• 공업화학
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• 제24권1호
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• pp.104-111
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• 2013

본 연구에서는 생분해성 지방족 폴리에스터 중 비교적 고가인 poly(butylene adipate-co-terephthalate) (PBAT)와 상대적으로 저가의 생분해성 고분자인 polylactic acid (PLA)의 블렌드에 3종류의 개질제를 사용하여 그 효과를 조사하였다. 개질제로는 에폭시계의 커플링제와 diisocyanate계열의 methylenediphenyl 4,4'-diisocyanate (MDI)와 hexamethylene diisocyanate (HDI)를 사용하였다. 여러 가지 조성의 블렌드에 용융흐름지수, 동적 점탄성을 조사하였다. 또한, 인장시험을 통한 기계적 물성 조사와 FE-SEM으로 시편의 파단표면을 관찰하였다. 이를 통해 PLA/PBAT 블렌드의 상용성과 개질제의 효과 및 기계적물성에 미치는 영향을 고찰하였다. 개질제로 HDI를 사용했을 때 PLA/PBAT의 인장물성이 크게 증가하였다.

• 대한조선학회논문집
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• 제38권4호
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• pp.75-82
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• 2001

건조 후 수행하는 수압시험 또는 화물의 적재 등과 같은 정하중은 파랑변동하중에 비하여 선체구조물에 상당히 큰 응력을 유발한다. 이러한 정하중이력에 의하여, 선체구조물의 응력집중으로 인해 피로강도가 문제되는 용접이음부에서는, 재료의 탄소성 거동에 의하여 초기용접잔류응력이 상당히 이완될 것으로 예상된다. 따라서, 이러한 용접이음부의 피로강도를 평가할 때에는 이완된 잔류응력의 영향을 고려하는 것이 보다 합리적이다. 본 연구에서는 선체구조물의 여러 가지 용접형태 중 Padding plate가 용접된 형태에 대하여 정하중이력($0.5{\sigma}Y,\;0.85{\sigma}Y$)에 의한 초기 용접잔류응력의 변화를 측정하며, 잔류응력의 변화가 피로강도에 미치는 영향을 검토한다.

• 한국해양공학회지
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• 제29권3호
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• pp.241-248
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• 2015

A subsea pipeline for oil/gas transportation or gas injection is subjected to extreme variations in internal pressure and temperature, which can involve a strain rate effect on the pipeline material. This paper describes the flow stress characteristics of a pipeline material called API 5L X52N PSL2, using and experimental approach. High-speed tensile tests were carried out for two metal samples taken from the base and weld parts. The target temperature was 100℃, but two other temperature levels of –20℃and 0℃ were taken into account. Three strain rates were also considered for each temperature level: quasi static, 1/s, and 10/s. Flow stress data were proposed for each temperature level according to these strain rates. The dynamic hardening behaviors of the base and weld metals appeared to be nonlinear on the log-scale strain rate axis. A very high material constant value was required for the Cowper-Symonds constitutive equation to support the experimental results.

• Nuclear Engineering and Technology
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• 제50권2호
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• pp.218-222
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• 2018

An oxide-dispersion-strengthened (ODS) layer was formed on Zircaloy-4 tubes by a laser beam scanning process to increase mechanical strength. Laser beam was used to scan the yttrium oxide ($Y_2O_3$)-coated Zircaloy-4 tube to induce the penetration of $Y_2O_3$ particles into Zircaloy-4. Laser surface treatment resulted in the formation of an ODS layer as well as microstructural phase transformation at the surface of the tube. The mechanical strength of Zircaloy-4 increased with the formation of the ODS layer. The ring-tensile strength of Zircaloy-4 increased from 790 to 870 MPa at room temperature, from 500 to 575 MPa at $380^{\circ}C$, and from 385 to 470 MPa at $500^{\circ}C$. Strengthening became more effective as the test temperature increased. It was noted that brittle fracture occurred at room temperature, which was not observed at elevated temperatures. Resistance to dynamic high-temperature bursting improved. The burst temperature increased from 760 to $830^{\circ}C$ at a heating rate of $5^{\circ}C/s$ and internal pressure of 8.3 MPa. The burst opening was also smaller than those in fresh Zircaloy-4 tubes. This method is expected to enhance the safety of Zr fuel cladding tubes owing to the improvement of their mechanical properties.

