• 센서학회지
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• 제32권5호
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• pp.290-294
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• 2023

Among various types of harmful gases, hydrogen sulfide is a strong toxic gas that is mainly generated during spillage and wastewater treatment at industrial sites. Hydrogen sulfide can irritate the conjunctiva even at low concentrations of less than 10 ppm, cause coughing, paralysis of smell and respiratory failure at a concentration of 100 ppm, and coma and permanent brain loss at concentrations above 1000 ppm. Therefore, rapid detection of hydrogen sulfide among harmful gases is extremely important for our safety, health, and comfortable living environment. Most hydrogen sulfide gas sensors that have been reported are electrical resistive metal oxide-based semiconductor gas sensors that are easy to manufacture and mass-produce and have the advantage of high sensitivity; however, they have low gas selectivity. In contrast, the electrochemical sensor measures the concentration of hydrogen sulfide using an electrochemical reaction between hydrogen sulfide, an electrode, and an electrolyte. Electrochemical sensors have various advantages, including sensitivity, selectivity, fast response time, and the ability to measure room temperature. However, most electrochemical hydrogen sulfide gas sensors depend on imports. Although domestic technologies and products exist, more research is required on their long-term stability and reliability. Therefore, this study includes the processes from electrode material synthesis to sensor fabrication and characteristic evaluation, and introduces the sensor structure design and material selection to improve the sensitivity and selectivity of the sensor. A sensor case was fabricated using a 3D printer, and an Ag reference electrode, and a Pt counter electrode were deposited and applied to a Polytetrafluoroethylene (PTFE) filter using PVD. The working electrode was also deposited on a PTFE filter using vacuum filtration, and an electrochemical hydrogen sulfide gas sensor capable of measuring concentrations as low as 0.6 ppm was developed.

• Journal of the Korean Wood Science and Technology
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• 제52권1호
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• pp.1-12
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• 2024

Betung bamboo (Dendrocalamus asper) is used as a building and handicraft material in Indonesia; however, bamboo needs to be dried to increase its stability. This study aimed to evaluate the efficiency of drying bamboo using solar energy and different drying oven designs. The betung bamboo pieces were dried using a direct solar dryer (direct drying) and an indirect solar dryer (indirect drying) and then the decrease in levels that occurred based on the relative humidity (RH) and temperature values achieved in the two dryers were compared. The highest average temperature in the direct indirect drying oven compartment was 60.1 ± 13.1℃ with 19.9 ± 16.4% RH and 60.2 ± 11.9℃ with 19.5 ± 15.5% RH, respectively. The drying defect in indirect drying was lower than that in direct drying, and indirect drying had a 61.7% greater average water loss than direct drying with significant difference (95%, analysis of variance) based on water loss/compartment volume parameters. Thus, the solar drying oven can be used to air-dry bamboo (14%) for 7 d from an initial moisture content of 70%-80% in bamboo strips. The results of this research can be used for small-scale bamboo processing industries that have limited use of electrical energy with quite good results.

• Current Photovoltaic Research
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• 제12권1호
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• pp.1-5
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• 2024

Perovskite solar cells have exhibited a remarkable increase in efficiency from an initial 3.8% to 26.1%, marking a significant advancement. However, challenges persist in the commercialization of perovskite solar cells due to their low stability with respect to humidity, light exposure, and temperature. Moreover, the instability of the organic charge transport layer underscores the need for exploring inorganic alternatives. In the manufacturing process of the perovskite solar cells' oxide charge transport layer, ultraviolet-ozone (UVO) treatment is commonly applied to enhance the wettability of the perovskite solution. The UVO treatment on metal oxides has proven effective in suppressing surface oxygen vacancies and removing surface organic contaminants. This study focused on the characterization of nickel oxide as the hole transport material in perovskite solar cells, specifically investigating the impact of UVO treatment on film properties. Through this analysis, changes induced by the UVO treatment were observed, and consequent alterations in the device characteristics were identified.

