• Title/Summary/Keyword: ECO2

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Research Trends on Developments of High-performance Perfluorinated Sulfonic Acid-based Polymer Electrolyte Membranes for Polymer Electrolyte Membrane Fuel Cell Applications (고분자 전해질 막 연료전지 응용을 위한 고성능 과불소화계 전해질 막 개발 연구 동향)

  • Choi, Chanhee;Hwang, Seansoo;Kim, Kihyun
    • Membrane Journal
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    • v.32 no.5
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    • pp.292-303
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    • 2022
  • An eco-friendly energy conversion device without the emission of pollutants has gained much attention due to the rapid use of fossil fuels inducing carbon dioxide emissions ever since the first industrial revolution in the 18th century. Polymer electrolyte membrane fuel cells (PEMFCs) that can produce water during the reaction without the emission of carbon dioxide are promising devices for automotive and residential applications. As a key component of PEMFCs, polymer electrolyte membranes (PEMs) need to have high proton conductivity and physicochemical stability during the operation. Currently, perfluorinated sulfonic acid-based PEMs (PFSA-PEMs) have been commercialized and utilized in PEMFC systems. Although the PFSA-PEMs are found to meet these criteria, there is an ongoing need to improve these further, to be useful in practical PEMFC operation. In addition, the well-known drawbacks of PFSA-PEMs including low glass transition temperature and high gas crossover need to be improved. Therefore, this review focused on recent trends in the development of high-performance PFSA-PEMs in three different ways. First, control of the side chain of PFSA copolymers can effectively improve the proton conductivity and thermal stability by increasing the ion exchange capacity and polymer crystallinity. Second, the development of composite-type PFSA-PEMs is an effective way to improve proton conductivity and physical stability by incorporating organic/inorganic additives. Finally, the incorporation of porous substrates is also a promising way to develop a thin pore-filling membrane showing low membrane resistance and outstanding durability.

Complete Genome Analysis of Spodoptera exigua Nucleopolyhedrovirus Isolated in Korea (한국에서 분리된 파밤나방 핵다각체병 바이러스의 전체 유전체 분석)

  • Jae Bang, Choi;Hyun-Soo, Kim;Soo-Dong, Woo
    • Korean journal of applied entomology
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    • v.61 no.3
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    • pp.449-460
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    • 2022
  • The morphology and whole genome sequence of Spodoptera exigua nucleopolyhedrovirus K1 (SeNPV-K1) isolated in Korea were analyzed for the use as an eco-friendly control source against S. exigua. The polyhedra of SeNPV-K1 was amorphous with a size of 0.6-1.8 ㎛, and there was no external difference with the previously reported SeNPV. As a result of analyzing the nucleotide sequence of the whole genome, it was composed of 135,756 bp, which is 145 bp more than that of the previously reported SeNPV. The G+CG+C content was 44% and there were 6 homologous repeated sequences, so there was no significant difference from the previous report. As a result of ORF analysis, SeNPV-K1 had 137, two fewer than those previously reported, and 4 ORFs present only in SeNPV-K1 were confirmed. These 4 ORFs are non-essential genes and were not considered to have a significant influence on the characteristics of the SeNPV. The genome vista analysis showed that the overall sequence similarity between SeNPV-K1 and the previously reported SeNPV was very high. The whole genome of SeNPV-K1 analyzed for the first time in Korea was found to be similar to the previously reported SeNPV, but it was confirmed that it was a novel resource in Korea with different isolate.

An Explorative Study on Theoretical Potential of Critical Realism as Social Welfare Paradigm (사회복지 패러다임(paradigm)으로서 비판적 실재론의 가능성에 대한 탐색적 연구)

  • Woo, Ah Young;Kim, Giduk
    • Korean Journal of Social Welfare Studies
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    • v.44 no.2
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    • pp.465-497
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    • 2013
  • This paper criticizes the ontological and epistemological dichotomy in social sciences including social welfare and probes into Critical Realism as an alternative paradigm. Many theories for social welfare have adhered to dichotomous ontological standpoint, 'agency' vs. 'social structure', and Eco-system approach have occupied dominant position to integrate this dichotomy. These theoretical standpoint have had great influence on social work practice. On the other hand, dichotomous epistemological standpoint which is constituted of different views of phenomena, 'positivism' and 'constructionism', have had great influence on social work research and practice. These dichotomous ontological and epistemological approach have a limit to reveal qualitative nature of the relationship between agency and social structure, to ponder the deeper reality, the mechanism of stratified reality, and the reality being independent of agency. Replacing these approaches, Critical Realism unfold the theoretical potential as an alternative paradigm for social welfare through the discussion on stratified realty(the empirical, the actual, and the real), intransitive/transitive dimension, double hermeneutics in these dimensions, and the conditions for conceptualization, duality of structure and practice, transformation model of agency and structure.