• Elastomers and Composites
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• 제56권4호
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• pp.209-216
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• 2021

In this study, we observed the mechanical properties, thermal stability, and low temperature sealing performance of fluorosilicone elastic composites. When the blend ratio of Phenyl vinyl methyl silicone (PVMQ) was increased, the tensile strength, modulus at 100%, and compression set were decreased. The thermal stability of fluorosilicone elastic composites showed a similar tendency. These were caused by poorer green strength of PVMQ than Fluorosilicone rubber (FVMQ). The change in the tensile strength and elongation at -40℃ showed a decreasing tendency with increasing PVMQ blend ratio. By increasing the PVMQ blend ratio, low-temperature performance was improved. The Dynamic mechanical analysis (DMA) results showed that T_g was decreased and low-temperature performance was improved with increasing PVMQ blend ratio. However tanδ was decreased becaused of the poor green strength and elasticity of PVMQ. From a hysteresis loss at -40℃, the hysteresis loss value was increased and fluorosilicone elastic composites showed the decreasing tendency of elasticity with increasing PVMQ blend ratio. From the TR test, TR10 was decreased with increasing PVMQ blend ratio. FS-4 (45% PVMQ blended composites) showed a TR10 of -68.0℃ that was 5℃ lower than that of FS-1 (100% FVMQ). The gas leakage temperature was decreased with increasing PVMQ blend ratio. The gas leakage temperature of FS-4 was -69.2℃ that was 5℃ lower than that of FS-1. Caused by the polymer chain started to transfer from a glassy state to a rubbery state and had a mobility of chain under T_g, the gas leakage temperature showed a lower value than T_g. The sealing performance at low temperature was dominated by T_g that directly affected the mobility of the polymer chain.

• Geomechanics and Engineering
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• 제25권3호
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• pp.195-205
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• 2021

Time effect on the deformation and strength characteristics of geogrid reinforced sand retaining wall has become an important issue in geotechnical and transportation engineering. Three physical model tests on geogrid reinforced sand retaining walls performed under various loading conditions were simulated to study their rate-dependent behaviors, using the presented nonlinear finite element method (FEM) analysis procedure. This FEM was based on the dynamic relaxation method and return mapping scheme, in which the combined effects of the rate-dependent behaviors of both the backfill soil and the geosynthetic reinforcement have been included. The rate-dependent behaviors of sands and geogrids should be attributed to the viscous property of materials, which can be described by the unified three-component elasto-viscoplastic constitutive model. By comparing the FEM simulations and the test results, it can be found that the present FEM was able to be successfully extended to the boundary value problems of geosynthetic reinforced soil retaining walls. The deformation and strength characteristics of the geogrid reinforced sand retaining walls can be well reproduced. Loading rate effect, the trends of jump in footing pressure upon the step-changes in the loading rate, occurred not only on sands and geogrids but also on geogrid reinforced sands retaining walls. The lateral earth pressure distributions against the back of retaining wall, the local tensile force in the geogrid arranged in the retaining wall and the local stresses beneath the footing under various loading conditions can also be predicted well in the FEM simulations.