• 한국군사과학기술학회지
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• 제27권1호
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• pp.43-50
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• 2024

Large planar military antenna boasts a range of electrical components, including TRA(Transmit-Receive Assembly), signal processors, etc. which engage in computations and calculations. These processes generate a significant amount of heat, leading to unforeseen consequences for the equipment. To mitigate these adverse effects, it's imperative to implement a cooling system that can effectively reduce heat-related issues. Given the antenna's intricate nature and the multitude of components it houses, a two-step estimation process is necessary. The first step involves a comprehensive model calculation to determine the total flow characteristics, while the second step entails a thermal analysis of individual TRA set. In this study, we depicted an antenna set using simplified 3D models of its components, considering their material and thermal properties. The sequential analysis process facilitated the calculation of branched flow rates, providing insights into the individual TRA. This approach also allowed us to design a cooling system for the TRA set, assessing its thermal stability in high-temperature environments. To ensure the optimal performance of TRA, breaking down the analysis into stages based on the cooling system's structure can assist operators in predicting numerical results more effectively.

• Journal of Electrochemical Science and Technology
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• 제15권3호
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• pp.321-344
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• 2024

Transition metal compounds (TMCs) are being researched as promising electrode materials for electrochemical energy storage devices (supercapacitors). Among TMCs, transition metal phosphates (TMPs) have good, layered structures owing to open framework and protonic exchange capability among different layers, good surface area due to engrossed porosity, rich active redox reaction sites owing to octahedral structure and variable valance metallic ions. Hence TMPs become more ideal for supercapacitor electrode materials compared to other TMCs. However, TMPs have got some issues like low conductivity, rate performance, stability, energy, and power densities. But these problems can be addressed by making their composites with carbonaceous materials, e.g., carbon nanotubes (CNTs), graphene oxide (GO), graphitic carbon (GC), etc. A few factors like high surface area, excellent electrical conductivity of carbon materials and variable valence metal ions in TMPs caused great enhancement in their electrochemical performance. This article tries to discuss and compare the published data, majorly in last decade, regarding the electrochemical energy storage potential of pristine unary, binary, and ternary TMPs and their hybrid composites with carbonaceous materials (CNTs, GOs/rGOs, GC, etc.). The electrochemical performance of the hybrids has been reported to be higher than the pristine counterparts. It is hoped that the current review will open a new gateway to study and explore the high performance TMPs based supercapacitor materials.

• Nuclear Engineering and Technology
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• 제56권5호
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• pp.1584-1602
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• 2024

It is vital to output the required electrical power following various task requirements when the space reactor power supply is operating in orbit. The dynamic performance of the closed Brayton cycle thermoelectric conversion system is initially studied and analyzed. Based on this, a load tracking power regulation method is developed for the liquid metal cooled space reactor power system, which takes into account the inlet temperature of the lithium on the hot side of the intermediate heat exchanger, the filling quantity of helium and xenon, and the input amount of the heat pipe radiator module. After comparing several methods, a power regulation method with fast response speed and strong system stability is obtained. Under various changes in power output, the dynamic response characteristics of the ultra-small liquid metal lithium-cooled space reactor concept scheme are analyzed. The transient operation process of 70 % load power shows that core power variation is within 30 % and core coolant temperature can operate at the set safety temperature. The second loop's helium-xenon working fluid has a 65K temperature change range and a 25 % filling quantity. The lithium at the radiator loop outlet changes by less than ±7 K, and the system's main key parameters change as expected, indicating safety. The core system uses less power during 30 % load power transient operation. According to the response characteristics of various system parameters, under low power operation conditions, the lithium working fluid temperature of the radiator circuit and the high-temperature heat pipe operation temperature are limiting conditions for low-power operation, and multiple system parameters must be coordinated to ensure that the radiator system does not condense the lithium working fluid and the heat pipe.

• 한국인터넷방송통신학회논문지
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• 제24권4호
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• pp.141-146
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• 2024

기존의 화석연료와 발전기를 통하여 에너지를 생산하고 즉시 소모하던 방식에서 에너지를 저장하고 효율적으로 생산하고 이용하기 위한 에너지저장장치(ESS, Energy Storage System)가 개발되었다[1]. 이러한 에너지저장장치에 현재까지 2차전지 리튬이온(Li-ion) 배터리를 가장 많이 사용하고 있다. 따라서 리튬이온 배터리의 성능, 수명, 안전성을 향상시키기 위하여 셀(Cell) 단위로 관리하는 BMS(Battery Management System)의 역할이 매우 중요하다[2]. 특히 BMS의 기능 중 셀 간의 불균형 전압을 균형적으로 맞추는 셀 밸런싱(Cell Balancing) 기법은 에너지저장장치에서 배터리의 최적화를 도모할 수 있다. 이러한 최적화를 통해 모든 셀이 동일한 전압과 용량을 유지하여 성능향상, 출력 안정성을 유지할 수 있다[3]. 따라서 본 논문에서는 셀 간의 불균형이 발생한 리튬이온 배터리를 충전할 때 BMS의 기능 중 하나인 셀 밸런싱 기법의 동작 특성에 대하여 살펴보고자 한다.

