• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2002년도 International Meeting on Information Display
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• pp.445-448
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• 2002

New banana-shaped achiral compounds, 1,3-phenylene bis [4-{4-(7-octenyloxy)phenyliminomethyl}benzoate](PBOEB), 1,3-phenylene bis [4-{3-fluoro-4-(7-octenyloxy)phenyliminomethyl}benzoate] (PBFOEB), 1,3-phenylene bis [4-{4-(10-undecyloxy)phenyliminomethyl}benzoate](PBEUB), and 1,3phenylene bis [4-{3-fluoro-4-(10-undecyloxy)phenyliminomethyl}benzoate](PBFEUB) were obtained by general synthetic methods. PBOEB and PBFOEB having the octenyloxy groups such as $-(CH_2)_6CH=CH_2$ showed ferroelectric switching, and their values of spontaneous polarization on reversal of an applied electric field were 120 nC/$cm^2$ and 225 nC/$cm^2$, respectively. PBEUB and PBFEUB having the undecyloxy groups such as $-{CH_2)_9CH=CH_2$ showed antiferroelectric switching, and their values of spontaneous polarization on reversal of an applied electric field were 120 nC/$cm^2$ and 140 nC/$cm^2$, respectively. We could obtain ferroelectric and antiferroelectric phases by controlling the number of carbon atom in alkenyloxy chains of bent-core molecules.

• Journal of Welding and Joining
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• 제23권2호
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• pp.81-89
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• 2005

A numerical model for multiple reflection effects of a polarized beam on laser grooving has been developed. The surface of the treated material is assumed to reflect laser irradiation in a fully specular fashion. Combining electromagnetic wave theory with Fresnel's relation, the reflective behavior of a groove surface can be obtained as well as the change of the polarization status in the reflected wave field. The material surface is divided into a number of rectangular patches using a bicubic surface representation method. The net radiative flux far these patch elements is obtained by standard ray tracing methods. The changing state of polarization of the electric field after reflection was included in the ray tracing method. The resulting radiative flux is combined with a set of three-dimensional conduction equations governing conduction losses into the medium, and the resulting groove shape and depth are found through iterative procedures. It is observed that reflections of a polarized beam play an important role not only in increasing the material removal rate but also in forming different final groove shapes. Comparison with available experimental results for silicon nitride shows good agreement for the qualitative trends of the dependence of groove shapes on the electric field vector orientation.

• 한국반도체및디스플레이장비학회:학술대회논문집
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• 한국반도체및디스플레이장비학회 2003년도 추계학술대회 발표 논문집
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• pp.163-168
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• 2003

In the present study, the piezoelectricity and polarization of multilayer ceramic actuator, being designed to stack PMN-PZ-PT ceramic layers and Ag-Pd electrode layers alternatively, were investigated under a consideration of geometric factor, the volume ratio of the ceramic to the electrode layers. The actuators were fabricated by tape casting of $0.2Pb(Mg_{1/3}Nb_{2/3)O_3-0.38PbZrO_3-0,42PbTiO_3$ followed by lamination and burnout & co-firing processes. The actuators of $10\times10\times0.6~2\textrm{mm}^3$ in size were formed in a way that $60 ~ 200\mu\textrm{m}$ thick were stacked alternatively with $5\mu\textrm{m}$ thick electrode layer. Increases in polarization and electric field-induced displacement with thickness of the ceramic layer were attributed to change of $90^{\circ}$/$180^{\circ}$ domain ratio, which was affected by interlayer internal stress. The piezoelectricity and actuation behaviors were found to depend upon the volume ratio (or thickness ratio) of ceramic to electrode layers.

