• 제목/요약/키워드: Effective charge density

검색결과 80건 처리시간 0.025초

간호사의 조직몰입과 이직의도에 대한 예측변인으로서 간호단위의 사회연결망 (Social Networks of Nursing Units as Predictors of Organizational Commitment and Intent to Leave of Nurses)

  • 원효진
    • 한국콘텐츠학회논문지
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    • 제20권6호
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    • pp.187-196
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    • 2020
  • 본 연구는 간호단위의 사회연결망을 과업조언 연결망과 친교연결망으로 구분하여 구조적 특성을 파악하고, 간호사의 조직몰입, 이직의도와의 관계를 분석하기 위해 시도되었다. 4개 병원, 30개 간호단위에서 근무하는 420명의 일반간호사를 대상으로 하였으며, 자료는 UCINET 6.0, SPSS 20.0과 HLM 7.0을 이용하여 분석되었다. 과업조언 연결망에서는 수간호사의 연결정도 중심성이 조직몰입에, 간호단위의 밀도가 이직의도에 영향을 미치는 것으로 나타났다. 친교연결망에서는 수간호사의 근접중심성과 책임간호사의 매개중심성이 조직몰입에, 간호단위의 밀도와 책임간호사의 매개중심성이 이직의도에 영향을 미치는 것으로 나타났다. 본 연구 결과를 통한 간호사들 사이에 형성되는 사회연결망에 대한 이해를 바탕으로, 적절한 인력 배치를 위한 연결망 구조와 기회, 조건을 개발하고 다양한 형태의 전략을 수립하기 위한 이론적 근거를 제공할 수 있을 것이다.

나일론과 양모/산성염료계에 대한 계면동전위적 연구 (Electrokinetic Studies on Nylon and Wool/Acid Dye System)

  • 박병기;김진우;김찬영
    • 한국염색가공학회지
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    • 제1권1호
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    • pp.19-25
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    • 1989
  • In past, dye diffusion and dyeing rate in fibers have been emphasized in dyeing phenomena. However, in the light of the properties of colloids in the surface of disperse phase and dispersion, there exist specific characters such as adsorption or electric double layer, which seems to play important roles in determining the physiochemical properties in the dyeing system. Electrostatic bonding, hydrogen bonding and Van der Waals adsorption are common in dyeing as well as covalent bonding. Particularly, electrostatic bonding is premised on the existance of ionic radicals in fibers. The present study was aimed to clarify the electrokinetic phenomena of dyeing through the role of electric double layer by ion in amphoteric fibers with different ionic effects under different pH. Spectrophotometric analysis method was used to compare dyeing condition of surface, which can be detected by electrokinetic phenomena and the inner of fibers after deceleration of dyed fibers. Nylon and wool, the typical amphoteric fibers were dyed with monoazo acid dyes such as C.I. Acid Orange 20, and C.I. Acid Orange 10. Various combinations were prepared by combining pH, temperature and dye concentration, in order to generate streaming electric potential which were measured by microvolt meter and specific conductivity meter. The results were transformed to zeta potential by Helmholtz-Smoluchowski formular and to surface electric charge density by Suzawa formular, surface dye amount, and effective surface area of fibers. The amount of dyes of inner fibers were also measured by the Lambert-Beer’s law. The main results obtained are as follows. 1. By measuring zeta pontential, it was possible to detect the dyeing mechanism, surface charge density, surface dye amount and effective surface area concerning dye adsorption of the amphoteric fibers. 2. Zeta pontential increases in negative at low pH and high dye concentration in the process of dyeing. This implied that there existed ionic bond formation in the dyeing mechanism between acid dyes and amphoteric fibers. 3. Dibasic acid dye had little changing rate in zeta potential due to the difference in solubility of dye and in number of dissociated ions per dye molecule to bond with amino radicals of amphoteric fibers. The dye adsorption of mono basic acid dye was higher than that of dibasic acid dye. 4. The effective surface areas concerning dyeing were $6.3E+05\;cm^2/g$ in nylon, $1.6E+07\;cm^2/g$ in wool fiber being higher order of wool then nylon.

