• Title/Summary/Keyword: Electro-Chemical Process

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RECENT DEVELOPMENTS OF MEMBRANE TECHNOLOGY IN JAPAN

  • Kimura, Shoji
    • Proceedings of the Membrane Society of Korea Conference
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    • 1991.04a
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    • pp.10-12
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    • 1991
  • The first membrane technology applied in the Japanese industry was a. electro-dialysis(ED) process using ion-exchange meabranes. These membranes were first developed in early 50ties and the Japanese government decided to use this method for concentration of sea water to produce salt, which was then produced by solar evaporation. This development program started from 1960 by the Japan monopoly Coop. (at that time). To apply ED process for sea-water concentrat ion it was necessary to develop ion-exchange membranes having very low electric resistance to avoid energy loss due to Joule heat, and those having selectivity to permeate single valent ions only to avoid scale formation in the ED stacks. These Japanese companies, Asahi Glass, Asahi Chemical and Tokuyama Soda, have succeeded to develop such membranes, and until 1971 all of the seven salt manufacturing companies had adopted ED for production of food salt.

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Fabrication and Characterization of Composite LSCF-Ag Cathode for Solid Oxide Fuel Cells using Electron Beam Irradiation Process

  • Kang, Hyun Suk;Jung, Yung-Min;Song, Rak-Hyun;Peck, Dong-Hyun;Park, ChangMoon;Lee, Byung Cheol
    • Bulletin of the Korean Chemical Society
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    • v.35 no.10
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    • pp.2969-2973
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    • 2014
  • A new process to fabricate a composite LSCF-Ag cathode material for SOFCs by electron beam (e-beam) irradiation process has been suggested for operation under intermediate temperature range of $600-700^{\circ}C$. A composite LSCF-Ag cathode with uniformly coated Ag nanoparticles on the surface of the LSCF material was prepared by a facile e-beam irradiation method at room temperature. The morphology of the composite LSCF-Ag material was analyzed using a TEM, FE-SEM, and EDS. The prepared composite LSCF-Ag material can play a significant role in increasing the electro-catalytic activities and reducing the operating temperature of SOFCs. The performance of a tubular single cell prepared using the composite LSCF-Ag cathode, YSZ electrolyte and a Ni/YSZ anode was evaluated at reduced operating temperature of $600-700^{\circ}C$. The micro-structure and chemical composition of the single cell were investigated using a FE-SEM and EDS.

Study on Scale-up of Electro-Electrodialysis [EED] Cell for HI Concentration (HI 농축을 위한 전해-전기투석 셀의 스케일-업에 관한 연구)

  • Lee, Sang-Ho;Hong, Seong-Dae;Kim, Jeong-Keun;Hwang, Gab-Jin;Moon, Il-Sik
    • Journal of Hydrogen and New Energy
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    • v.18 no.4
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    • pp.458-463
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    • 2007
  • An experimental study on scale-up of Electro-electrodialysis(EED) to increase the efficiency of HI decomposition section in the IS(Iodine-Sulfur) process was carried out. The EED stack extends the effective area of the membrane to 20 times of that formerly used in a single EED unit cell. The experiment was carried out using HIx solution($HI:H_2O:I_2=1:8.4{\sim}9:1.85{\sim}1.9$) at $100^{\circ}C$ and various solution flow rates of 20, 30, 40 and 50 cc/min. The increased HI molality in catholyte after one-pass throughout from the EED stack was 3 mol/kg-$H_2O$, 2.2 mol/kg-$H_2O$, 2 mol/kg-$H_2O$ and 1.37 mol/kg-$H_2O$ at 20, 30, 40 and 50 cc/min, respectively. These values satisfied the target of HI molality(the increase of HI molality: 2 mol/kg-$H_2O$) in the IS process for hydrogen production of 20 L/hr.

Nuclear Design Methodology of Fission Moly Target for Research Reactor

  • Cho, Dong-Keun;Kim, Myung-Hyun;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • v.31 no.4
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    • pp.365-374
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    • 1999
  • A nuclear design of fission moly production targets for a research reactor, HANARO was peformed. It was found that the use of MCNP-4A, ORIGEN-2 code was reliable for the analysis of production characteristics of $^{99}$ Mo in a target fuel at an irradiation holes. A parametric study was done for the optimization of target location, target dimension, target shape and fuel materials. It was shown that a fuel thickness was the most sensitive parameters and electro-deposited target gave the highest 99Mo yield ratio. A pellet target with vibro-compaction powder, however, showed the largest production capacity and better engineering feasibility even with less yield ratio. Ten kinds of optimized target design for both LEU and HEU satisfied all the given design constraints. The most favorable design was the HEU ring-shaped electro-deposited target, considered the safety limit, production yield, chemical process easiness, yield ratio, and amount of radioactive waste.

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Mechanical properties of electro gas welds with different discharge amount of slag (용접 슬래그 배출량에 따른 Electro Gas 용접부의 기계적 특성 변화)

  • Goo, Yeon-Baeg;Sung, Hee-Joon;Kim, Kyeong-Ju
    • Proceedings of the KWS Conference
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    • 2010.05a
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    • pp.26-26
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    • 2010
  • EGW process has been applied to joining of ship block with vertical-up position at high production rate. The workability of EGW, however, has been interrupted by too much slag production. Two electrodes EGW showed more severe workability than that of one electrode EGW. Therefore, to understand the effect of discharge amount of EGW slag on workability and mechanical properties, two different slag discharge amount have been controlled at the same welding conditions. The results are as follows; 1) Workability has been improved by any additional slag discharge. 2) Mechanical properties have been deteriorated with any additional slag discharge. 3) Chemical compositions of weld metal have been changed by any additional slag discharge.