Characteristics of Biodegradable Films and Their Effects on Soybean Growth

  • Ye Geon Kim;Hyo Jin Lee;Do Jin Lee;Yong In Kuk
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.50-50
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    • 2022
  • Recently, the use of mulching film has increased in soybean cultivation. Polyethylene (PE) films and biodegradable films (BF) have the advantages of improving soil moisture retention, geothermal maintenance, and CO2 maintenance as well providing weed control. Furthermore, BFs are a material that can compensate for the shortcomings of PE because it has the ability to decompose naturally by soil microorganisms, sunlight, and geothermal heat. Many researches have been carrying out studies regarding the development of BFs for these very reasons. This study was conducted better understand which films are optimal for soybean cultivation after evaluations of soybean growth and film characteristics of various BFs. BFs Farmsbio (Farm Hannong), Heulgro Film (Sejin Bio), Vonto Film (Eco-Hansung), two unnamed biodegradable films (Seojin Bio and Taesung), and a PE film were used in this study. For the control plots, no mulching was used. Experimental fields were fertilized according to conventional cultivation methods, tilled, and then covered with either BFs or PE films. After 1 week, soybean (cv. Daechan) seeds were seeded. Germination rate and plant height were measured at weekly intervals after seeding. In addition, pH, EC, and decomposition and light transmittance levels of films were measured during the experimental period. Daily average temperatures and relative humidity in soils was measured during the experimental period. There was no significant difference in germination rates and plant height in both crops grown with BFs and PE films, but crops grown in the control plot had significantly lower germination rates and growth. Soil pH was not significantly different regardless of treatments (BF, PE, and non-mulching) at 14, 28, and 42 days after seeding. In general, the EC contents in the control plots was lower than in crops grown using BFs and PE films. With the exception of some BFs, light transmittance and decomposition levels of films did not, in general, increase up to 70 days after soybean seeding. Since this study is ongoing, we are continually investigating these parameters. The average daily moisture in soil was higher in crops grown with BFs and PE films than in the control plot. However, the daily average soil temperature was not consistent regardless of treatments. Therefore, the BFs used in this study can be used without negative impacts on soybean growth.

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Biodegradable Film Decomposition Levels and Their Effects on Growth and Yield of Corn Crops

  • Ye Geon Kim;Hyun Hwa Park;Do Jin Lee;Yong In Kuk
    • Proceedings of the Korean Society of Crop Science Conference
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    • 2022.10a
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    • pp.52-52
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    • 2022
  • Recently, PE (polyethylene) film has been used increasingly in com cultivation. However, PE films often cause soil and environment contamination. In order to reduce this problem, many researches have been carrying out studies on biodegradable films (BF) that are easily decomposed by soil microorganisms. Therefore, this study was conducted to determine which BF is optimal for growth and yield of com crops while also having the highest rates of film decomposition. BFs Farmsbio (Farm Hannong), Heulgro Film (Sejin Bio), Vonto Film (Eco-Hansung) as well as a selected PE film were used in this study. For the control, we used crops grown without any kind of mulching. Experimental fields were fertilized according to conventional cultivation methods, tilled, and then covered by either BF or PE. After 1 week, com (cv. MIBECK2ho) at the 3-leaf stage (16 days after seeding) was transplanted. Plant height was measured at 18 and 32 days after transplanting and heading stages. Yield components and yield were also measured at harvest. In addition, pH, EC, and decomposition and light transmittance levels of films were investigated during the experimental period. Daily average temperature, relative humidity and organic matter in soils were also measured during the experimental period. There was no significant difference in plant height, heading date, and silking between crops with BFs and PE, but the crops grown with BFs and PE films reached higher growth parameters in a shorter amount of time than the crops in the non-mulching control. Additionally, there were no significant differences in yield components such as length of ears, ear width, ear weight, and yield in crops that were grown using films or crops in the control plot. Light transmittance and decomposition levels of films generally increased with time after transplanting, and was highest in the Heulgro film than other BFs. Soil pH and organic matter in crops using BFs and PE films were significantly higher than in the control plot at 99 and 113 days after transplanting. In general, the EC contents in the control plot was lower than in crops using BFs and PE films. The average daily moisture in soil was higher when BFs and PE films were used than in the control plot. However, the daily average soil temperature was higher in crops using BFs and PE films than in the control plots at the beginning of the experimental period, but there was no consistent difference in soil temperature towards the later part of the experimental period. Therefore, the BFs used in this study were shown to be helpful without causing negative impacts on the growth and yield of com.

