• Title/Summary/Keyword: Electro-Oxidation

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The Investigation of Electro-Oxidation of Methanol on Pt-Ru Electrode Surfaces by in-situ Raman Spectroscopy

  • She, Chun-Xing;Xiang, Juann;Ren, Bin;Zhong, Qi-Ling;Wang, Xiao-Cong;Tian, Zhong-Qun
    • Journal of the Korean Electrochemical Society
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    • v.5 no.4
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    • pp.221-225
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    • 2002
  • Assisted by the highly sensitive confocal microprobe Raman spectrometer and proper surface roughening procedure, the Raman investigation on the adsorption and reaction of methanol was performed on Pt-Ru electrodes with different coverages. A detailed description of the roughening process of the Pt electrodes and the underpotential deposition of the Ru was given. Reasonably good Raman signal reflecting the metal-carbon vibration and CO vibration was detected. The appearance of vibrations of the Ru oxides, together with the existence of Ru-C, Pt-C and CO bands, clearly demonstrates the participation of the bi-functional mechanism during the oxidation process of methanol on Pt-Ru electrodes. The Pt-Ru electrode was found to have a higher catalytic activity over Pt electrodes. This preliminary study shows that electrochemical Raman spectroscopy can be applied to the study of rough electrode surface.

Characterization of Electro-Polymerized Polyaniline Film on the Cold Rolled Sheet in the Oxalic acid and Sodium Molybdate Electrolyte (옥살산과 몰리브덴산나트륨 전해액에서 냉연강판에 전해중합된 폴리아닐린 피막의 특성)

  • Lim, Ki-Young;Yoon, Jeong-Mo;Ki, Joon-Seo;Jang, Yong-Seok
    • Korean Journal of Materials Research
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    • v.16 no.6
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    • pp.386-393
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    • 2006
  • Increasing environmental concerns require to solve the problem produced due to the use of heavy metals in coating formulations. Therefore, it is necessary to develop new coating strategy employing inherently conducting polymers such as polyaniline. Polyaniline is a conductive polymer that is synthesized by oxidation polymerization, and the electrochemical and chemical polymerization are possible for the oxidation of aniline. Electrochemical oxidation polymerization produces a fine surface and although voltage control is more convenient, it require electrolytic cells, and elaborate thin film can be acquired with the polymerization. Polyaniline films were electro-polymerized on cold rolled sheets using the galvanostat mode in the oxalic acidaniline-sodium molybdate electrolyte. The structure and properties of polyaniline film were studied using Potentiostat/Galvanostat 263A, FE-SEM,, AFM, SST, Colorimetry. A high corrosion resistance of polyaniline film was observed with an increase of corrosion potential by $500{\sim}600$ mV for the substrate covered with polyaniline.

Electro-catalytic Performance of PtRu Catalysts Supported on Urea-treated MWNTs for Methanol Oxidation

  • Park, Jeong-Min;Park, Soo-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.159-159
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    • 2009
  • In this work, nitrogen and oxygen functionalities was introduced to the graphite nanofibers (GNFs) and their effect on electrocatalytic performance of the GNF supports for direct methanol fuel cells (DMFCs) was invesigated. The nitrogen and oxygen groups were introduced through the urea treatments and acid treatment, respectively. And, PtRu catalysts deposited on modified GNFs were prepared by a chemical reduction method. The catalysts were characterized by means of elemental analysis, nitrogen adsorption, and X-ray photoelectron spetroscopy (XPS). The structure and morphological characteristics of the catalysts were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). As a result, the Pt-Ru nanoparticles were impregnated on GNFs with good formation in 3-5 nm. And, the cyclic voltammograms for methanol oxidation revealed that the methanol oxidation peak varied depending on changes of surface functional groups. It was thus considered that the PtRu deposition was related to the reduction of PtRu and surface characteristics of the carbon supports. The changes of surface functional groups were related to PtRu reduction, significantly affect the methanol oxidation activity of anode electrocatalysts in DMFCs.

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Electrochemical Degradation of Phenol by Electro-Fenton Process (전기-펜톤 공정에 의한 페놀의 전기화학적 분해)

  • Kim, Dong-Seog;Park, Young-Seek
    • Journal of Environmental Health Sciences
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    • v.35 no.3
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    • pp.201-208
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    • 2009
  • Oxidation of phenol in aqueous media by electro-Fenton process using Ru-Sn-Sb/graphite electrode has been studied. Hydrogen peroxide was electrically generated by reaction of dissolved oxygen in acidic solutions containing supporting electrolyte and $Fe^{2+}$ was added in aqueous media. Phenol degradation experiments were performed in the presence of electrolyte media at pH 3. Effect of operating parameters such as current, electrolyte type (NaCl, KCl and $Na_2SO_4$) and concentration, $Fe^{2+}$ concentration, air flow rate and phenol concentration were investigated to find the best experimental conditions for achieving overall phenol removal. Results showed that current of 2 A, NaCl electrolyte concentration of 2g/l, 0.5M concentration of $Fe^{2+}$, air flow rate of 1l/min were the best conditions for mineralization of the phenol by electro-Fenton.

