• Title/Summary/Keyword: Dyes and dyeing

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Dyeing Properties of Nylon 66 Nano Fiber with High Molecular Mass Acid Dyes

  • Lee Kwon Sun;Lee Beom Soo;Park Young Hwan;Park Yoon Chul;Kim Yong Min;Jeong Sung Hoon;Kim Sung Dong
    • Fibers and Polymers
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    • v.6 no.1
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    • pp.35-41
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    • 2005
  • Research and development of nano fiber products is very active over the world. Physical characteristics and dyeing properties of nylon 66 nano fiber were investigated in this study. X-ray diffraction, DSC, analysis of amino end group, and water absorption were performed to get information concerning physical properties of nano fiber. Nylon 66 nano fiber was dyed with high molecular mass acid dyes. Effects of dyeing temperature, pH of dyeing solution, and concentration of acid dyes on dyeing properties such as rate of dyeing and the extent of exhaustion, were examined and compared to those of regu­lar fiber. It was found that nano fiber adsorbed acid dyes at lower temperature, got rapidly dyed, and its extents of exhaustion at specific dyeing temperature were higher than regular fiber. It was also observed that nano fiber could adsorb a large amount of acid dye without a significant loss in the extent of exhaustion. Washing fastness of the dyed nano fiber was lower by $1/2\~1$ grade, light fastness by 1 grade than the dyed regular fiber.

A Study on the Dyeability of Natural Dyes of Sustainable Seaweed-Containing Fiber (지속 가능한 해초 함유 섬유의 천연염료 염색성에 관한 연구)

  • Kim, Sojin;Choi, Kyoungmi
    • Journal of Fashion Business
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    • v.26 no.3
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    • pp.87-97
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    • 2022
  • This study investigated the dyeability and color change of the natural dyes of SeaCell, a biodegradable functional fiber that is permanently added to cellulose fibers with natural additives extracted from seaweeds. The natural dyes used in the study are five dyes. Gardenia and turmeric, which are yellow-based natural dyes, Sappan wood and Lac, which are red-based natural dyes, and Indigo, a blue-based natural dye, were selected. The dyeability and color change according to the change of the mordant conditions and the number of times of dyeing were investigated. In addition, the dyeing properties and colors of cotton and silk fibers were compared under the same dyeing conditions as SeaCell. The study results are as follows. It was found that SeaCell had lower dyeing properties than silk, a protein fiber, in gardenia, sappan wood, and lac dyes, but had higher dyeing properties than cotton with the same cellulose component as SeaCell fibers. In the case of turmeric, it showed higher dyeing properties than cotton except for the no mordant condition. In the case of Indigo dye, SeaCell shows the best dyeability, indicating that it is a very suitable fiber for Indigo dyeing. As sustainable functional fibers are continuously developed in the future, natural dyes that are environmentally friendly and human-friendly are actively introduced and commercialized, and it is expected that they can be used as reference materials.

Study of Dyeing Properties by Swelling Agent on meta-aramid Fiber with Cationic Dyes (Swelling agent에 따른 메타계 아라미드 섬유의 Cationic dye 염색특성)

  • Kim, Eun-Mi;Park, Chung-Won;Choi, Jae-Hong
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.1-7
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    • 2012
  • Dyeing and fastness characteristics of 100% meta-aramid fiber were investigated with cationic dyes and swelling agents under various dyeing conditions such as dyeing temperature and pH of dye bath. Dye exhaustion started at around $80^{\circ}C$ and settled down at $130^{\circ}C$. Among swelling agents used, N-methyl formanilide showed comparatively higher K/S values comparing to 1-phenoxypropan-2-ol. Under weak acidic conditions in the range pH 5 to 7, the exhaustion of cationic dyes could be enhanced leading to higher adsorption and stability of colorimetric property. Wash and rubbing fastness were generally good but low light fastness found can be attributable to the poor photo-stability of the cationic dyes.