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Facile Synthesis of g-C3N4 Modified Bi2MoO6 Nanocomposite with Improved Photoelectronic Behaviors

  • Zhu, Lei;Tang, Jia-Yao;Fan, Jia-Yi;Sun, Chen;Meng, Ze-Da;Oh, Won-Chun
    • 한국재료학회지
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    • 제31권11호
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    • pp.593-600
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    • 2021
  • Herein, a series of g-C3N4 modified Bi2MoO6 nanocomposites using Bi2MoO6 and melamine as original materials are fabricated via sintering process. For presynthesis of Bi2MoO6 an ultrasonic-assisted hydrothermal technique is researched. The structure and composition of the nanocomposites are characterized by Raman spectroscopy, X-ray diffraction (XRD), and high-resolution field emission scanning electron microscopy (SEM). The improved photoelectrochemical properties are studied by photocurrent density, EIS, and amperometric i-t curve analysis. It is found that the structure of Bi2MoO6 nanoparticles remains intact, with good dispersion status. The as-prepared g-C3N4/Bi2MoO6 nanocomposites (BMC 5-9) are selected and investigated by SEM analysis, which inhibits special morphology consisting of Bi2MoO6 nanoparticles and some g-C3N4 nanosheets. The introduction of small sized g-C3N4 nanosheets in sample BMC 9 is effective to improve the charge separation and transfer efficiency, resulting in enhancing of the photoelectric behavior of Bi2MoO6. The improved photoelectronic behavior of g-C3N4/Bi2MoO6 may be attributed to enhanced charge separation efficiency, photocurrent stability, and fast electron transport pathways for some energy applications.

Study of Optimal Conditions Affecting the Photothermal Effect and Fluorescence Characteristics of Indocyanine Green

  • Seo, Sung Hoon;Bae, Min Gyu;Park, Hyeong Ju;Ahn, Jae Sung;Lee, Joong Wook
    • Current Optics and Photonics
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    • 제5권5호
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    • pp.554-561
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    • 2021
  • Indocyanine green (ICG) is a cyanine dye that has been used in medical diagnostics based on fluorescence imaging, and in medical therapy based on the photothermal effect. It is important to systematically understand the photothermal effect and fluorescence characteristics of ICG simultaneously. By varying a number of conditions such as laser power density, laser irradiation wavelength, concentration of ICG solution, and exposure time of laser irradiation, the intensity properties of fluorescence and the temperature change induced by the photothermal effect are measured simultaneously using a charge-coupled-device camera and a thermal-imaging camera. The optimal conditions for maximizing the photothermal effect are determined, while maintaining a relatively long lifetime and high efficiency of the fluorescence for fluorescence imaging. When the concentration of ICG is approximately 50 ㎍/ml and the laser power density exceeds 1.5 W/cm2, the fluorescence lifetime is the longest and the temperature induced by the photothermal effect rapidly increases, exceeding the critical temperature sufficient to damage human cells and tissues. The findings provide useful insight into the realization of effective photothermal therapy, while also specifying the site to be treated and enabling real-time treatment monitoring.

오스테나이트 스테인리스강의 해수에서 전기화학적 특성에 미치는 전해연마시간의 영향 (Effect of electropolishing process time on electrochemical characteristics in seawater for austenitic stainless steel)

  • 황현규;신동호;허호성;김성종
    • 한국표면공학회지
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    • 제55권4호
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    • pp.236-246
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    • 2022
  • Electropolishing is a surface finishing treatment that compensates for the disadvantages of the mechanical polishing process. It not only has a smooth surface, but also improves corrosion resistance. Therefore, the purpose of this investigation is to examine the corrosion resistance and electrochemical characteristics in seawater of UNS S31603 with electropolishing process time. The roughness improvement rate after electropolishing was improved by about 78% compared to before polishing, indicating that the electropolishing is effective. As a result of potential measuring of mechanical polishing and electropolishing, the potential of electropolishing was nobler than the mechanical polishing condition. As a result of calculating the corrosion current density after potentiodynamic polarization experiment with electropolishing conditions, the corrosion current density of mechanical polishing was about 6.4 times higher than that of electropolishing. After potentiodynamic polarization experiment with electropolishing conditions, the maximum damage depth of mechanical polishing was about 2.2 times higher than that of electropolishing(7 minutes). In addition, the charge transfer resistance of the specimen electropolished for 7 minutes was the highest, indicating improved corrosion resistance.

A Study on the Hydraulic Pump/Motor Control in the Flywheel Hybrid Vehicle

  • Oh, Boem-Sueng;Ahn, Kyoung-Kwan;Cho, Yong-Rae
    • 제어로봇시스템학회:학술대회논문집
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    • 제어로봇시스템학회 2004년도 ICCAS
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    • pp.307-311
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    • 2004
  • In this study, a novel hybrid vehicle is proposed. The vehicle has a flywheel-engine hybrid system. Flywheels are more effective as energy charge systems than electric batteries in a respect of output power density. However, transmissions to effectively drive flywheels are very complex systems such as CVTs (Continuously Variable Transmissions). In the proposed hybrid vehicle, Constant Pressure System is employed, which is hydraulic power transmission. Using Constant Pressure Systems, hydraulic CVTs are easily realized with variable displacement pumps/motors. In this paper, firstly, the proposed flywheel hybrid vehicle making use of Constant Pressure System is described. Secondly, fuel consumption characteristics of the flywheel hybrid vehicle are experimentally examined with the stationary test facility, which employs a flywheel as a load emulating vehicle inertia. Finally, the experimental results and discussions are described. Fuel consumption of 26km/L is expected for 10 mode driving schedule with vehicle mass of 1500kg.