Formation and Properties of Electroplating Copper Pillar Tin Bump (구리기둥주석범프의 전해도금 형성과 특성)

  • Soh, Dea-Wha
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.16 no.4
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    • pp.759-764
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    • 2012
  • Copper Pillar Tin Bump (CPTB) was investigated for high density chip interconnect technology development, which was prepared by electroplating and electro-less plating methods. Copper pillar tin bumps that have $100{\mu}m$ pitch were introduced with fabrication process using a KM-1250 dry film photoresist (DFR), with copper electroplating for Copper Pillar Bump (CPB) formation firstly, and then tin electro-less plating on it for control oxidation. Electric resistivity and mechanical shear strength measurements were introduced to characterize the oxidation effects and bonding process as a function of thermo-compression. Electrical resistivity increased with increasing oxidation thickness, and shear strength had maximum value with $330^{\circ}C$ and 500 N at thermo-compression process. Through the simulation work, it was proved that the CPTB decreased in its size of conduction area as time passes, however it was largely affected by the copper oxidation.

Formation and Properties of Electroplating Copper Pillar Tin Bump on Semiconductor Process (반도체공정에서 구리기둥주석범프의 전해도금 형성과 특성)

  • Wang, Li;Jung, One-Chul;Cho, Il-Hwan;Hong, Sang-Jeen;Hwang, Jae-Ryong;Soh, Dea-Wha
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2010.10a
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    • pp.726-729
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    • 2010
  • Copper Pillar Tin Bump (CPTB) was investigated for high density chip interconnect technology development, which was prepared by electroplating and electro-less plating methods. Copper pillar tin bumps that have $100{\mu}m$ pitch were introduced with fabrication process using a KM-1250 dry film photoresist (DFR), with copper electroplating for Copper Pillar Bump (CPB) formation firstly, and then tin electro-less plating on it for control oxidation. Electric resistivity and mechanical shear strength measurements were introduced to characterize the oxidation effects and bonding process as a function of thermo-compression. Electrical resistivity increased with increasing oxidation thickness, and shear strength had maximum value with $330^{\circ}C$ and 500 N thermo-compression process. Through the simulation work, it was proved that when the CPTB decreased in its size, it was largely affected by the copper oxidation.

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Electro-oxidation Kinetics of Cerium(III) in Nitric Acid Using Divided Electrochemical Cell for Application in the Mediated Electrochemical Oxidation of Phenol

  • Matheswaran, Manickam;Balaji, Subramanian;Chung, Sang-Joon;Moon, Il-Shik
    • Bulletin of the Korean Chemical Society
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    • v.28 no.8
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    • pp.1329-1334
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    • 2007
  • The electrochemical oxidation of cerium(III) was carried out using divided and undivided electrochemical cells in nitric acid medium. It was found that divided cell with Nafion 324 as the separator gave good conversion yield with high current efficiency compared to the undivided cell. The efficiency of the divided electrochemical cell was further optimized in terms of cell voltage, temperature, flow rate of solution recirculation, concentrations of Ce(III) and nitric acid. The better conditions for 1 M Ce(III) in 3 M nitric acid were found to be 2.5 V, 363 K and 100 mL/min recirculation flow rate based on the current efficiency under the experimental conditions investigated. The Ce(IV) oxidant produced was used as a mediator for the mineralization of phenol. The mineralization efficiency of the cerium mediated electrochemical oxidation was found rapid and higher compared to the direct electrochemical oxidation based on CO2 evolution under the same conditions.

Studies on Enhanced Oxidation of Estrone and Its Voltammetric Determination at Carbon Paste Electrode in the Presence of Cetyltrimethylammonium Bromide

  • Yang, Chunhai;Xie, Pingping
    • Bulletin of the Korean Chemical Society
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    • v.28 no.10
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    • pp.1729-1734
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    • 2007
  • The electrochemical behaviors of estrone in the presence of various surfactants were examined with great details. It is found that a cationic surfactant, cetyltrimethylammonium bromide (CTAB), obviously facilitates the electro-oxidation of estrone at carbon paste electrode (CPE) from the significant peak current enhancement and the negative shift of peak potential. Additionally, chronocoulometry and electrochemical impedance spectroscopy (EIS) were also used for further investigation of the electrode process of estrone, indicating that low concentration of CTAB exhibits excellent enhancement effects on the electrochemical oxidation of estrone, greatly enhances the diffusion coefficient and the electron transfer rate. Based on this, an electrochemical method was proposed for the determination of estrone. The oxidation peak current is proportional to the concentration of estrone in the ranges over 9.0 × 10?8 - 8.0 × 10?6 mol/L, and a low detection limit of 4.0 × 10?8 mol/L was obtained for 180s accumulation at open circuit (S/N = 3). Finally, this proposed method was demonstrated using estrone tablets with good satisfaction.

An Electro-Fenton System Using Magnetite Coated One-body Catalyst as an Electrode (일체형 산화철 촉매를 전극으로 하는 전기펜톤산화법)

  • Choe, Yun Jeong;Ju, Jeh Beck;Kim, Sang Hoon
    • Applied Chemistry for Engineering
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    • v.29 no.1
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    • pp.117-121
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    • 2018
  • A stainless steel mesh was applied to the cathode of an electro-Fenton system. Methylene blue (MB) solution was chosen as the model waste water with non-biodegradable pollutants. For the model waste water, the degradation efficiency was compared among various SUS mesh cathodes with different surface treatments and magnetite coatings on them. With increasing amount of the magnetite coating on SUS mesh, the degradation efficiency also increased. The improved electro-catalytic characteristic was explained by the increased amount of in situ generated hydrogen peroxide near the cathode surface. Cyclic voltammetry data also showed improved electro-catalytic performance for SUS mesh with more magnetite coatings on them.