The Dyeing Properties of Poly(trimethylene terephthalate) by Disperse Dyes with Different Energy Level (Energy Level이 다른 분산염료를 이용한 Poly(trimethylene terephthalate)섬유의 염색성)

  • 백지연;김정렬;이난형;윤태희;김삼수
    • Textile Coloration and Finishing
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    • v.15 no.5
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    • pp.316-320
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    • 2003
  • In order to investigate the dyeing property of poly trimethylene terephthalate(PTT) fabric, the dyeing of PTT fabric was carried at under condition of different dyeing temperature by using several disperse dyes with different energy level. Particularly, this study discussed the PTT dyeing thermodynamically. Used disperse dyes were selected based on the their chemical structure and energy level. The obtained results were as followings; The dye adsorption of S type disperse dye such as C. I. Disperse Blue 79 increased with increasing dyeing temperature. In a exhaustion rate of PTT fabric with disperse dyes, C. I. Disperse Blue 56 showed higher values than that of C. I. Disperse Orange 29 and Blue 79. For the interpretation of thermodynamic dyeing behavior, the partition coefficient ( K ) and some several thermodynamic parameters such as standard affinity$(-\mu^\circ)$ and heat of dyeing$(\Delta{H}^\circ)$ calculated from the adsorption isotherm. From above results, as the energy level of disperse dye is small, the partition coefficient and standard affinity increased. But the heat of dyeing of PTT fabric with disperse dye showed high negative value in order of E type(C. I. Disperse Blue 56), SE type(C. I. Disperse Orange 29) and S type(C. I. Disperse 79).

A Study on the Dyeing of Polyester Fiber in Alkaline Dyebath ―Dyeing Properties of Disperse dyes According to variation of pH values― (폴리에스테르섬유의 알칼리욕염색에 관한 연구 -pH변화에 따른 분산염료의 염색성을 중심으로-)

  • Sung, Woo Kyung;Ryu, Ki Hyo;Park, Soo Min;Kim, Kyung Hwan
    • Textile Coloration and Finishing
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    • v.8 no.1
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    • pp.34-42
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    • 1996
  • This Study was made to investigate alkaline dyeing systems for a new dyeing applicable polyester fibers. Disperse dyes for dyeing of polyester fibers were C.I. Red 60, Blue 56 and Yellow 54 as three primary colors of E type which used widely on the scene. Dyeing properties of dispers dyes on the polyester fibers are discussed according to variation of pH values for application of alkaline dyeing method compared with to ordinary acidic dyebath. Alkaline pH of the dyebath was controlled to pH 9 and 10.5 with buffer solutions using each hydrochloride and disodiumtetraborate, disodiumtetraborate and sodium hydroxide to promote the reproducibility of dyeing. Dyeing properties of dispers dyes on the polyester fibers by alkaline dyeing method compared with to ordinary acidic dyebath were discussed by estimation of color, wash-fastness, bleeding and migration of dyed polyester fabric.

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Dyeing and Crosslinking of Chitosan Fibers with $\alpha$-Bromoacrylamide Reactive Dyes ($\alpha$-Bromoacrylamide계 반응염료에 의한 키토산 섬유의 염색 및 가교)

  • 박병기;박봉수;정용식;이근완
    • Textile Coloration and Finishing
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    • v.14 no.3
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    • pp.26-33
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    • 2002
  • Dyeing properties and crosslinking effect of bifunctional reactive dyes on chitosan fiber were investigated to improve the stability of chitosan fiber against the mild acidic solution and the wet processing. Chitosan fibers were crosslinked with epichlorohydrin for comparing purpose, and dyed with C. I. Reactive Red 194, C. I. Reactive Blue 50, and the reactive dye having two $\alpha$-bromoacrylamide groups at various concentrations. The initial dyeing rates of reactive dyes are rapid and chitosan fibers absorb the relatively large amount of dyes. The chitosan fibers dyed with these dyes show the low degree of swelling and the low solubility in 1 % acetic acid solution and also represent the higher thermal stability The reactive dye with two $\alpha$-bromoacrylamide groups shows higher crosslinking effect than other dyes.

Dyeing of High Strength and High Molecular Weight Polyethylene Fiber Using Super Hydrophobic Red Fluorescence Dyes (고강도/고분자량 폴리에틸렌 섬유의 적색 초소수성 형광염료 염색)

  • Kim, Taegun;Lee, Junheon;Park, Jihoon;Kim, Taekyeong
    • Textile Coloration and Finishing
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    • v.30 no.4
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    • pp.237-244
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    • 2018
  • Three super hydrophobic red fluorescence dyes were selected to dye high molecular weight polyethylene fiber. Their absorbance and emission spectra were obtained and Stokes' shift was measured. Fluorescence emission strength of the dyes on the fiber was investigated and therefore Fluoro Red 3 was determined as the best one among those three dyes in this experiment. Dyeing properties and fluorescence intensities were investigated using the Fluoro Red 3 on high molecular weight polyethylene fiber at various dyeing conditions. The optimum concentration of a dispersing agent was appeared at 10wt% in aqueous solution. The best dyeing was obtained at $125^{\circ}C$ for 1 hour. The color fastnesses to the washing and rubbing were as high as ratings 4~5, however, the fastness to light was exhibited ratings 2~3.

