• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.20 no.10
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• pp.918-923
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• 2007

Fuel cell is a modular, high efficient and environmentally energy conversion device, it has become a promising option to replace the conventional fossil fuel based electric power plants. The high temperature fuel cell has conspicuous feature and high potential in being used as an energy converter of various fuel to electricity and heat. Corrosions in molten electrolytes and the electric conductivity across the oxide scale have crucial characteristics. When molten salts are involved, high temperature corrosions become severe. In this sense, corrosions of alloys with molten carbonates have the most severe material problems. Systematic investigation on corrosion behavior of Fe/21Cr/Ti or Al alloy has been done in (62+38)mol% (Li+K)$CO_3$ melt at $650^{\circ}C$ using the electrochemical impedance spectroscopy method. It was found that the corrosion current of these Fe-based alloys decreased with increasing Al or Ti. And Al addition improved the corrosion resistance of this type of specimen and more improvement of corrosion resistance was observed at the specimen added with Al.

• Journal of the Korean Ceramic Society
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• v.56 no.3
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• pp.317-324
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• 2019

Cr-diamond-like carbon (Cr-DLC) films were deposited using a hybrid method involving both physical vapor deposition and plasma-enhanced chemical vapor deposition. DLC sputtering was carried out using argon and acetylene gases. With an increase in the DC power, the Cr content increased from 14.7 to 29.7 at%. The Cr-C bond appeared when the Cr content was 17.6 at% or more. At a Cr content of 17.6 at%, the films showed an electrical conductivity of > 363 S/cm. The current density was 9.12 × 10^-2 ㎂/㎠, and the corrosion potential was 0.240 V. Therefore, a Cr content of 17.6 at% was found to be optimum for the deposition of the Cr-DLC thin films. The Cr-DLC thin films developed in this study showed high conductivity and corrosion resistance, and hence, are suitable for applications in separators.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.24 no.11
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• pp.23-29
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• 2010

The principal factor determining an optimum design method for cathodic protection is finding the protection current for preventing the corrosion of existing, already laid pipe. Some factors currently used to test designs include the sizes and lengths of pipes, soil resistivity, and the coating damage rate. We believe this method and current formulae are not optimum due to the uncertainty of determining the coating damage rate and the corrosion protection current's density. This paper analyzes the amount of protection current obtained by performing a temporary current test using data describing existing laid pipe. We then propose determining the corrosion protection current by using the temporary current test after modifying the formula. In addition, we suggest a way to choose optimized cathodic protection and the process of design by executing the design and taking account of such factors as a site condition of 34km-long non-protected water supply pipe lines (stages I and II) in ${\bigcirc}{\bigcirc}$ region, climate, interferences, and durability.

• The Transactions of the Korean Institute of Power Electronics
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• v.26 no.2
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• pp.90-95
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• 2021

In contrast to AC grounding systems, the ground electrode in DC systems continuously maintains positive or negative polarity. Ground electrodes with (+) polarity proceeds by oxidation reaction. Thus, the DC current should flow opposite to the polarity of the leakage current flowing through the (+) ground electrode by using a compensation electrode, and the current flowing through the (+) ground electrode can be 0A. However, according to protecting the (+) ground electrode, the compensation electrode corrodes and gets damaged. Thus, the (+) ground electrode must be protected from corrosion, and the service life of the compensation electrode must be extended. As an alternative, the average value of the current flowing through the compensation electrode should be equal with the value of the leakage current flowing through the (+) ground electrode by using the square waveform. Throughout the experiment, the degree of corrosion on the compensation electrode is analyzed by the frequency of the compensation electrode for a certain time. In the experiment, the frequencies of the square waveform are considered for 0.1, 1, 10, 20, 50, 100 Hz, and 1 kHz. Through experiments and analysis, the optimal frequency for reducing the electrolytic damage of the (+) electrode and compensation electrode in an LVDC grounding environment is determined.

• Journal of Electrochemical Science and Technology
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• v.12 no.4
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• pp.440-452
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• 2021

Enhancement of durability and reduction of maintenance cost of concrete, with the implementation of various approaches, has always been a matter of concern to researchers. The integration of pozzolans as a substitute for cement into the concrete is one of the most desirable technique. Silica fume (SF) and colloidal nanosilica (CS) have received a great deal of interest from researchers with their significant performance in improving the durability of concrete. The synergistic role of the micro and nano-silica particles in improving the main characteristics of cemented materials needs to be investigated. This work aims to examine the utility of partial substitution of cement by SF and CS in binary and ternary blends in the improvement of the durability characteristics linked to resistance for electrochemical corrosion using electrical resistivity and half-cell potential analysis and chloride penetration trough rapid chloride penetration test. Furthermore, the effects of this silica mixture on the compressive strength of concrete under normal and aggressive environment have also been investigated. Based on the maximum compression strength of the concrete, the optimal cement substituent ratios have been obtained as 12% SF and 1.5% CS for binary blends. The optimal CS and SF combination mixing ratios has been obtained as 1.0% and 12% respectively for ternary blends. The ternary blends with substitution of cement by optimal percentage of CS and SF exhibited decreased rate for electrochemical corrosion. The strength and durability studies were found in consistence with the microstructural analysis signifying the beneficiary role of CS and SF in upgrading the performance of concrete.