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Production of a New Biosurfactant by a New Yeast Species Isolated from Prunus mume Sieb. et Zucc.

  • Jeong-Seon Kim;Miran Lee;Dae-Won Ki;Soon-Wo Kwon;Young-Joon Ko;Jong-Shik Kim;Bong-Sik Yun;Soo-Jin Kim
    • Journal of Microbiology and Biotechnology
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    • v.33 no.8
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    • pp.1023-1029
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    • 2023
  • Biosurfactants reduce surface and interfacial tension due to their amphiphilic properties and are an eco-friendly alternative for chemical surfactants. In this study, a new yeast strain JAF-11 that produces a biosurfactant was selected using drop collapse method, and the properties of the extracts were investigated. The nucleotide sequences of the strain were compared with closely related strains and identified based on the D1/D2 domain of the large subunit ribosomal DNA (LSU) and internal transcribed spacer (ITS) regions. Neodothiora populina CPC 39399T, the closest species with strain JAF-11, showed a sequence similarity of 97.75% for LSU and 94.27% for ITS, respectively. The result suggests that the strain JAF-11 represents a distinct species that cannot be assigned to any existing genus or species in the family Dothideaceae. Strain JAF-11 produced a biosurfactant reducing the surface tension of water from 72 mN/m to 34.5 mN/m on the sixth day of culture and the result of measuring the critical micelle concentration (CMC) by extracting the crude biosurfactant was found to be 24 mg/l. The molecular weight 502 of the purified biosurfactant was confirmed by measuring the fast atom bombardment mass spectrum. The chemical structure was analyzed by measuring 1H nuclear magnetic resonance (NMR), 13C NMR, and two-dimensional NMRs of the compound. The molecular formula was C26H46O9, and it was composed of one octanoyl group and two hexanoyl groups to myo-inositol moiety. The new biosurfactant is the first report of a compound produced by a new yeast strain, JAF-11.

A Study on the Evaluation of the Adsorption Efficiency of Heavy Metals by the Content of Jellyfish Extract at Immunity Reaction in Alginate bead (알긴산 비드에 혼합된 해파리 면역 반응물질 함량에 따른 중금속 흡착효율 평가에 관한 연구)

  • Jong Hwan Kim;Hyeok Jin Park;Inho Choi;Eunjin Kim;I Song Choi;Jong-Min Oh
    • Journal of Environmental Impact Assessment
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    • v.32 no.6
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    • pp.431-436
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    • 2023
  • As the industry develops, the amount of heavy metals flowing into the ecosystem is increasing. Heavy metals are difficult to decompose and remain in the ecosystem for a long time and cause toxicity, which is removed by physicochemical methods such as adsorption, filtration, and chemical precipitation during water treatment. In this study, Alginate bead was selected as a chelating resin for adsorbing and removing heavy metals, and the Jellyfish Extract at Immunity reaction (JEI) were mixed to evaluate the adsorption efficiency of heavy metals accordingly. beads mixed with JEI showed high adsorption efficiency in lead (79-99%) and copper (64-70%) according to the characteristics of Alginate, and low adsorption efficiency in cadmium (25-37%) and zinc (5-6%). Although heavy metal adsorption did not increase in proportion to the content of JEI, 50% and 100% JEI beads showed significant increases. As a result of applying the reaction rate equation, it was found that it was more suitable for the pseudo-secondary reaction equation than the pseudo-first reaction equation.

Very Short- and Long-Term Prediction Method for Solar Power (초 장단기 통합 태양광 발전량 예측 기법)

  • Mun Seop Yun;Se Ryung Lim;Han Seung Jang
    • The Journal of the Korea institute of electronic communication sciences
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    • v.18 no.6
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    • pp.1143-1150
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    • 2023
  • The global climate crisis and the implementation of low-carbon policies have led to a growing interest in renewable energy and a growing number of related industries. Among them, solar power is attracting attention as a representative eco-friendly energy that does not deplete and does not emit pollutants or greenhouse gases. As a result, the supplement of solar power facility is increasing all over the world. However, solar power is easily affected by the environment such as geography and weather, so accurate solar power forecast is important for stable operation and efficient management. However, it is very hard to predict the exact amount of solar power using statistical methods. In addition, the conventional prediction methods have focused on only short- or long-term prediction, which causes to take long time to obtain various prediction models with different prediction horizons. Therefore, this study utilizes a many-to-many structure of a recurrent neural network (RNN) to integrate short-term and long-term predictions of solar power generation. We compare various RNN-based very short- and long-term prediction methods for solar power in terms of MSE and R2 values.