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Simplified Design and Optimization of Slotless Brushless DC Machine for Micro-Satellites Electro-Mechanical Batteries

  • Abdi, Babak;Bahrami, Hamid;Mirtalaei, S.M.M.
    • Journal of Electrical Engineering and Technology
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    • v.8 no.1
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    • pp.124-129
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    • 2013
  • Electro-Mechanical Batteries have important advantages compared with chemical batteries, especially in Low Earth Orbit satellites applications. High speed, slotless, external rotor, brushless DC machines are proposed and used in these systems as Motor/Generator. A simplified analytic design method is given for this type of machines and, the optimization of machine in order to have maximum efficiency and minimum volume and weight are given in this paper. Particle swarm optimization (PSO) is used as the optimization algorithm and the finite element-based simulations are used to confirm the design and optimization process and show less than 6% error in parametric design.

A Study on the Aged Landfill Leachate Treatment with Electrolysis (전기분해공법을 이용한 고령화된 매립장 침출수 처리에 관한 연구)

  • Chung Soon-Hyung;Lee Young-Sei;Choi Hyun-Kuk;Choi Joon-Ho
    • Journal of environmental and Sanitary engineering
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    • v.20 no.1 s.55
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    • pp.32-39
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    • 2005
  • Recently, sanitary landfill was one of the most widely used for disposal of waste in Korea. With increasing of use and public awareness of this method for disposal. there is an increased concern with respect to the pollution potential by the landfill leachate. Especially, an aged landfill leachate contained relatively large amount of the nonbiodegradable substances which could not be removed by biological treatment processes. So, this study was conducted to the removal of nonbiodegradable substances, such as Humic acid and Fulvic acid with the electrolysis. In this study, electrode materials, electrolyte concentration, electrode distance, current density, and pH value were found to have significant effect on both pollutant removal efficiency and current efficiency in electrochemical oxidation process.

Phase Separated Structure and Electro-optical Properties of the (Polymer/Liquid Crystal) Composite Films ((고분자/액정) 복합막의 상분리구조와 전기광학 특성)

  • Park, K.S.;Noh, C.H.;SaKong, D.S.;Nam, K.D.;Kajiyama, T.
    • Journal of the Korean Applied Science and Technology
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    • v.12 no.2
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    • pp.29-39
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    • 1995
  • The phase separated structure and the electro-optical properties of the (polymer/liquid) crystal : LC) composite film strongly depended on the weight fraction of LC in it. The continuous LC phase was formed in a three-dimensional polymer network when the LC weight fraction was above 40wt%. The aggregation structure of the composite film could be controlled by controlling the solvent evaporation velocity during the film preparation process. The smaller LC domains or channels were formed in the case of the faster solvent evaporation velocity. The composite film exhibited reversible light scattering-light transmission switching upon electric field -OFF and -ON states, respectiverly. The light scattering properties of the composite film strongly depended on the spatial distortion of the nematic directors as well as the mismatch in refractive indices between matrix polymer and LC.

Fabrication of Metallic Nano-Filter Using UV-Imprinting Process (UV 임프린팅 공정을 이용한 금속막 필터제작)

  • Noh Cheol Yong;Lee Namseok;Lim Jiseok;Kim Seok-min;Kang Shinill
    • Transactions of Materials Processing
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    • v.14 no.5 s.77
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    • pp.473-476
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    • 2005
  • The demand of on-chip total analyzing system with MEMS (micro electro mechanical system) bio/chemical sensor is rapidly increasing. In on-chip total analyzing system, to detect the bio/chemical products with submicron feature size, a filtration system with nano-filter is required. One of the conventional methods to fabricate nano-filter is to use direct patterning or RIE (reactive ion etching). However, those procedures are very costly and are not suitable fur mass production. In this study, we suggested new fabrication method for a nano-filter based on replication process, which is simple and low cost process. After the Si master was fabricated by laser interference lithography and reactive ion etching process, the polymeric mold was replicated by UV-imprint process. Metallic nano-filter was fabricated after removing the polymeric part of metal deposited polymeric mold. Finally, our fabrication method was applied to metallic nano-filter with $1{\mu}m$ pitch size and $0.4{\mu}m$ hole size for bacteria sensor application.

Study on the Synthesis of Alumina Membrane by Anodization in Sulfuric Acid (황산전해액에서 양극산화에 의한 알루미나 막 제조에 관한 연구)

  • Kim, Hyun;Chang, Yoon Ho;Hahm, Yeong Min
    • Applied Chemistry for Engineering
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    • v.8 no.5
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    • pp.756-762
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    • 1997
  • The experiment was carried out to fabricate alumina membrane which has a cylindrical pore structure by anodizing aluminium plate in sulfuric acid solution with the electrochemical technique. The aluminium plate for anodizing was prepared by the pretreatment process such as chemical, electro-polishing and thermal treatment. The pore size distribution and the film thickness of alumina membrane were investigated by the implementation of scanning electron microscope(SEM) and BET method. The results show that the oxide film has a geometrical structures like a Keller model and that the membrane has a uniform pore distribution. The pore size and the oxide film thickness are dependent on the anodizing process variables such as the electrolyte concentration, the reation temperature and the anodizing current density.

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