• Advances in materials Research
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• 제4권2호
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• pp.113-132
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• 2015

The phenomena of high-voltage polarization and conductivity in oriented vinylidenefluoride and tetrafluoroethylene copolymer films have been investigated. It was shown that under certain electric fields, injection of carriers from the material of electrodes appears The barrier for holes injection in the copolymer was found to be lower than that for electrons. It results in more effective screening of the external field near the anode than near cathode. Electrones, ejected from cathode, creating negative charge by trapping on the surface. It is shown that the electrons injected from cathodes create a negative homocharge on the copolymer surface and then become captured on the surface shallow traps. Their nature has been studied by the x-ray photoelectron spectroscopy. It was shown that these traps may consist of chemical defects in the form of new functional groups formed by reactions of surface macromolecules with sputtered atoms of aluminum. The asymmetric shape of hysteresis curves was explained by the difference in mobility of injected holes and electrons. These factors caused appearance of "non-closed" hysteresis curves for fluorine-containing polymer ferroelectrics. Hysteresis phenomena observed at low electric fields (below coercive ones) are to associate with the behavior of the domains localized in the ordered regions formed during secondary crystallization of copolymers.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제52권12호
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• pp.553-558
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• 2003

The A S $r_{0.7}$B $i_{2.6}$T $a_2$ $O_{9}$ (SBT)thin films are deposited on Pt-coated electrode(Pt/$TiO_2$/$SiO_2$/Si) using a RF magnetron sputtering method. The electrical properties of SBT capacitors with top electrodes were studied. In the XRD pattern, the SBT thin films in all annealing temperatures had (105) orientation. In the SEM images, Bi-layered perovskite phase was crystallized at 75$0^{\circ}C$ and grains largely grew in oxygen annealing atmosphere. The electrical properties of SBT capacitor with top electrodes represent a favorable properties in Pt electrode. The maximum remanent polarization and the coercive electric field with Pt electrode are 12.40C/$\textrm{cm}^2$ and 30kV/cm, respectively. The dielectric constant and leakage current density with Pt electrode is 340 and 6.8110$^{-10}$ A/$\textrm{cm}^2$, respectively.y.y.

• 한국전기전자재료학회논문지
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• 제13권9호
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• pp.791-795
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• 2000

Amorphous chalcogenide glasses have a wide variety of light-induced effects. In this study, we have investigated the diffraction efficiency of chalcogenide. As$_{40}$ Ge$_{10}$ Se$_{15}$ S$_{35}$ thin films by the various applied electric fields. The holographic grating in these thin films has been formed using a linearly polarized He-Ne laser light (633nm). The diffraction efficiency was investigated the two method of applied electric field in the perpendicular and parallel to the direction of inducing beam. We obtained that properties of diffraction efficiency in the two methods of applied electric field. The result is shown that the diffraction efficiency of parallel electric field is 285% increase, η=1.1$\times$10$^{-3}$ and the diffraction efficiency of perpendicular electric field is 80% decrease, η=9.83$\times$10$^{-5}$ . Also, we have investigated the anisotropy property on chalcogenide thin films by the electric field effects.

• 한국재료학회지
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• 제29권2호
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• pp.73-78
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• 2019

Lead free $(Ba_{0.7}Ca_{0.3})TiO_3$ thick films with nano-sized grains are prepared using an aerosol deposition (AD) method at room temperature. The crystallinity of the AD thick films is enhanced by a post annealing process. Contrary to the sharp phase transition of bulk ceramics that has been reported, AD films show broad phase transition behaviors due to the nano-sized grains. The polarization-electric hysteresis loop of annealed AD film shows ferroelectric behaviors. With an increase in annealing temperature, the saturation polarization increases because of an increase in crystallinity. However, the remnant polarization and cohesive field are not affected by the annealing temperature. BCT AD thick films annealed at $700^{\circ}C/2h$ have an energy density of $1.84J/cm^3$ and a charge-discharge efficiency of 69.9 %, which is much higher than those of bulk ceramic with the same composition. The higher energy storage properties are likely due to the increase in the breakdown field from a large number of grain boundaries of nano-sized grains.

