  • 하덕용;강형부;최승길;최경호
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.15 no.9
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    • pp.822-829
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    • 2002
  • This paper deals with the distribution characteristics of the current density and axial magnetic flux density for each slits made on the contact electrode in the vacuum interrupter with axial magnetic field type using 3-dimension finite element analysis. It has been known that the presence of an axial magnetic field parallel to the current flow in the arc plasma can increase the high current breaking capacity of vacuum interrupter by carrying out the arc plasma from constricted mode to diffusion mode. The axial magnetic field is created of itself by current flow in the segments of coil electrode behind the contact electrode. The analyzed results show that if the slits are made in the contact electrode, they can increase the current density and axial magnetic flux density in the contact electrode surface and at the gap distance, which is due to decrease the effect of eddy currents flowing in the contact electrode. The phase shift due to eddy currents, defined 3s time difference between the maximum value of current and axial magnetic field, is decreased still more by increasing the number of slits made in the contact electrode at the center point of gap distance. These results demonstrate that 3-dimension finite element analysis has a great deal of merits in the development and evaluation of new electrode at the design of vacuum interrupter.

Effect of LiCoO2 Cathode Density and Thickness on Electrochemical Performance of Lithium-Ion Batteries

  • Choi, Jaecheol;Son, Bongki;Ryou, Myung-Hyun;Kim, Sang Hern;Ko, Jang Myoun;Lee, Yong Min
    • Journal of Electrochemical Science and Technology
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    • v.4 no.1
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    • pp.27-33
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    • 2013
  • The consequences of electrode density and thickness for electrochemical performance of lithium-ion cells are investigated using 2032-type coin half cells. While the cathode composition is maintained by 90:5:5 (wt.%) with $LiCoO_2$ active material, Super-P electric conductor and polyvinylidene fluoride polymeric binder, its density and thickness are independently controlled to 20, 35, 50 um and 1.5, 2.0, 2.5, 3.0, 3.5 g $cm^{-3}$, respectively, which are based on commercial lithium-ion battery cathode system. As the cathode thickness is increased in all densities, the rate capability and cycle life of lithium-ion cells become significantly worse. On the other hand, even though the cathode density shows similar behavior, its effect is not as high as the thickness in our experimental range. This trend is also investigated by cross-sectional morphology, porosity and electric conductivity of cathodes with different densities and thicknesses. This work suggests that the electrode density and thickness should be chosen properly and mentioned in detail in any kinds of research works.

Investigation of Spatial Distribution of Plasma Density between the Electrode and Lateral Wall of Narrow-gap CCP Source (좁은 간격 CCP 전원의 전극과 측면 벽 사이 플라즈마 분포)

  • Choi, Myung-Sun;Jang, Yunchang;Lee, Seok-Hwan;Kim, Gon-Ho
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.4
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    • pp.1-5
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    • 2014
  • The plasma density distribution in between the electrode and lateral wall of a narrow gap CCP was investigated. The plasma density distribution was obtained using single Langmuir probe, having two peaks of density distribution at the center of electrode and at the peripheral area of electrodes. The plasma density distribution was compared with the RF fluctuation of plasma potential taken from capacitive probe. Ionization reactions obtained from numerical analysis using CFD-$ACE^+$ fluid model based code. The peaks in two region for plasma density and voltage fluctuation have similar spatial distribution according to input power. It was found that plasma density distribution between the electrode and the lateral wall is closely related with the local ionization.

Study on the Electrode Characteristics for the Alkaline Water Electrolysis (알칼리 수전해용 전극에 관한 연구)

