• Title/Summary/Keyword: Electrochemical study

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Lithium Insertion Behavior of Nanoscopic Co3O4 Prepared with Avian Egg Membrane as a Template

  • Christy, Maria;Jisha, M.R;Kim, Ae-Rhan;Nahm, Kee-Suk;Yoo, Dong-Jin;Suh, E.K.;Kumari, T. Sri Devi;Kumar, T. Prem;Stephan, A. Manuel
    • Bulletin of the Korean Chemical Society
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    • v.32 no.4
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    • pp.1204-1208
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    • 2011
  • Nanoscopic $Co_3O_4$ particles were prepared using avian egg membrane as a template at $800^{\circ}C$. The prepared materials were subjected to XRD, SEM, TEM and Raman spectroscopic studies. Cyclic voltammetry study shows a single step oxidation and reduction process. Electrochemical lithium insertion behavior of the materials was examined in coin cells of the 2032 configuration. The material showed a discharge capacity 600mAh/g even after 20 cycles.

Enrichment of Electrochemically Active Bacteria Using a Three-Electrode Electrochemical Cell

  • Yoon, Seok-Min;Choi, Chang-Ho;Kim, Mi-A;Hyun, Moon-Sik;Shin, Sung-Hye;Yi, Dong-Heui;Kim, Hyung-Joon
    • Journal of Microbiology and Biotechnology
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    • v.17 no.1
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    • pp.110-115
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    • 2007
  • Electrochemically active bacteria were successfully enriched in an electrochemical cell using a positively poised working electrode. The positively poised working electrode (+0.7 V vs. Ag/AgCl) was used as an electron acceptor for enrichment and growth of electrochemically active bacteria. When activated sludge and synthetic wastewater were fed to the electrochemical cell, a gradual increase in amperometric current was observed. After a period of time in which the amperometric current was stabilized (generally 8 days), linear correlations between the amperometric signals from the electrochemical cell and added BOD (biochemical oxygen demand) concentrations were established. Cyclic voltammetry of the enriched electrode also showed prominent electrochemical activity. When the enriched electrodes were examined with electron microscopy and confocal scanning laser microscopy, a biofilm on the enriched electrode surface and bacterium-like particles were observed. These experimental results indicate that the electrochemical system in this study is a useful tool for the enrichment of an electrochemically active bacterial consortium and could be used as a novel microbial biosensor.

Potential Dependence of Electrochemical Etching Reaction of Si(111) Surface in a Fluoride Solution Studied by Electrochemical and Scanning Tunneling Microscopic Techniques

  • Bae, Sang-Eun;Youn, Young-Sang;Lee, Chi-Woo
    • Journal of Electrochemical Science and Technology
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    • v.11 no.4
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    • pp.330-335
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    • 2020
  • Silicon surface nanostructures, which can be easily prepared by electrochemical etching, have attracted considerable attention because of its useful physical properties that facilitate application in diverse fields. In this work, electrochemical and electrochemical-scanning tunneling microscopic (EC-STM) techniques were employed to study the evolution of surface morphology during the electrochemical etching of Si(111)-H in a fluoride solution. The results exhibited that silicon oxide of the Si(111) surface was entirely stripped and then the surface became hydrogen terminated, atomically flat, and anisotropic in the fluoride solution during chemical etching. At the potential more negative than the flat band one, the surface had a tendency to be eroded very slowly, whereas the steps of the terrace were not only etched quickly but the triangular pits also deepened on anodic potentials. These results provided information on the conditions required for the preparation of porous nanostructures on the Si(111) surface, which may be applicable for sensor (or device) preparation (Nanotechnology and Functional Materials for Engineers, Elsevier 2017, pp. 67-91).

Electrochemical Oxidation of Carbon Felt for Redox Flow Battery (Redox flow battery용 carbon felt 전극의 전기화학적 산화)

  • Jung, Young-Guan;Hwang, Gab-Jin;Kim, Jae-Chul;Ryu, Cheol-Hwi
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.721-727
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    • 2011
  • All vanadium redox-flow battery (VRFB) has been studied actively as one of the most promising electrochemical energy storage systems for a wide rage of applications such as electric vehicles, photovoltaic arrays, and excess power generated by electric power plants at night time. In this study, carbon felt electrodes were treated by electrochemical oxidation with KOH, and the cyclic voltammetry were studied in order to investigate redox reactivity of vanadium ion species with carbon felt electrodes. Besides the effect of electrochemical oxidation on the surface chemistry of carbon felt electrodes were investigated using the X-ray photoelectron spectroscopy (XPS). After electrochemical oxidation, XPS analysis of PAN based GF20-3 carbon felt electrode revealed on increase in the overall surface oxygen content of the carbon felts after electrochemical oxidation. Redox reaction characteristics using cyclic voltammetry (CV) were ascertained that the electrochemical treated electrode were more reversible than the untreated electrode.

Vibration Electrochemical Polishing (VECP) for Improved Surface Defects of Stainless Steel (스테인리스강의 표면 결점 개선을 위한 진동 전기화학 폴리싱)

  • Kim, Uk Su;Park, Jeong Woo
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.22 no.5
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    • pp.795-799
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    • 2013
  • This paper describes a novel hybrid surface polishing process combining non-traditional electrochemical polishing (ECP) with external artificial ultrasonic vibration. The purpose of this study is to develop an easier method for improving stainless steel surfaces. To this end, vibration electrochemical polishing (VECP), a novel ultrasonic manufacturing process, for enhancing electrochemical reaction and surface quality compared with that achieved using conventional ECP is suggested. In addition, for finding the optimized experimental conditions, the two methods are compared under various current densities. Localized roughness of the work material is measured with atomic force microscopy (AFM) and scanning electron microscopy (SEM) for obtaining detailed surface information.

