• Journal of Electrochemical Science and Technology
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• 제8권4호
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• pp.344-355
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• 2017

In this study, a numerical approach is adopted to investigate the effectiveness factors for distributed electrochemical reactions in thin active reaction layers of solid oxide fuel cells (SOFCs), taking into account the Butler-Volmer reaction kinetics. The mathematical equations for the electrochemical reaction and charge conduction process were formulated by assuming that the active reaction layer has a small thickness, homogeneous microstructure, and high effective electronic conductivity. The effectiveness factor is defined as the ratio of the actual reaction rate (or equivalently, current generation rate) in the active reaction layer to the nominal reaction rate. From extensive numerical calculations, the effectiveness factors were obtained for various charge transfer coefficients of 0.3-0.8. These effectiveness data were then fitted to simple correlation equations, and the resulting correlation coefficients are presented along with estimated magnitude of error.

• Journal of Electrochemical Science and Technology
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• 제11권3호
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• pp.195-219
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• 2020

Today, rechargeable lithium-ion batteries are an essential portion of modern daily life. As a promising alternative to traditional energy storage systems, they possess various advantages. This review attempts to provide the reader with an indepth understanding of the working mechanisms, current technological progress, and scientific challenges for a wide variety of lithium-ion battery (LIB) electrode nanomaterials. Electrochemical thermodynamics and kinetics are the two main perspectives underlying our introduction, which aims to provide an informative foundation for the rational design of electrode materials. Moreover, both anode and cathode materials are clarified into several types, using some specific examples to demonstrate both their advantages and shortcomings, and some improvements are suggested as well. In addition, we summarize some recent research progress in the rational design and synthesis of nanostructured anode and cathode materials, together with their corresponding electrochemical performances. Based on all these discussions, potential directions for further development of LIBs are summarized and presented.

• 대한화학회지
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• 제54권4호
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• pp.380-386
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• 2010

황산 용액에서 양극산화(anodization)에 의하여 생성되는 산화피막의 생성과정(growth kinetics)과 이 피막의 전기적 성질을 전기화학적 임피던스 측정법(electrochemical impedance spectroscopy)으로 조사하였다. 산화피막은 $Al_2O_3$로 점-결함 모형(point defect model)에 따라 성장하였으며, n-형 반도체의 전기적 성질을 보였다.

• Journal of Electrochemical Science and Technology
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• 제14권2호
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• pp.105-119
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• 2023

The electrochemical chlorine evolution reaction (CER) is an important electrochemical reaction and has been widely used in chlor-alkali electrolysis, on-site generation of ClO^-, and Cl₂-mediated electrosynthesis. Although precious metal-based mixed metal oxides (MMOs) have been used as CER catalysts for more than half a century, they intrinsically suffer from a selectivity problem between the CER and parasitic oxygen evolution reaction (OER). Hence, the design of selective CER electrocatalysts is critically important. In this review, we provide an overview of the fundamental issues related to the electrocatalysis of the CER and design strategies for selective CER electrocatalysts. We present experimental and theoretical methods for assessing the active sites of MMO catalysts and the origin of the scaling relationship between the CER and the OER. We discuss kinetic analysis methods to understand the kinetics and mechanisms of CER. Next, we summarize the design strategies for new CER electrocatalysts that can enhance the reactivity of MMO-based catalysts and overcome their scaling relationship, which include the doping of MMO catalysts with foreign metals and the development of non-precious metal-based catalysts and atomically dispersed metal catalysts.

• 전기화학회지
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• 제3권2호
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• pp.96-99
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• 2000

리튬 망간 산화물 박막의 고율 방전 특성을 향상시키기 위하여 사진 식각 법을 이용하여 미세 패턴된 양극 박막을 제조하였다. 방전 전류 밀도를 달리하여 측정한 결과, 리튬 이온의 intercalations kinetic레 관계하는 전하 전달 저항 값이 감소하게 되어 고율 방전 특성이 향상되었다.

• The Korean Journal of Ceramics
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• 제4권2호
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• pp.61-67
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• 1998

The significance of point defects as relevant centers concerning electrochemical function is highlighted. Starting from the most simple case of dilute equilibrium bulk defect chemistry, influence of defect interaction and in particular the impact of interfaces on point defect redistribution are considered. Then recent progress in the field of kinetics in bulk and at boundaries is discussed. Finally, selected applications with emphasis on battery and sensor technology are presented.

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 1999년도 제3회 총회 및 추계학술발표회
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• pp.58-58
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• 1999

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 1998년도 제1회 총회 및 추계학술발표회
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• pp.95-95
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• 1998

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2001년도 춘계총회 및 학술발표회
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• pp.32-32
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• 2001

• 한국전기화학회:학술대회논문집
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• 한국전기화학회 2004년도 춘계총회 및 학술발표회
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• pp.8-8
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• 2004