  • Choi, Ho-Sang;Yim, Doo-Soon;Rhyu, Cheol-Hwe;Kim, Jae-Chul;Hwang, Gab-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.23 no.2
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    • pp.117-124
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    • 2012
  • Alkaline electrolysis needs the electrode having a low overvoltage and good corrosion resistance in alkaline solution such as KOH and NaOH, for the oxygen and hydrogen production. The commercial materials such as SUS(stainless steel)-316, Ni and NiFe were evaluated for the electrode in alkaline electrolysis. The test solution for the alkaline electrolysis used 1~9M NaOH and 1~9M KOH. The voltage increased with an increase of current density in each solution. As for the 15wt.% (about 5M) NaOH, the voltage of the tested electrode under the current density of 1.8A/$cm^2$ showed the almost same value. The voltage over the current density of 1.8A/$cm^2$ deceased in the order: Ni${\fallingdotseq}$NiFe$cm^2$ showed the almost same value. The voltage over the current density of 1.8A/$cm^2$ deceased in the order: NiFe${\fallingdotseq}$SUS-316. From the results, it was estimated that NiFe and Ni was suitable as the electrode for the alkaline water electrolysis using NaOH and KOH electrolyte.

Influence of the Density Gradient on the Current of the Electrode Immersed in the Non-uniform Plasma (플라즈마 삽입전극의 전류에 미치는 밀도 구배의 영향)

  • Hwang, Hui-Dong;Gu, Chi-Wuk;Chung, Kyung-Jae;Choe, Jae-Myung;Kim, Gon-Ho;Ko, Kwang-Cheol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.24 no.6
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    • pp.504-509
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    • 2011
  • The conducting current of non-uniform plasma immersed electrode consists of ion current and secondary electron emission current caused by the impinging ion current. The ion current is determined by the ion dose passing through the sheath in front of electrode and the ion distribution in front of the electrode plays an important role in the secondary electron emission. The investigation of the distributed plasma and secondary electron effect on electrode ion current was carried out as the stainless steel electrode plugged with quartz tube was immersed in the inductively coupled Ar plasma using the antenna powered by 1 kw and the density profile was measured. After that, the negative voltage was applied by 1 kV~6 kV to measure the conduction current for the analysis of ion current.

Study of a High Energy Density Battery Using a 3D Sulfur Electrode (3D S 전극을 활용한 고에너지밀도 전지 연구)

  • Song, Da-in
    • New & Renewable Energy
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    • v.16 no.4
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    • pp.1-8
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    • 2020
  • The possibility of conversion to the RC-MAT propulsion system (gasoline engine → electric motor) was studied. However, as commercial battery capacities are low. it is not possible to change the propulsion system. Nevertheless, development of nex-generation batteries is necessary for high capacity and high energy density. Although Li/S batteries are theoretically suitable as new generation batteries, these batteries are not composed of only Li and S. Hence, ensuring high energy density can be difficult. Moreover, electrolytes are important components in the study of energy density; hence, the battery by Li2S8 Molarity was sorted. There are no studied on its various electrode components. In this study, a Li/S battery was fabricated using an assorted 3D sulfur electrode of high energy density and its electrochemical properties were studied. The Li/S battery has a high energy density of 468 Wh/kg at 1.28 M Li2S8 (A805-1.28). Its capacity rapidly decreased after 1 cycle with more than 1 M Li2S8.

The Effect of Compressing ER Electrode on Electrorheological Properties of Anhydrous ER Fluids (ER 유체용 압축전극이 ER 유체의 전기유변학적 특성에 미치는 영향)

  • Ahn, Byeng-Gil
    • Tribology and Lubricants
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    • v.18 no.1
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    • pp.16-23
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    • 2002
  • For increasing the yield stress of ER fluids, the compressing ER electrode was developed and the compressing electrorheological (ER) behavior of anhydrous ER fluids in silicone oil of phosphorous ester cellulose powder was investigated. Under constant electric field, not only the current density but also the yield stress of anhydrous ER fluids were studied as varying the compressing length of ER electrode distance. From the experimental results the compressing of ER electrode had a large influence to the ER properties of anhydrous ER fluids. The current density was proportional to the compressing length of ER electrode under constant electric field and volume fraction also tile compressing yield stress was proportional to the volume fraction of dispersed particles under constant electric field and compressing length. When the ER electrode was compressed with 150mm after charging the electric field, 4 kV, tile yield stress of phosphoric ester cellulose ER fluids increased to thirteen times comparing with the yield stress measured at normal electrode.