• 청정기술
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• 제30권3호
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• pp.258-266
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• 2024

Rechargeable Li-SnO₂ batteries suffer from issues such as poor electronic/ionic conductivity and huge volume changes. In order to overcome these inherent limitations, this study designed a cell with a unique hierarchical structure, denoted as SnO₂@PCNF. The SnO₂@PCNF cell design incorporates in-situ generated SnO₂ nanoparticles strategically positioned within N-doped porous carbon nanofibers (PCNF). The in-situ generated SnO₂ nanoparticles can alleviate strains during cycling and shorten the pathway for the ions and electrons, improving the utilization of active materials. Moreover, the N-doped PCNF establishes a continuously conductive network to further increase the electrical conductivity and also buffers the significant volume changes that occur during charging and discharging. The resulting SnO₂@PCNF cell exhibits outstanding electrochemical performance and stable cycling characteristics. Notably, a reversible capacity of 520 mAh g^-1 was achieved after 100 cycles at 70 mA g^-1. Even under a higher current density of 1 A g^-1, the cell maintained a capacity retention of 393 mAh g^-1 after 1,000 cycles. These results highlight the SnO₂@PCNF cell's exceptional cycling stability and superior rate capability.

• 한국재료학회지
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• 제22권2호
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• pp.61-65
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• 2012

A $Li_2O-2SiO_2$ ($LS_2$) glass was investigated as a lithium-ion conducting oxide glass, which is applicable to a fast ionic conductor even at low temperature due to its high mechanical strength and chemical stability. The $Li_2O-2SiO_2$ glass is likely to be broken into small pieces when quenched; thus, it is difficult to fabricate a specifically sized sample. The production of properly sized glass samples is necessary for device applications. In this study, we applied spark plasma sintering (SPS) to fabricate $LS_2$ glass samples which have a particular size as well as high transparency. The sintered samples, $15mm\phi{\times}2mmT$ in size, ($LS_2$-s) were produced by SPS between $480^{\circ}C$ and $500^{\circ}C$ at 45MPa for 3~5mim, after which the thermal and dielectric properties of the $LS_2$-s samples were compared with those of quenched glass ($LS_2$-q) samples. Thermal behavior, crystalline structure, and electrical conductivity of both samples were analyzed by differential scanning calorimetry (DSC), X-ray diffraction (XRD) and an impedance/gain-phase analyzer, respectively. The results showed that the $LS_2$-s had an amorphous structure, like the $LS_2$-q sample, and that both samples took on the lithium disilicate structure after the heat treatment at $800^{\circ}C$. We observed similar dielectric peaks in both of the samples between room temperature and $700^{\circ}C$. The DC activation energies of the $LS_2$-q and $LS_2$-s samples were $0.48{\pm}0.05eV$ and $0.66{\pm}0.04eV$, while the AC activation energies were $0.48{\pm}0.05eV$ and $0.68{\pm}0.04eV$, respectively.

• 전기학회논문지
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• 제67권5호
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• pp.635-643
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• 2018

This paper propose a method to identify the motor parameters and improve input voltage error which affect the low speed position error of the back-emf(back electromotive force) based sensorless algorithm and to secure the operation reliability and stability even in the case where the load fluctuation is severe and the start and low speed operation frequently occurs. In the model-based observer used in this paper, stator resistance, inductance, and input voltage are particularly influential factors on low speed performance. Stator resistance can cause resistance value fluctuation which may occur in mass production process, and fluctuation of resistance value due to heat generated during operation. The inductance is influenced by the fluctuation due to the manufacturing dispersion and at a low speed where the change of the current is severe. In order to find stator resistance and inductance which have different initial values and fluctuate during operation and have a large influence on sensorless performance at low speed, they are commonly measured through 2-point calculation method by 2-step align current injection. The effect of voltage error is minimized by offsetting the voltage error. In addition, when the command voltage is used, it is difficult to estimate the back-emf due to the relatively large distortion voltage due to the dead time and the voltage drop of the power device. In this paper, we propose a simple circuit and method to detect the voltage by measuring the PWM(Pulse Width Modulation) pulse width and compensate the voltage drop of the power device with the table, thereby minimizing the position error due to the exact estimation of the back-emf at low speed. The suitability of the proposed algorithm is verified through experiment.