• Title/Summary/Keyword: Eco powder

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Direct Solid State Synthesis of Zn4Sb3 by Hot Pressing and Thermoelectric Properties (열간 압축 공정에 의한 Zn4Sb3의 직접 고상 반응 합성 및 열전특성)

  • Ur Soon-Chul
    • Journal of Powder Materials
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    • v.12 no.4 s.51
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    • pp.255-260
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    • 2005
  • Direct solid state synthesis by hot pressing has been applied in order to produce high efficiency $Zn_4Sb_3$ bulk specimens. Single phase $Zn_4Sb_3$ with 98.5% of theoretical density was successfully produced by direct hot pressing of elemental powders containing 1.2 at.% excess Zn. Thermoelectric properties as a function of temperature were investigated from room temperature to 600 K and compared with results of other studies. Transport properties at room temperature were also evaluated. Thermoelectric properties of single phase $Zn_4Sb_3$ materials produced by direct synthesis were measured and are comparable to the published data. Direct solid state synthesis by hot pressing provides a promising processing route in this material.

Fluidity and compressive strength characteristics of no-cement composite according to fly ash replacement rate (플라이애시 대체율에 따른 무시멘트 복합체의 유동성 및 압축강도 특성)

  • Lee, Jae-In;Park, Jeong-Yeon;Kim, Chae-Young;Yoon, Joo-Ho;Choi, Se-Jin
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2023.11a
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    • pp.195-196
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    • 2023
  • Recently, the importance of eco-friendly and sustainable development has been emphasized. The construction industry also needs to make efforts to reduce cement use, which accounts for 8% of greenhouse gas emissions. This study examined the fluidity and compressive strength of a cementless composite using fine blast furnace slag powder and fly ash without using cement in order to reduce greenhouse gas emissions due to the use of cement.

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Production of Fe Amorphous Powders by Gas-Atomization Process and Subsequent Spark Plasma Sintering of Fe amorphous-ductile Cu Composite Powder Produced by Ball-milling Process (II) - II. SPS Behaviors of Composite Powders and their Characteristics - (가스분무법에 의한 Fe계 비정질 분말의 제조와 볼밀링공정에 의한 연질 Cu분말과의 복합화 및 SPS 거동 (II) - II. 복합분말의 SPS와 특성 -)

  • Kim, Jin-Chun;Kim, Ji-Soon;Kim, H.J.;Kim, Jeong-Gon
    • Journal of Powder Materials
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    • v.16 no.5
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    • pp.326-335
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    • 2009
  • Fe based (Fe$_{68.2}$C$_{5.9}$Si$_{3.5}$B$_{6.7}$P$_{9.6}$Cr$_{2.1}$Mo$_{2.0}$Al$_{2.0}$) amorphous powder, which is a composition of iron blast cast slag, were produced by a gas atomization process, and sequently mixed with ductile Cu powder by a mechanical ball milling process. The Fe-based amorphous powders and the Fe-Cu composite powders were compacted by a spark plasma sintering (SPS) process. Densification of the Fe amorphous-Cu composited powders by spark plasma sintering of was occurred through a plastic deformation of the each amorphous powder and Cu phase. The SPS samples milled by AGO-2 under 500 rpm had the best homogeneity of Cu phase and showed the smallest Cu pool size. Micro-Vickers hardness of the as-SPSed specimens was changed with the milling processes.

Evaluation of Hydrogenation Behavior of MgHx-Graphene Composites by Mechanical Alloying (기계적 합금화법으로 제조한 MgHx-Graphene 복합재료의 수소화 거동 특성)

  • Lee, Soo-Sun;Lee, Na-Ri;Kim, Kyeong-Il;Hong, Tae-Whan
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.6
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    • pp.780-786
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    • 2011
  • Mg hydride had high hydrogen capacity (7.6%), lightweight and low cost materials and it was promising hydrogen storage material at high temperature. However, commercial applications of the Mg hydride are currently hindered by its high absorption/desorption temperature, and very slow reaction kinetics. one of the approaches to improve the kinetic is $MgH_x$ intermixed with carbon. And it shows that carbon and carbon allotropes have a beneficial effect on hydrogen sorption in Mg. The graphene is a kind of carbon allotropes which is easily desorbed reaction at low temperatures because its reaction is exothermic. In this work, the effect of graphene concentration on the kinetics of Mg hydrogen absorption reaction was investigated. The $MgH_x$-Graphene composites has been prepared by hydrogen induced mechanical alloy (HIMA). The synthesized powder was characterized by XRD and simultaneous TG, DSC analysis. The hydrogenation behaviors were evaluated by using a sievert's type automatic PCT apparatus. In this research, results of kinetic profiles exhibit hydrogen absorption rate of $MgH_x$-5wt.% and 10wt.% graphene composite, as 1.25wt.%/ms, 10.33wt.%/ms against 0.88wt.%/ms for $MgH_x$ alone at 473K.