• Archives of Metallurgy and Materials
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• v.65 no.3
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• pp.1063-1067
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• 2020

Dynamic charge carrier transport behavior in the zirconium (Zr) oxide was investigated based on the frequency-dependent capacitance-voltage (C-V) and temperature-dependent current-voltage (I-V) measurements. The Zr oxide was formed on the ZIRLO and newly developed zirconium-based alloy (NDZ) by corrosion in the PWR-simulated loop at 360℃. The corrosion test for 90 days showed that the NDZ exhibits better corrosion resistance than ZIRLO alloy. Based on the C-V measurement, dielectric constant values for the Zr oxide was estimated to be 11.28 and 11.52 for the ZIRLO and NDZ. The capacitance difference between low and high frequency was larger in the ZIRLO than in the NDZ, which was attributed to more mobile electrical charge carriers in the oxide layer on the ZIRLO alloy. The current through the oxide layers on the ZIRLO increased more drastically with increasing temperature than on the NDZ, which indicating that more charge trap sites exist in the ZIRLO than in NDZ. Based on the dynamic charge carrier transport behavior, it was concluded that the electrical charge carrier transport within the oxide layers was closely related with the corrosion behavior of the Zr alloys.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.58 no.9
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• pp.1764-1768
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• 2009

As the demand of electric power is increasing rapidly, the need of the compact and light electric power device is also increased. Copper clad aluminum (CCA) is newly proposed electrical conductor, because of its light-weight and low-cost characteristics, to replace the existing conductor made of copper. This paper presents the salt-proof characteristics of the copper clad aluminum (CCA) to certificate long time safe operation of the newly proposed electrical conductor. The two types of the CCA conductor were tested in the neutral salt spray tester. The experimental results of two types of the CCA with salt spray were presented in this paper. The results comprise resistance measured data, micro picture of the selected surface, and component measured data according to the elapsed time. The period of the experiment was 1,000 hours. There was no evidence to show the corrosion of CCA during the whole period of the experiments.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2020.11a
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• pp.149-150
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• 2020

Granting self-sensing performance in a building is an important performance to ensure the degree of damage and safety of the building. Since the current research is being conducted in the state before deterioration loss occurs, it is necessary to confirm whether the self-sensing performance is maintained even in the damaged conductive cement composite. As part of the study, electrical resistance characteristics were analyzed in conductive cement composites in which freeze-thawing and chemical corrosion occurred. As a result, it was found that the change in electrical resistance value due to freeze-thawing was not as large as 1%, and chemical corrosion occurred. It was found that the change in electrical resistance value of the tested specimen increased by about 10%.

• Korean Journal of Materials Research
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• v.18 no.5
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• pp.259-265
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• 2008

The corrosion and degradation factors of a current collector in a molten carbonate fuel cell (MCFC) were investigated to determine the optimized coating thickness of nickel on STS316L. The results show that the surface morphology and electrical properties depended on the nickel coating thickness. The surface morphology gradually changed from a flat to a porous structure along as the nickel coating thickness decreased, and the electrical resistance of the nickel-coated STS316L increased as the nickel coating thickness decreased. This can be attributed to the diffusion of elements of Fe and Cr from the substrate through the nickel grain boundaries. Additionally, carburization in the metal grains or grain boundaries in an anodic environment was found to influence the electrical properties due to matrix distortion. The resistance of Cr-oxide layers formed in an anodic environment causes a drop in the potential, resulting in a decrease in the system efficiency.

• Corrosion Science and Technology
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• v.4 no.2
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• pp.56-59
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• 2005

In rebar concrete structure, the corrosion of rebar can arise the deterioration of concrete structure and may affect the safety of the whole system. Recently, several methods for corrosion protection have been used and are more important for concrete structure using the sand including chloride ion. Among several protections, electrical cathodic protection has been expected to be one of the most useful methods in corrosion protection for reinforcement of concrete structures. The anode for cathodic protection needs high current density, high corrosion resistance and low overvoltage. To fill up the special qualities, the insoluble anodes were developed and these anodes were coated with metal oxide of $TiO_2$, $ZrO_2$, $RuO_2$, and $IrO_2$. Lifetime of these anodes can be one of the important factors affecting the lifetime of concrete structure in cathodic protection. In this work, several anodes were made by sol-gel method and thermal decomposition method and the lifetime of these anodes was evaluated by NACE international standard test method, TM 0294-94. Also, we did analyze the properties of coated metal oxides.