• 대한토목학회논문집
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• 제8권1호
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• pp.173-185
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• 1988

철근콘크리트 보의 전단피로거동(剪斷疲勞擧動)에 관(關)해 실험적(實驗的)인 연구(硏究)를 실시하여, 수치해석(數値解析) 결과(結果)와 비교(比較) 검토하였다. 전단실험(剪斷實驗)은 정적실험(靜的實驗)과 피로파괴실험(疲勞破壞實驗)으로 구별하였는데, 정적실험(靜的實驗)에서는 3가지 경우의 시험부재(試驗部材) 4개를 제작하여 실험한 결과, 응력과 스터럽의 변형률 관계를 관찰하였고, 피로파괴실험(疲勞破壞實驗)에서는 4가지 경우의 시험부재(試驗部材) 11개를 제작하여 실험한 결과, 하중-중앙처짐 관계와 하중-인장철근 변형률 관계 그리고, 하중-스터럽의 변형률 관계를 관찰하였다. 100 만회(萬回)에 대한 부재(部材)의 피로강도(疲勞强度)는 정적극한강도(靜的極限强度)의 약 65%임을 확인할 수 있었다.

• 한국자동차공학회논문집
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• 제18권1호
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• pp.127-130
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• 2010

This paper deals with the formability of DP590 steel considering the strain rate. The strain hardening coefficient, elongation and r-value were obtained from the static and dynamic tensile test. As strain rate increases from static to 100/s, the strain hardening coefficient and the uniform elongation decrease and the elongation at fracture and r-value decrease to 0.1/s and increase again to 100/s. The high speed forming limit tests with hemi-spherical punch were carried out using the high speed crash testing machine and high speed forming jig. The high speed forming limit of DP590(order of $10^2$/s) decreases compared to the static forming limit(order of $10^{-3}$/s) and the forming limit band in high speed forming test is narrower than that in the static forming test. This tendency may be due to the development of brittleness with increase of stain rate.

• 접착 및 계면
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• 제6권2호
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• pp.13-20
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• 2005

환경 친화적인 자연섬유 강화 고분자 복합재료의 계면 전단강도는 총체적인 기계적 물성을 조절하는데 매우 중요한 역할을 수행한다. Ramie와 Kenaf 섬유 강화 에폭시 복합재료의 계면 전단강도는 최종 물성을 위한 최적 조건을 찾아내기 위해 미세역학시험법과 비파괴 음향방출시험을 이용하여 평가했다. Ramie와 Kenaf 섬유의 동적 접촉각을 측정했고, 계면 접착에서 젖음성과 상호 관련시켜서 해석하였다. Ramie와 Kenaf 섬유의 기계적 물성은 단섬유 인장시험을 통해 조사했고, 통계학적으로 uni-와 bimodal Weibull 분포를 통해서 분석하였다. Ramie와 Kenaf 섬유에 대한 실제 신장율의 clamping 효과의 영향도 평가할 수 있었다. 두 가지의 다른 미세파괴 형상은 섬유다발과 단섬유 복합재료로부터 오는 축방향의 debonding과 섬유상의 fracture는 인장과 압축하중하에서 관찰할 수 있었다.

• Corrosion Science and Technology
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• 제20권1호
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• pp.26-36
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• 2021

Pipes operating in the seawater environment faces cavitation degradation and corrosion of the metallic component, as well as a negative synergistic effect. Cavitation degradation shows the mechanism by which materials deteriorate by causing rapid change of pressure or high-frequency vibration in the solution, and introducing the formation and explosion of bubbles. In order to rate the cavitation resistance of materials, constant conditions have been used. However, while a dynamic cavitation condition can be generated in a real system, there has been little reported on the effect of ultrasonic amplitude on the cavitation resistance and mechanism of composites. In this work, 3 kinds of epoxy coatings were used, and the cavitation resistance of the epoxy coatings was evaluated in 3.5% NaCl at 15 ℃ using an indirect ultrasonic cavitation method. Eleven kinds of mechanical properties were obtained, namely compressive strength, flexural strength and modulus, tensile strength and elongation, Shore D hardness, water absorptivity, impact test, wear test for coating only and pull-off strength for epoxy coating/carbon steel or epoxy coating/rubber/carbon steel. The cavitation erosion mechanism of epoxy coatings was discussed on the basis of the mechanical properties and the effect of ultrasonic amplitude on the degradation of coatings.