• Korean Chemical Engineering Research
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• 제56권5호
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• pp.679-686
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• 2018

폴리아미드 역삼투막을 이용하여 염화나트륨, 아세트산나트륨, 구연산나트륨 용액의 역삼투 농축실험을 행하고, 농도분극 현상을 압력, 용질의 종류, 농축액의 초기 농도를 변수로 연구하였다. 투과 플럭스에 대한 압력과 농도의 영향을 살펴보면, 공정 압력이 증가할수록 그리고 원액의 초기 농도가 작을수록 투과플럭스가 증가하였다. 농도분극이 일어나면 막 표면의 농도가 증가하여 투과플럭스가 감소한다. 농도분극은 농축이 진행됨에 따라 투과 플럭스의 감소로 이어지고 농도분극 층에서 용질 역확산을 통하여 점차 감소하였다. 이온의 크기, 분자량, 전하량이 증가함에 따라 막표면에서 정전기적 반발력이 커서 농도분극의 이론적 해석과 실험값의 차이가 컸다.

• 마이크로전자및패키징학회지
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• 제28권3호
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• pp.25-32
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• 2021

본 논문에서는 X-Band 대역에서 이중 편파 특성을 갖는 Magneto-Electric(ME) dipole 배열안테나를 제안하고, 이를 Low Temperature Co-fired Ceramic (LTCC) 공정을 이용하여 구현 및 측정하였다. 제안된 배열안테나는 LTCC로 구성된 1 × 1 ME dipole 안테나 32 개를 Teflon PCB에 배열하여 8 × 4 배열 안테나로 구성된다. 1 × 1 ME dipole 안테나는 두 쌍의 방사체에서 각각 수직 편파와 수평 편파를 방사하여 이중 편파를 구현하게 된다. 2개의 Port 급전은 LTCC를 이용한 적층 공정을 통해 구현하였으며, 각 각의 Port는 포트 간 격리도를 확보하기 위해 Γ-shaped feeding strip을 통해 독립적으로 방사체에 급전된다. 안테나 배열에 사용된 Teflon PCB는 4층 구조로 형성하였으며, 상단 면과 하단 면을 통해 2개의 Port가 급전된다. 그리고 배열되는 안테나와 Teflon PCB의 임피던스 정합을 위해 Teflon PCB의 전송선로에 λ_g/4 변환기를 적용하였으며 시뮬레이션을 통해 최적 파라미터를 얻었다. 구현된 ME dipole 8 × 4 배열안테나의 크기는 15.5 mm × 11 mm × 4.2 mm이며, Port 1 급전 시 측정된 방사 최대 이득은 18.2 dBi, cross-pol은 1.0 dBi이고 Port 2 급전 시 측정된 방사 최대 이득은 18.1 dBi, Cross-pol은 3.2 dBi로 확인하였다.

• Transactions on Electrical and Electronic Materials
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• 제6권4호
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• pp.177-185
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• 2005

Fatigue characteristics of lead zirconate titanate (PZT) films deposited by electron cyclotron resonance plasma enhanced chemical vapor deposition (ECR-PECVD) were investigated. The fatigue characteristics were investigated with respect to PZT film thickness, domain structure, fatigue pulse height, temperature, electrode materials and electrode configurations. The used top and bottom electrode materials were Pt and $RuO_2$. In the fatigue characteristics with fatigue pulse height and PZT film thickness, the fatigue rates are independent of the applied fatigue pulse height at the electric field regions to saturate the P-E hysteresis and polarization $(P^*,\;P^A)$ characteristics. The unipolar and bipolar fatigue characteristics of PZT capacitors with four different electrode configurations $(Pt//Pt,\;Pt//RuO_2,\;RuO_2//Pt,\;and\;RuO_2//RuO_2)$ were also investigated. The polarization-shifts during the unipolar fatigue and the temperature dependence of fatigue rate suggest that the migration of charged defects should not be expected in our CVD-PZT films. It seems that the polarization degradations are attributed to the formation of charged defects only at the Pt/PZT interface during the domain switching. The charged defects pin the domain wall at the vicinity of Pt/PZT interface. When the top and bottom electrode configurations are of asymmetric $(Pt//RuO_2,\;RuO_2//Pt)$, the internal fields can be generated by the difference of charged defect densities between top and bottom interfaces.