A Study on the Dyeing according to Kinds of Loess (황토 종류에 따른 염색성 연구)

  • 강영의;박순옥
    • Textile Coloration and Finishing
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    • v.15 no.6
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    • pp.39-46
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    • 2003
  • The experiments about dyeing concentration, temperature and time were done using yellow, red and purple loess as natural inorganic dyes in order to verify a degree of dyeing, characteristics of color and fastness. The results were as following; 1. As a result of analyzing components of loess, purple loess was much than other loess in quartz component and coarse particles contained. This affected to the degree of dyeing. 2. The stronger dyeing concentration was, the more the degree of dyeing was improved, and yellow loess containing fine particles was the best in the degree of dyeing. 3. When it was dyed with raising up to $100^\circ{C}$ for 10 minutes after stirring for 20 minutes at $60^\circ{C}$, was better than on starting at $40^\circ{C}$ or $80^\circ{C}$ in the degree of dyeing. Also yellow loess was the best in these experiments. 4. Washing fastness of loess was low such as other natural dyes, but dyeing wasn't transferred to other textiles. On the other hand, light fastness of it was very excellent and rubbing fastness was relatively good as 3~3.5.

Reuse of Sodium Sulfate Recovered from Farm Drainage Salt as Dyeing Builder of Levelling Dyes - Analysis of Color Difference -

  • Jung, Jiyoon
    • The International Journal of Costume Culture
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    • v.6 no.1
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    • pp.11-18
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    • 2003
  • Agricultural drainage salt generated during irrigation of crops in San Joaquin Valley, California, exceeds 600,000 tons annually and cumulates in the field in a rapid rate. As a result, the waste is taking out more farmlands for salt storage and disposal, imposing serious concerns to environment and local agricultural industry. In searching for a potential solution to reduce or eliminate the waste, this research explored feasibility of producing a value-added product, sodium sulfate, from the waste and utilizing the product in textile dyeing. The results indicated that sodium sulfate could be produced from the salt and could be purified by a recrystallization method in a temperature range within the highest and lowest daily temperatures in summer in the valley. The recovered sodium sulfate samples, with purities ranging from 67% to 99.91, were compared with commercially available sodium sulfate in the dyeing of levelling dyes. In nylon fabrics, the salt samples had little color difference in the dyeing with C.I. Acid Yellow 23 and C.I. Acid Blue 158. All salt samples' gray scale was 5 grade. In wool fabrics, the salt samples had little color difference in dyeing with C.I. Acid Yellow 23 and C.I. Arid Blue 158. All salt samples' gray scale was 5 grade. Generally, the dyeing of levelling dyes using recovered salts from farm drainage had little color difference than the dyeing of levelling dyes using commercial sodium sulfate.

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Dyeing of Nylon/Cotton Blend with Acid Dyes Using Sodium 2-(2,3- dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino)-benzenesulfonate (Sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino)-benzenesulfonate를 이용한 나일론/면 복합소재의 단일 산성염료 일욕염색)

  • Kim, Mi-Kyung;Yoon, Nam-Sik;Kim, Tae-Kyeong
    • Textile Coloration and Finishing
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    • v.24 no.1
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    • pp.8-17
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    • 2012
  • In order to dye nylon/cotton blended fabrics in solid colors with only acid dyes, a hetero-bifunctional bridge compound (DBDCBS) was examined. The bridge compound was designed to react only onto cotton fabrics first, on which amino-containing acid dyes react later by covalent bonding. By the effect of DBDCBS, amino-containing acid dyes exhibited high affinity toward the cotton fabrics. From the dyeing properties examined at various conditions, the optimum dyeing was decided at pH 4 and $100^{\circ}C$. Consequently, the solid color was obtained on nylon/cotton blended fabrics in one bath dyeing process using only acid dyes. The DBDCBS did not show any negative effect on nylon side in terms of dyeing and physical properties.