• Title/Summary/Keyword: Effective diffusion

검색결과 844건 처리시간 0.021초

저탄소 Dual Phase강의 가공시효에 미치는 탄소유효확산 및 전위분포의 영향 (Effects of Dislocation Distribution and Carbon Effective Diffusion on Strain Aging Behavior of a Low Carbon Dual Phase Steel)

  • 유상협;정기채;홍기하;박경태
    • 소성∙가공
    • /
    • 제30권5호
    • /
    • pp.226-235
    • /
    • 2021
  • The strain aging behavior of a low carbon dual phase steel was examined in two conditions: representing room temperature strain aging (100 ℃ × 1 hr after 7.5 % prestrain) and bake hardening process (170 ℃ × 20 min after 2 % prestrain), basing on carbon effective diffusion and dislocation distribution. The first principle calculations revealed that (Mn or Cr)-vacancy-C complexes exhibit the strongest attractive interaction compared to other complexes, therefore, act as strong trapping sites for carbon. For room temperature strain aging condition, the carbon effective diffusion distance is smaller than the dislocation distance in the high dislocation density region near ferrite/martensite interfaces as well as ferrite interior considering the carbon trapping effect of the (Mn or Cr)-vacancy-C complexes, implying ineffective Cottrell atmosphere formation. Under bake hardening condition, the carbon effective diffusion distance is larger compared to the dislocation distance in both regions. Therefore, formation of the Cottrell atmosphere is relatively easy resulting in to a relatively large increase in yield strength under bake hardening condition.

칼럼 확산 실험을 통한 아연 및 카드뮴의 유효확산계수에 미치는 온도영향 (Temperature Effect on Effective Diffusion Coefficients of Zn and Cd through Column Diffusion Tests)

  • 도남영;이승래
    • 한국지반환경공학회 논문집
    • /
    • 제3권1호
    • /
    • pp.13-26
    • /
    • 2002
  • 본 연구에서는 아연 및 카드뮴의 확산계수에 미치는 온도영향에 대한 연구를 위해 $15^{\circ}C$$55^{\circ}C$에서 확산실험을 수행하였다. 온도변화에 따른 유효확산계수의 변화를 비교할 경우 두 금속 모두에서 $55^{\circ}C$에서의 유효확산계수가 $15^{\circ}C$에서의 확산계수에 비해 최대 10배까지 큰 것으로 나타났다. 그리고 온도증가에 따른 확산속도의 증가와 더불어 중금속들의 흡착량 또한 증가하는 것으로 나타났다. 그러므로 지연인자를 얻는 방법의 차이에 따라 비교적 흡착량을 과다하게 평가하는 흡착실험을 통해 얻은 지연인자를 이용하여 유효확산계수를 산정할 경우 확산계수를 과대평가 할 수 있다. 그리고 연속추출 실험 결과, 아연의 경우에는 탄산염 형태로의 분배경향이 가장 크게 나타났고, 카드뮴의 경우에는 이온교환형태로의 분배가 가장 크게 나타났다. 특히 실험을 수행한 온도가 증가함에 따라 아연 확산실험의 경우에는 탄산염 형태와 유기물 형태로의 분배가 증가하는 것으로 나타났다. 반면 카드뮴 확산실험의 경우에는 온도변화와 무관하게 60%이상이 이온교환 형태로 분배됨을 알 수 있었다.

  • PDF

이온교환 평판도파로의 실효굴절율 측정 및 해석 (Analysis and Measurement of Effective Refractive Indices with Ion-exchanged Slab Waveguide)

  • 천석표;박정일;박태성;정홍배
    • 한국전기전자재료학회:학술대회논문집
    • /
    • 한국전기전자재료학회 1995년도 춘계학술대회 논문집
    • /
    • pp.73-76
    • /
    • 1995
  • In this study, the slab waveguide was fabricated using potassium-nitride(KNO$_3$) or silver-nitride (AgNO$_3$) molten sources by ion-exchange process. The effective refractive indices of waveguide were measured by Prism-Coupling method. and The characteristics of waveguide(mode dispersion, effective diffusion depth. surface refractive index, diffusion coefficient, and refractive index profile etc,) were investigated by WKB method, In the case of potassium ion-exchange, the computer calculation showed that the refractive index profile of waveguide followed Gaussian function, the surface refractive index increased with ion-exchange time and the effective diffusion depth increased a little as ion-exchange time increased, while the surface refractive index of silver ion-exchanged waveguide decreased with ion-exchange time because of the ion depletion on the surface of waveguide, and the effective diffusion depth seriously with ion-exchange tim. Double ion-exchanged waveguide was fabricated by performing silver ion-exchange after potassium ion-exchange. Double ion-exchanged waveguide had a tight mode binding force since the surface refractive index was larger than single step ion-exchanged waveguide.

  • PDF

Combustion and Radiation Characteristics of Oxygen-Enhanced Inverse Diffusion Flame

  • Hwang, Sang-Soon;Gore, Jay-P
    • Journal of Mechanical Science and Technology
    • /
    • 제16권9호
    • /
    • pp.1156-1165
    • /
    • 2002
  • The characteristics of combustion and radiation heat transfer of an oxygen-enhanced diffusion flame was experimentally analyzed. An infrared radiation heat flux gauge was used to measure the thermal radiation of various types of flames with fuel, air and pure oxygen. And the Laser Induced Incandescence (LII) technique was applied to characterize the soot concentrations which mainly contribute to the continuum radiation from flame. The results show that an oxygen-enhanced inverse diffusion flame is very effective in increasing the thermal radiation compared to normal oxygen diffusion flame. This seems to be caused by overlapped heat release rate of double flame sheets formed in inverse flame and generation of higher intermediate soot in fuel rich zone of oxygen-fuel interface, which is desirable to increase continuum radiation. And the oxygen/methane reaction at slight fuel rich condition (ø=2) in oxygen-enhanced inverse flame was found to be more effective to generate the soot with moderate oxygen availability.