Electrochemical Effectiveness Factors for Butler-Volmer Reaction Kinetics in Active Electrode Layers of Solid Oxide Fuel Cells

  • Nam, Jin Hyun
    • Journal of Electrochemical Science and Technology
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    • v.8 no.4
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    • pp.344-355
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    • 2017
  • In this study, a numerical approach is adopted to investigate the effectiveness factors for distributed electrochemical reactions in thin active reaction layers of solid oxide fuel cells (SOFCs), taking into account the Butler-Volmer reaction kinetics. The mathematical equations for the electrochemical reaction and charge conduction process were formulated by assuming that the active reaction layer has a small thickness, homogeneous microstructure, and high effective electronic conductivity. The effectiveness factor is defined as the ratio of the actual reaction rate (or equivalently, current generation rate) in the active reaction layer to the nominal reaction rate. From extensive numerical calculations, the effectiveness factors were obtained for various charge transfer coefficients of 0.3-0.8. These effectiveness data were then fitted to simple correlation equations, and the resulting correlation coefficients are presented along with estimated magnitude of error.

AFM based Surface Verifications of Pulse Electrochemical Polishing for Various Frequency Conditions (주파수 변화에 따른 AFM 기반의 펄스 전기화학 폴리싱 표면특성 분석)

  • Kim, Young-Bin;Kim, Jong-Tye;Ahn, Dong-Gyu;Park, Jong-Rak;Jeong, Sang-Hwa;Park, Jeong-Woo
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.21 no.2
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    • pp.246-251
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    • 2012
  • Pulse electrochemical polishing process has been used to improve mechanical properties such as surface roughness and corrosion resistance on conductive metallic materials. In addition, pulse electrochemical polishing process with various frequency may produce a lustrous, smoother, deburred and cleaned surface on workpiece. The aim of this paper is to study surface characteristics of pulse electrochemical polishing for various frequency conditions using AFM to verify localized surface variation in nanometer scale.

Nano Carbon Material Based Electrochemical Actuators (탄소 나노 재료 기반의 전기-화학적 구동기)

  • Cha, Ju-Young;Kang, In-Pil
    • Journal of the Korean Society for Precision Engineering
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    • v.28 no.11
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    • pp.1251-1258
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    • 2011
  • With the help of nanoscale materials like carbon nanotube (CNT), there is the potential to develop new actuators that will provide higher work per cycle than previous actuator technologies, and generate much higher mechanical strength. In this study, the electrochemical actuation characteristics of nano carbon materials were experimentally studied to develop electrochemical actuators. The electrochemical actuators were composed of aqueous NaCl electrolyte and their actuating electrodes were made of multi-walled carbon nanotube (MWCNT)/polystyrene composite and graphene respectably. Actuation is proportional to charging transfer rate, and the electrolysis with an AC voltage input has very complex characteristics. To quantify the actuation property, the strain responses and output model were studied based on electrochemical effects between the nano carbon films and the electrolyte.

A Study on the Electrochemical Hydrogenation Reaction Mechanism of the Laves Phase Hydrogen Storage Alloys (Laves phase계 수소저장합금의 전기화학적 수소화 반응 매카니즘에 관한 연구)

  • Lee, Ji-Youl;Kim, Chan-Jung;Kim, Dai-Ryong
    • Transactions of the Korean hydrogen and new energy society
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    • v.8 no.1
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    • pp.31-41
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    • 1997
  • In order to investigate the mechanism of electrochemical hydrogenation reaction on Zr-based Laves phase hydrogen storage alloy electrodes, electrochemical charge/discharge characteristics, potentiostatic/dynamic polarizations and electrocehmical impedance spectroscopy(EIS) of Zr-Ti-Mn-Ni and Zr-Ti-Mn-Ni-M(M=Fe, Co, Al) alloys were examined. Electrochemical discharge capacities of the alloys were quite different with gas charge capacities. Therefore, it was considered that discharge capacities of the alloys depend on electrochemical kinetic factors rather then thermodynamic ones. Discharge efficiencies were increased linearly with exchange current densities. The results of potentiostatic/dynamic polarization measurements showed that electrochemical charge and discharge reaction of Zr-based Laves phase hydrogen storage alloys is controlled by charge transfer process at the electrode surface. The EIS measurements also confirmed this result.

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Electrochemical Properties of PPy/CNT Electrodes Prepared by Chemical Process for Ultracapacitor

  • Shin, Jeong-Gyun;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
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    • v.10 no.2
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    • pp.141-144
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    • 2007
  • Polypyrrole(PPy) was composite with MWNT to attain cycle stable by chemical method. We have been considered PPy is the ideal material for high energy density electrochemical capacitor due to pseudo capacitor reaction. In this study we found that increase in cycle life due to composite MWNT. Also PPy/MWNT composite material have resulted larger capacitance and exhibits better electrochemical behavior. The structural feature was investigated by using SEM and TEM. The PPy/CNT composite is not only a promising ultracapacitor material for energy storages but also has a good possibility because of its great capacitive properties, simple preparation and low cost.