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Study on the Electrode Characteristics for the Alkaline Water Electrolysis

알칼리 수전해용 전극에 관한 연구

  • 최호상 (경일대학교 화학공학과) ;
  • 임두순 (호서대학교 일반대학원 그린에너지 공학과) ;
  • 유철휘 (호서대학교 일반대학원 그린에너지 공학과) ;
  • 김재철 (호서대학교 일반대학원 그린에너지 공학과) ;
  • 황갑진 (호서대학교 일반대학원 그린에너지 공학과)
  • Received : 2012.03.20
  • Accepted : 2012.04.27
  • Published : 2012.04.30

Abstract

Alkaline electrolysis needs the electrode having a low overvoltage and good corrosion resistance in alkaline solution such as KOH and NaOH, for the oxygen and hydrogen production. The commercial materials such as SUS(stainless steel)-316, Ni and NiFe were evaluated for the electrode in alkaline electrolysis. The test solution for the alkaline electrolysis used 1~9M NaOH and 1~9M KOH. The voltage increased with an increase of current density in each solution. As for the 15wt.% (about 5M) NaOH, the voltage of the tested electrode under the current density of 1.8A/$cm^2$ showed the almost same value. The voltage over the current density of 1.8A/$cm^2$ deceased in the order: Ni${\fallingdotseq}$NiFe$cm^2$ showed the almost same value. The voltage over the current density of 1.8A/$cm^2$ deceased in the order: NiFe${\fallingdotseq}$SUS-316. From the results, it was estimated that NiFe and Ni was suitable as the electrode for the alkaline water electrolysis using NaOH and KOH electrolyte.

Keywords

References

  1. 황갑진, 강경석, 한혜정, 김종욱, "특허분석에 의한 수전해 수소제조 기술동향", 한국수소 및 신에너지학회논문집, Vol. 18, No. 1, 2007, pp. 95-108.
  2. 김봉진, 김종욱, 고현민, "국내 저온 수전해 수소 생산의 경제성 평가", 한국수소 및 신에너지학회 논문집, Vol. 22, No. 4, 2011, pp. 559-567.
  3. 김종원, 최호상, 황갑진 등, "수소에너지", 아진출판사, 서울, 2005, pp. 15-106.
  4. M. J. Giz, M. C. Marengo, E. A. Ticianelli and E. R. Gonzalez, "Electrochemial and physical characterization of Ni-Cu-Fe alloy for chlor-alkali hydrogen cathodes", ECLETICA, 28(2), 2003, pp. 21-28. https://doi.org/10.1590/S0100-46702003000200003
  5. E. B. Catro, S. G. Real and L. F. Pinheiro Dick, "Electrochemical charaterization of porous nikelcobalt oxide electrodes", Int. J. Hydrogen Energy, 29, 2004, pp. 255-261. https://doi.org/10.1016/S0360-3199(03)00133-2
  6. Gab-Jin Hwang and Haruhiko Ohya, "Preparation of cation exchange membrane as a separator for the all-vanadium redox flow battery", J. Membr. Sci., 120, 1996, pp. 55-67. https://doi.org/10.1016/0376-7388(96)00135-4

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