산소부하 이중 역 확산화염의 특성 및 복사열전달에 관한 연구 (A Study on Radiation Heat Transfer and the Characteristics of Oxygen Enriched Double Inversed Diffusion Flame)

  • 이성호;황상순
    • 한국연소학회:학술대회논문집
    • /
    • 한국연소학회 2000년도 제21회 KOSCO SYMPOSIUM 논문집
    • /
    • pp.101-112
    • /
    • 2000
  • An Experimental study of oxygen enriched double inversed diffusion flame was conducted to understand the flame characteristics and radiation heat transfer. The infrared radiation meter was used to measure of various combination of fuel, air and pure oxygen. The results show that oxygen enriched double inversed diffusion flame is very effective to increase of thermal radiation and proper addition of pure oxygen in air flow can intensity thermal radiation of flame. And it can be found that oxygen enriched double inversed diffusion flame could give benefits of cost effective and very high energy saving.

  • PDF

A Study on Radiation Heat Transfer and Characteristics of Oxygen Enriched Double Inversed Diffusion Flame

  • Lee, Sung-Ho;Hwang, Sang-Soon
    • 한국연소학회지
    • /
    • 제6권2호
    • /
    • pp.50-64
    • /
    • 2001
  • An experimental study of oxygen enriched double inversed diffusion flame was conducted to understand the flame characteristics and radiation heat transfer. The infrared radiation meter was used to measure of various combination of fuel, air and pure oxygen. The results show that oxygen enriched double inversed diffusion flame is very effective to increase of thermal radiation and proper addition of pure oxygen in air flow can intensify thermal radiation of flame. And it can be found that oxygen enriched double inversed diffusion flame could give benefits of cost effective and very high energy.

  • PDF

Migration of calcium hydroxide compounds in construction waste soil

  • Shin, Eunchul;Kang, Jeongku
    • Advances in environmental research
    • /
    • 제4권3호
    • /
    • pp.183-196
    • /
    • 2015
  • Migration of leachate generated through embankment of construction waste soil (CWS) in low-lying areas was studied through physical and chemical analysis. A leachate solution containing soluble cations from CWS was found to have a pH above 9.0. To determine the distribution coefficients in the alkali solution, column and migration tests were conducted in the laboratory. The physical and chemical properties of CWS satisfied environmental soil criteria; however, the pH was high. The effective diffusion coefficients for CWS ions fell within the range of $0.725-3.3{\times}10^{-6}cm^2/s$. Properties of pore water and the amount of undissolved gas in pore water influenced advection-diffusion behavior. Contaminants migrating from CWS exhibited time-dependent concentration profiles and an advective component of transport. Thus, the transport equations for CWS contaminant concentrations satisfied the differential equations in accordance with Fick's 2nd law. Therefore, the migration of the contaminant plume when the landfilling CWS reaches water table can be predicted based on pH using the effective diffusion coefficient determined in a laboratory test.

Kinetics and diffusion studies in urease-alginate biocatalyst beads

  • Nakarani, Mukesh;Kayastha, Arvind M
    • Advances in Traditional Medicine
    • /
    • 제7권1호
    • /
    • pp.79-84
    • /
    • 2007
  • Urease was immobilized with calcium alginate by entrapment method in the form of spherical beads and stored in Tris/acetate buffer (pH 7.3) at $4^{\circ}C$. Urease immobilized at different concentration of alginate beads (3%, 4% and 5%) showed higher apparent $K_{m}$ values than the soluble urease. Furthermore, $K_{m}$ has been shown to be corelated with effective diffusion coefficient (De) at different concentration of alginate gel. The present study showed that diffusion and reaction contribute to control the overall rate.

침탄질화 처리된 SCM415강의 깊이에 따른 확산 및 마모특성 변화 (The Change in Diffusion Coefficient and Wear Characteristic in Carbonitriding Layer of SCM415 Steel)

  • 이수연;윤국태;허석환;이찬규
    • 한국표면공학회지
    • /
    • 제44권5호
    • /
    • pp.207-212
    • /
    • 2011
  • In this study, the change in diffusion coefficient and wear characteristic with depth in the carbonitriding layer of SCM415 steel was discussed. To determine the diffusion coefficient, depth profile of carbon was measured from the surface using the Glow Discharge Spectrometer. In otherwise, measurements of carbide fraction, micro vickers hardness of surface and observation of microstructure have been implemented through the SEM image. $Fe_3$(C,N) layer and effective depth were increased as the time for carbonitriding takes longer. According to wear experiment, the results showed that wear resistance was improved by $Fe_3$(C,N) layer and effective depth.

유한요소 해석을 통한 수소확산에 미치는 영향 평가 (Assessment of Effective Factor of Hydrogen Diffusion Equation Using FE Analysis)

  • 김낙현;오창식;김윤재
    • 대한기계학회논문집A
    • /
    • 제34권6호
    • /
    • pp.709-715
    • /
    • 2010
  • 수소 확산과 탄-소성 거동이 결합된 모델은 이미 제시되어 있다. 본 논문에서는 수소확산에 미치는 인자들과 그 영향에 대해 연구하였다. 각 인자들의 영향을 비교하기 위해 저탄소강 재료의 균열이 있는 무한 평판 모델에 대해 수소확산과 기계적 하중이 연계된 유한요소 해석을 수행하였다. 유한요소 해석 결과는 Taha와 Sofrinis의 연구(2001) 결과와 비교하여 검증하였다.