An Enhanced Water Solubility and Antioxidant Effects of Seed and Pamace of Schisandra chinensis (Turcz.) Baill Formulation by HME (Hot-Melt Extrusion) (HME (Hot-Melt Extrusion)를 이용한 오미자 씨 및 박의 수용성 및 항산화 효과 향상)

  • Eun Ji Go;Min Ji Kang;Min Jun Kim;Jung Dae Lim;Young-Suk Kim;Jong-Min Lim;Min Jeong Cho;Tae Woo Oh;Seokho Kim;Kyeong Tae Kwak;Byeong Yeob Jeon
    • Herbal Formula Science
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    • v.31 no.4
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    • pp.215-230
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    • 2023
  • Objectives : Schisandra chinensis (Turcz.) Baill contains many nutrients and exhibits high physiological functions. It has been shown that Schisandra seed and pamace contains more nutrients than fruits and thus have higher antioxidant efficacy. In this study, seed and pamace of Schisandra chinensis (Turcz.) Baill (SPSC) were treated with hot-melt extrudate (HME) extrusion to produce water-soluble nanoparticles. Methods : SPSC was treated with HME to prepare nanoparticles. In this process, excipients (hydroxypropyl methylcellulose, pullulan, 2-hydroxylpropyl-beta-cyclodextrin, lecithin) were added to prepare a hydrophilic polymer matrix. To compare and analyze the antioxidant effect and schizandrin content, total flavonoid content, total phenol content and ABTS assay were measured. To confirm the effect of increasing the water solubility of the particles, particle size and water solubility index measurements were performed. The molecular of the material was analyzed using Fourier transform infrared spectroscopy (FT-IR). Results : The particle size of HME extrudates decreased, while total phenols, flavonoids, schizandrin, antioxidant effect, and solubility increased. Through FT-IR, it was confirmed that the SPSC and the extrudate exhibit the same chemical properties. In addition, it was confirmed that when extracted with water, it exhibited a higher antioxidant effect than the ethanol extract. Conclusions : HME technology increased the solubility of SPSC, which are processing by-products, and improved their antioxidant effect to a higher degree. It was confirmed that SPSC could be used as an eco-friendly, high value-added material.

A Study on the Au Recoverability from Mongolian Tailings (몽골 광미로부터 Au 회수 가능성에 관한 연구)

  • Ko, Chin-Surk;Burentogtokh, Togtokhmaa;Lee, Jong-Ju;Park, Cheon-Young
    • Korean Journal of Mineralogy and Petrology
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    • v.33 no.1
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    • pp.41-51
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    • 2020
  • The purpose of this study was to investigate the possibility of eco-friendly/efficient recovery of valuable resources, such as Au from mine tailings, which are environmental pollutants in the Mongolian mine sector. For this purpose, this study selected 4 place of mine tailings of the Mongolian mines sector and carried out mineralogy evaluation of the valuable resources in the tailings. In this study, flotation was performed to separate and concentrate valuable resources in the tailings. Microwave nitric acid leaching was used to leach the valuable resources contained in the sample and to improve the Au grade. Chloride leaching attempted to leach Au from the leaching residues. XRD analysis of the tailings samples showed that most of the samples consisted of silicate minerals. As a result of confirming the content of the element through XRF analysis, the SiO2 content was very high, the Fe2O3 content was 2.32-4.23%, and the content of PbO, CuO and ZnO components were all within 2%. As a result of flotation for the tailings samples, the recovery of Au was the highest in Bayanairag sample (95.38%). As a result of microwave nitric solution experiment on Au concentrate sample obtained by flotation, the content of Au in the microwave nitrate leaching residue increased by 12.15% from 192.72 g/ton to 216.14g/ton in Khamo sample, the highest increase was 57.58% in Bayanairag sample. TCLP tests on tailings generated after flotation showed dissolution characteristics within EPA. Chloride leaching test was performed to recover Au from solid residues. The leaching rate was 87.43-89.35% within 10 minutes. For Khamo sample, 100% Au was leached after 60 minutes of leaching time. Therefore, in order to process the tailings continuously generated in Mongolia, applying the same process as the present study is expected to effectively recover the valuable resources contained in the tailings.