Recycling Method of Used Indium Tin Oxide Targets (폐 인듐주석산화물 타겟의 재활용 기술)

  • Lee, Young-In;Choa, Yong-Ho
    • Korean Journal of Materials Research
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    • v.22 no.4
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    • pp.174-179
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    • 2012
  • In this study, we demonstrated a simple and eco-friendly method, including mechanical polishing and attrition milling processes, to recycle sputtered indium tin oxide targets to indium tin oxide nanopowders and targets for sputtered transparent conductive films. The utilized indium tin oxide target was first pulverized to a powder of sub- to a few- micrometer size by polishing using a diamond particle coated polishing wheel. The calcination of the crushed indium tin oxide powder was carried out at $1000^{\circ}C$ for 1 h, based on the thermal behavior of the indium tin oxide powder; then, the powders were downsized to nanometer size by attrition milling. The average particle size of the indium tin oxide nanopowder was decreased by increasing attrition milling time and was approximately 30 nm after attrition milling for 15 h. The morphology, chemical composition, and microstructure of the recycled indium tin oxide nanopowder were investigated by FE-SEM, EDX, and TEM. A fully dense indium tin oxide sintered specimen with 97.4% of relative density was fabricated using the recycled indium tin oxide nanopowders under atmospheric pressure at $1500^{\circ}C$ for 4 h. The microstructure, phase, and purity of the indium tin oxide target were examined by FE-SEM, XRD, and ICP-MS.

Glass powder admixture effect on the dynamic properties of concrete, multi-excitation method

  • Kadik, Abdenour;Boutchicha, Djilali;Bali, Abderrahim;Cherrak, Messaouda
    • Structural Engineering and Mechanics
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    • v.74 no.5
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    • pp.671-678
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    • 2020
  • In this work, the dynamic properties of a high performance concrete containing glass powder (GP) was studied. The GP is a new cementitious material obtained by recycling waste glass presenting pozzolanic activity. This eco-friendly material was incorporated in concrete mixes by replacing 20 and 30% of cement. The mechanical properties of building materials highly affect the response of the structure under dynamic actions. First, the resonant vibration frequencies were measured on concrete plate with free boundary conditions after 14, 28 and 90 curing days by using an alternative vibration monitoring technique. This technique measures the average frequencies of several excitations done at different points of the plate. This approach takes into account the heterogeneity of a material like concrete. So, the results should be more precise and reliable. For measuring the bending and torsion resonant frequencies, as well as the damping ratio. The dynamic properties of material such as dynamic elastic modulus and dynamic shear modulus were determined by modelling the plate on the finite element software ANSYS. Also, the instantaneous aroused frequency method and ultrasound method were used to determine the dynamic elastic modulus for comparison purpose, with the results obtained from vibration monitoring technique.

Development and Quality Assessment of Healthy Bread using Korean Pine Leaf Powder

  • Eunbin Park;Soo In Ryu;Jean Kyung Paik
    • The Korean Journal of Food And Nutrition
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    • v.36 no.5
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    • pp.387-394
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    • 2023
  • With the advancement and diversification of the bread industry, eco-friendly products with less sugar and salt, and containing functional ingredients are being developed. To develop healthy bread, Korean pine leaf powder was added in different proportions (0%, 1%, 3%, 5%, and 7%), and the quality characteristics of the bread, namely height, moisture, color value, texture, antioxidant property, and sensory characteristics were evaluated. As the amount of leaf powder was increased in the bread, L-value in the range of 53.45~85.05 (p<0.001) and adhesiveness in the range of 0.13~0.32 mJ (p<0.001) decreased significantly, whereas b-value in the range of 16.75~30.74 (p<0.001), total polyphenol content in the range of 466.83~669.13 ug/mL, ABTS- in the range of 0.46~43.23%, DPPH-radical in the range of 1.39~45.76%, scavenging capacities (p<0.001), color in the range of 3.27~5.40 (p=0.017) and texture in the range of 4.33~4.80 (p=0.006) preferences increased significantly. This study could increase the utilization of Korean pine leaf and the production of healthy food with antioxidant properties.

