• Title/Summary/Keyword: Ecomaterials

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Poly(1,2-propylene glycol adipate) as an Environmentally Friendly Plasticizer for Poly(vinyl chloride) (폴리염화비닐의 친환경 가소제로서 Poly(1,2-propylene glycol adipate))

  • Zhao, Yan;Liang, Hongyu;Wu, Dandan;Bian, Junjia;Hao, Yanping;Zhang, Guibao;Liu, Sanrong;Zhang, Huiliang;Dong, Lisong
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.247-255
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    • 2015
  • Poly(1,2-propylene glycol adipate) (PPA) was used as an environmentally friendly plasticizer in flexible poly(vinyl chloride) (PVC). Thermal, mechanical, and rheological properties of the PVC/PPA blends were characterized by differential scanning calorimetry, dynamic mechanical analysis, tensile test, scanning electron microscopy and small amplitude oscillatory shear rheometry. The results showed that PPA lowered the glass transition temperature of PVC. The introduction of PPA could decrease tensile strength and Young's modulus of the PVC/PPA blends; however, elongation-at-break was dramatically increased due to the plastic deformation. The plasticization effect of PPA was also manifested by the decrease of dynamic storage modulus and viscosity in the melt state of the blends. The results indicated that PPA had a good plasticizing effect on PVC.

Fabrication of Nano-laminar Glass Composite Using Thin Flake

  • Kakisawa, Hideki;Minagawa, Kazumi;Halada, Kohmei
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09a
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    • pp.330-331
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    • 2006
  • Fabrication of a nano-laminar ceramic composite by sintering thin ceramic plates was examined. Silver-coated glass flakes with a thickness of less than $1{\mu}m$ were consolidated by pulsed current sintering or hotpressing to obtain model composites. The samples sintered at the optimum conditions were fairly dense, and the flakes were aligned by uniaxial press. The metal coating remained on the flakes through the sintering process, and became an interface layer between the flakes. No crack propagation through the transverse direction of the lamellar was observed in the indentation test. The possibilities of high resistance against crack propagation was suggested.

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A Study of R&D Paradigm For the Materials Technologies Involving Environmental Consciousness (재료기술의 환경패러다임 모색)

  • 하재우;권식철;김성준
    • Journal of Korea Technology Innovation Society
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    • v.2 no.1
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    • pp.104-117
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    • 1999
  • The R&D paradigm for the Materials Technologies involving Environmental Consciousness(MTEC) is sought in this paper with an emphasis on the background and importance of the METC. In this paper the MTEC is defined as "Green Materials Technology", and the Green Materials Technology is classified into four categories based on life cycle of the materials; \circled1Ecomaterials technology(materials design), \circled2Envimatec technology (manufacturing process), \circled3Materials life technology (use & maintenance) and \circled4Materials recycling technology (waste disposal). Each these four categories was introduced. In conclusion, the main R&D field and strategies for the four categories of the Green Materials Technology were suggested.

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Effect of Alumina contents in Feldspar and cullet for the Soda-lime glass manufacturing (Soda-Lime Glass에서 Cullet과 장석의 첨가에 따른 Alumina 변화가 제조공정에 미치는 영향)

  • No, Gwang-Hong;Kim, Jong-Ok
    • The Journal of Engineering Research
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    • v.6 no.1
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    • pp.15-27
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    • 2004
  • The first aim of mass product of glass in Automatic bottle glass industry is to decrease the cost and to increase the quality. Second, the cullet is how widely used to save the energy and reducing of ecomaterials. However the physical and chemical properties of Soda-lime glass would be come true at the lower than 2% $Al_2 O_3$. Unfortunately the $Al_2 O_3$ contents of domestic silica is greater than 4% Since small glass class than 200ml bottle is made in domestic silica the producting efficiency would be decreased due to the defect such as cord, knot, devitrite, pore etc. There are many problems such as devitrifiacation and deteriorated effect on production in glass industry became of increasing of plate glass cullet. It is tried to solve these kinds of problems using various analysing methods in this experiments.

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Effect of TiO2 Nanotube Length on Photocatalytic Activity with Different Light Intensities: Cr(VI) Reduction and Hydrogen Production (광량 및 TiO2 나노튜브 길이별 광활성 연구: Cr(VI)환원 및 수소제조)

  • Joo, Hyun-Ku;Shim, Eun-Jung;Lee, Jae-Min;Yoon, Jae-Kyung
    • Journal of Hydrogen and New Energy
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    • v.22 no.4
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    • pp.432-442
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    • 2011
  • Anodized tubular $TiO_2$ electrodes (ATTEs) with three noticeably different lengths are prepared to determine their optimum length for the photo-driven activity in the reaction of Cr(VI) reduction and hydrogen evolution. The ATTEs with ethylene glycol have longer $TiO_2$ tubes (7-15.6 ${\mu}m$) than those with hydrfluoric acid (0.6-0.8 ${\mu}m$). These samples, which differ only in the length of the tubes, with a wall thickness of ca. 20 nm, consist mainly of an anatase crystalline phase after heat treatment at $650^{\circ}C$, since the anatase crystallites at the tube walls do not undergo transformation into rutile phase, due to the constraints imposed by the wall thickness. Among them, the medium size (ca. 8 ${\mu}m$) tubes provide the optimum conditions, irrespective of the light intensity, which is explained in terms of the correlation between the amount of photons and the adsorbed electron acceptors and their location. Photocatalytic Cr(VI) reduction leads to ca. 60% reduction of Cr(VI) even under 1 sun irradiation with the medium-sized anodized $TiO_2$ tubes, but only ca. 20% with the short- and long-sized tubes. For hydrogen evolution, tubes longer than 8 ${\mu}m$ do not exhibit better performance with any light intensity.

Effect of Volume Fraction on Mechanical and Fatigue Crack Growth Properties of SiC Particle Reinforced AL Alloy Composites (체적비가 $SiC_{p}$/AL 복합재료의 기계적 및 피로균열진전 특성에 미치는 영향)

  • Gwon, Jae-Do;An, Jeong-Ju;Mun, Yun-Bae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.20 no.4
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    • pp.1301-1308
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    • 1996
  • In order to save the energy and protect the environment, it were studied about ecomaterials with the developed countries as central figure. In the Metal Matrix Composites(MMCs), this trends appeared the development of the MMCs which had excellent mechanical properties in spite of the low volume fraction of reinforcement. Therefore, in this study, fatigue crack growth test, tensile and hardness test were conducted in order to investigate the mechanical and fatigue properties of 5 %, and 10 % $SiC_{p}$/Al composites. As the results, in the tensile and hardness test, tensile strength and hardness increased but fatigue crack growth rate decreased with $SiC_{p}$/Al volume fraction. And in the view of fatigue failured surface through the SEM, fatigue crack initiated around the SiC particle and in low $\Delta{K}$ regions, fatigue creck detoured the SiC particle but crack propagated through the SiC particle in the high $\DeltaK$ regions.