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자려 진동형 히트 파이프를 이용한 저온 폐열 회수 열교환기의 성능 실험 (Performance Test of Low Temperature Waste Heat Recovery Heat Exchanger Using Self-excited Oscillating Heat Pipe)

  • 이욱현;이종현;김종수
    • 설비공학논문집
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    • 제12권9호
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    • pp.853-859
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    • 2000
  • In this study, low temperature waste heat recovery heat exchanger was developed using a principle of self-excited oscillating heat pipe. The heat exchanger of serpentine type was composed of extruded flat aluminum tube with 6 channels (3 nm$\times$ 2.75nm) and louvered fin. The heat transfer area density of heat exchanger was $331.9 m^2/m^3$. Working fluid is R141b and charge ratio was 40% by volume. Heat transfer rate and the effectiveness of heat exchanger was primary concern of this study. As a result, the effectiveness of heat exchanger was about 0.4-0.67, and recovered waste heat rate was about 4.5 kW per one unit of heat exchanger.

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키토산 표면처리가 종이의 항균성에 미치는 영향 (Effect of Chitosan Surface Treatment on the Antibacterial Properties of Paper)

  • 최찬호;전양;서영범
    • 펄프종이기술
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    • 제30권4호
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    • pp.59-68
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    • 1998
  • This study was to investigate the effect of chitosan molecular weight, its charge density, and its surface coating treatment on the antibacterial properties of paper. For this study, E.coil was used for antibacterial experiment. Results obtained were as follows : 1. The antibacterial properties of chitosan was significant on the surface-treated sheet. 2. Antibacterial property surface treatment was appeared to be effective when film was formed on the paper surface. 3. The antibacterial properties of chitosan-treated paper was dependent on the amount and the molecular weight of chitosan used. The lower the molecular weight of the chitosan down to 30,000 the better the antibacterial properties in this experiment. 4. Determination of the degree of chitosan-deacetylation by colloidal titration method was consistent with the more complicated and conventional FT-IR method.

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Compensation of Power Fluctuations of PV Generation System by SMES Based on Interleaving Technique

  • Kim, Seung-Tak;Park, Jung-Wook
    • Journal of Electrical Engineering and Technology
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    • 제10권5호
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    • pp.1983-1988
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    • 2015
  • This paper proposes the enhanced application of superconducting magnetic energy storage (SMES) for the effective compensation of power fluctuations based on the interleaving technique. With increases in demand for renewable energy based photovoltaic (PV) generation system, the output power fluctuations from PV generation system due to sudden changes in environmental conditions can cause serious problems such as grid voltage and frequency variations. To solve this problem, the SMES system is applied with its superior characteristics with respect to high power density, fast response for charge and discharge operations, system efficiency, etc. In particular, the compensation capability is effectively improved by the proposed interleaving technique based on its parallel structure. The dynamic performance of the system designed using the proposed method is evaluated with several case studies through time-domain simulations.

급속 열처리에 의한 $SiO_2$ 의 질화 (Rapid Thermal Nitridation of $SiO_2$)

  • 이용현;왕진석
    • 대한전자공학회논문지
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    • 제27권5호
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    • pp.709-715
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    • 1990
  • SiO2 films were nitrided by tungsten-halogen heated rapid thermal annealing in ammonia gas at temperatures of 900-1100\ulcorner for 15-180sec. The nitroxide films were analyzed using Auger electron spectroscopy. MIS caapcitors were fabricated using these films as gate insulators. I-V and C-V characteristics of MIS capacitors were investigated. The AES depth profiles of nitroxide film show that the nitrogen rich layer is, at the early stage of nitridation, formed at the surface of nitroxide film and near the interface between nitroxide and silicon. Nitridation of SiO2 makes the film have a larger effective average refractive index. The thermal nitridation of SiO2 on silicon causes the flatband voltage shift due to the change of the fixed charge density. It is found that the dominant conduction mechanism in nitroxide is Fowler-Nordheim tunneling. Rapid thermal nitridation of 200\ulcornerSiO2 on silicon results in an improvement in the dielectric breakdown electric field.

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