Predicting ESP and HNT effects on the mechanical properties of eco-friendly composites subjected to micro-indentation test

  • Saeed Kamarian;Ali Khalvandi;Thanh Mai Nguyen Tran;Reza Barbaz-Isfahani;Saeed Saber-Samandari;Jung-Il Song
    • Advances in nano research
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    • v.15 no.4
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    • pp.315-328
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    • 2023
  • The main goal of the present study was to assess the effects of eggshell powder (ESP) and halloysite nanotubes (HNTs) on the mechanical properties of abaca fiber (AF)-reinforced natural composites. For this purpose, a limited number of indentation tests were first performed on the AF/polypropylene (PP) composites for different HNT and ESP loadings (0 wt.% ~ 6 wt.%), load amplitudes (150, 200, and 250 N), and two types of indenters (Vickers or conical). The Young's modulus, hardness and plasticity index of each specimen were calculated using the indentation test results and Oliver-Pharr method. The accuracy of the experimental results was confirmed by comparing the values of the Young's modulus obtained from the indentation test with the results of the conventional tensile test. Then, a feed-forward shallow artificial neural network (ANN) with high efficiency was trained based on the obtained experimental data. The trained ANN could properly predict the variations of the mentioned mechanical properties of AF/PP composites incorporated with different HNT and ESP loadings. Furthermore, the trained ANN demonstrated that HNTs increase the elastic modulus and hardness of the composite, while the incorporation of ESP reduces these properties. For instance, the Young's modulus of composites incorporated with 3 wt.% of ESP decreased by 30.7% compared with the pure composite, while increasing the weight fraction of ESP up to 6% decreased the Young's modulus by 34.8%. Moreover, the trained ANN indicated that HNTs have a more significant effect on reducing the plasticity index than ESP.

Molluscicidal Effect of Eco-Friendly Agricultural Substances for Controlling Golden Apple Snails (Pomacea canaliculata, Lamarck)

  • Il Kyu Cho;Woo Young Cho;In Sun Cho;Heon Woong Kim;Seonghoon Hyeong;Jang Hyun Park;Young Sig Kim;Kil Yong Kim;Gi-Woo Hyoung
    • Korean Journal of Environmental Agriculture
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    • v.42 no.4
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    • pp.396-407
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    • 2023
  • The golden apple snail (Pomacea canaliculata) has been utilized as a natural and eco-friendly control of weeds in rice paddy fields. However, P. canaliculata can damage other crops. In this study, the effectiveness of plant extracts from various natural sources that are reportedly effective against pests in the control of P. canaliculata was investigated. The four plant extracts were effective against P. canaliculata and ranked in descending order as green tea seed (Camellia sinensis) > root of red spider lily (Lycoris radiata) > leaves of tobacco (Nicotiana tabacum) > root of sophora (Sophora flavescens). The mortality rate of P. canaliculata was increased using 200 to 2000 mg/kg of green tea seed powder. However, shrubby sophora root extract did not significantly increase the mortality rate. The LC50 and LC90 of green tea seed, tobacco leaves, shrubby sophora root, and red spider lily root were 900 and 2800 mg/L, 956 and 2320 mg/L, 2162 and 5325 mg/L, and 512 and 1054 mg/kg, respectively. The LC50 and LC90 of ground powder of C. sinensis, N. tabacum, S. flavescens and L. radiata were 248 and 646 mg/L, 403 and 733 mg/L, 409 and 905 mg/L, and 493 and 1141 mg/L, respectively. The findings indicate the remarkable control potency of green tea seeds against the golden apple snail. An organic material incorporating the four plant powders may help control green apple snail in an ecosystem-friendly manner.

Fabrication of $TiO_2$ Electrode Containing Scattering Particles in Dye-Sensitized Solar Cells (산란 입자를 포함하는 염료감응 태양전지용 $TiO_2$ 전극 제조)

  • Lee, Jin-Hyoung;Lee, Tae-Kun;Kim, Cheol-Jin
    • Journal of the Microelectronics and Packaging Society
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    • v.18 no.2
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    • pp.57-62
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    • 2011
  • The energy conversion efficiency of DSSCs (Dye-Sensitized Solar Cells) is dependent on the powder size, the structure, and the morphology of $TiO_2$ electrode. The higher efficiency is obtained with high surface area of the nanoanatase-$TiO_2$ powder adsorbed onto a lot more of the dye. Also, the enhancement of light scattering increases the efficiency with high adsorption of the dye. Powder size, crystalline phase, and shape of $TiO_2$ obtained by hydrothermal method have 15-20 nm, anatase and round. $TiO_2$ electrode has fabricated with the mixture of scattering $TiO_2$ particle with 0.4 ${\mu}m$ in nano-sized powder. Conversion efficiency of series of DSSCs was measured with volume fraction of scattering particle. Photovoltaic characteristics of DSSCs with 10% scattering particles are 3.51 mA for Jsc (short circuit current), 0.79 V for Voc(open circuit potential), filling factor 0.619 and 6.86% for efficiency. Jsc was improved by 11% and enhancement of efficiency by 0.77% compared with that of no scattering particles. The confinement of inserted light by light scattering particles has more increase of the injection of exiton(electron-hole pair) and decrease of moving path in electron. Efficiencies of DSSCs with more than 10% for scattering particles have reduced with increasing the pore in the $TiO_2$ electrode.