Textile Coloration and Finishing (한국염색가공학회지)

The Korean Society of Dyers and Finishers (한국염색가공학회)
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Dyeing of High Strength and High Molecular Weight Polyethylene Fiber Using Super Hydrophobic Red Fluorescence Dyes

고강도/고분자량 폴리에틸렌 섬유의 적색 초소수성 형광염료 염색

  • Kim, Taegun (Department of Textile System Engineering, Kyungpook National University) ;
  • Lee, Junheon (Department of Textile System Engineering, Kyungpook National University) ;
  • Park, Jihoon (Department of Textile System Engineering, Kyungpook National University) ;
  • Kim, Taekyeong (Department of Textile System Engineering, Kyungpook National University)
  • 김태건 (경북대학교 섬유시스템공학과) ;
  • 이준헌 (경북대학교 섬유시스템공학과) ;
  • 박지훈 (경북대학교 섬유시스템공학과) ;
  • 김태경 (경북대학교 섬유시스템공학과)
  • Received : 2018.11.21
  • Accepted : 2018.12.11
  • Published : 2018.12.27
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Abstract

Three super hydrophobic red fluorescence dyes were selected to dye high molecular weight polyethylene fiber. Their absorbance and emission spectra were obtained and Stokes' shift was measured. Fluorescence emission strength of the dyes on the fiber was investigated and therefore Fluoro Red 3 was determined as the best one among those three dyes in this experiment. Dyeing properties and fluorescence intensities were investigated using the Fluoro Red 3 on high molecular weight polyethylene fiber at various dyeing conditions. The optimum concentration of a dispersing agent was appeared at 10wt% in aqueous solution. The best dyeing was obtained at $125^{\circ}C$ for 1 hour. The color fastnesses to the washing and rubbing were as high as ratings 4~5, however, the fastness to light was exhibited ratings 2~3.

Keywords

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Figure 1. Chemical structure of super hydrophobic fluorescence red dyes used in this study.

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Figure 2. Absorbance and emission spectra of super hydrophobic fluorescence red dyes.

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Figure 3. Color strength(K/S) and fluorescence intensity of the super hydrophobic fluorescence red dyes on the HMWPE fiber.

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Figure 4. Color strength(K/S at λmax) and fluorescence intensity of the Fluoro Red 3 on HMWPE fiber at 125℃ for 1 hour according to the concentration of dispersing agent.

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Figure 5.Color strength(K/S at λmax) and fluorescence intensity of the Fluoro Red 3 on HMWPE fiber according to the dyeing temperature for 1 hour.

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Figure 6. Color strength(K/S at λmax) and fluorescence intensity of the Fluoro Red 3 on HMWPE fiber at 125℃ according to the dyeing time.

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Figure 7. Color strength(K/S at λmax) and fluorescence intensity of the Fluoro Red 3 on HMWPE fiber at 125℃ for 1 hour according to the concentration of dye.

Table 1. Color fastness of the HMWPE fiber dyed with the Fluoro Red 3 at 125℃ for 1 hour

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References

  1. J. U. Choi, M. H. Jee, M. H. Lee, J. S. Lee, and D. H. Baik, Structure and Property Relations in Heat-treated para-Aramid Fibers, Textile Science and Engineering, 47(1), 15(2010).
  2. H. J. Lee, J. S. Won, S. C. Lim, T. S. Lee, J. Y. Yoon, and S. G. Lee, Preparation and Characterization of PAN based Carbon Fiber with Carbonization Temperature, Textile Science and Engineering, 53(2), 103(2016). https://doi.org/10.12772/TSE.2016.53.103
  3. H. E. Khaljiri, R. E. Farsani, andK. A. Banaie, The Evaluation of the Thermal and Mechanical Properties of Aramid/Semi-Carbon Fibers Hybrid Composites, Fibers and Polymers, 18(2), 296(2017). https://doi.org/10.1007/s12221-017-6442-2
  4. L. Yao, C. Lee, and J. Kim, Fabrication of Electrospun meta-Aramid Nanofibers in Different Solvent Systems, Fibers and Polymers, 11(7), 1032(2010). https://doi.org/10.1007/s12221-010-1032-6
  5. M. An, H. Xu, Y. Lv, Q. Gu, and Z. Wang, Structural Difference of Gel-spun Ultra-high Molecular Weight Polyethylene Fibers Affected by Cold Drawing Process, Fibers and Polymers, 18(3), 549(2017). https://doi.org/10.1007/s12221-017-6399-1
  6. M. Bartusch, R. D. Hund, H. Hund, and C. Cheri, Surface Functionalisation of UHMW Polyethylene Textile with Atmospheric Pressure Plasma, Fibers and Polymers, 15(4), 736(2014). https://doi.org/10.1007/s12221-014-0736-4
  7. S. J. Kim, D. Kwak, and Y. Chae, Coloration of Ultra High Molecular Weight Polyethylene Fibers Using Alkyl-substituted Anthraquinoid Blue Dyes, Fibers and Polymers, 13(2), 212(2012). https://doi.org/10.1007/s12221-012-0212-y
  8. D. Kwak and T. Kim, Dyeing of Ultra High Molecular Weight Polyethylene Fiberswith Diaminoanthraquinoid Blue Disperse Dyes Having Linear Long Alkyl Substituents, Textile Coloration and Finishing, 24(3), 180 (2012). https://doi.org/10.5764/TCF.2012.24.3.180
  9. N. Jo, J. Lee, and T. Kim, Synthesis of Bluish-green Dyes for Pure Polyolefin Fibers, Textile Coloration and Finishing, 28(3), 156(2016). https://doi.org/10.5764/TCF.2016.28.3.156
  10. T. Kim and M. Ryu, Synthesis of Super Hydrophobic Orange Dyes Having Maximum Absorption at 450- 500nm for Pure Polyolefin Fibers, Textile Coloration and Finishing, 26(3), 165(2014). https://doi.org/10.5764/TCF.2014.26.3.165
  11. T. Kim, J. Park, J. Lee, and T. Kim, Dyeing of High Strength and High Molecular Weight Polyethylene Fiber Using Super Hydrophobic Fluorescence Dyes, Textile Coloration and Finishing, 29(4), 223(2017). https://doi.org/10.5764/TCF.2017.29.4.223
  12. H. Zollinger, "Color Chemistry", Wiley-VCH, Weinheim, pp.34-37, 2003.
  13. J. Yanga, X. Wang, X. Wang, and L. Xu, The Synthesis and Spectral Properties of Novel 4-phenylacetylene-1,8-naphthalimide Derivatives, Dyes and Pigments, 66, 83(2005). https://doi.org/10.1016/j.dyepig.2004.07.015
  14. C. Jianzhong, H. Suh, and S. Kim, Synthesis and Properties of Conjugated Copolymerswith 2-pyran-4-ylidene Malononitrile, Dyes and Pigments, 68, 75(2006). https://doi.org/10.1016/j.dyepig.2005.01.002
  15. O. Oter, K. Ertekin, C. Kirilmis, M. Koca, and M. Ahmedzade, Characterization of a Newly Synthesized Fluorescent Benzofuran Derivative and Usage as a Selective Fiber Optic Sensor for Fe(III), Sensors and Actuators B, 122, 450(2007). https://doi.org/10.1016/j.snb.2006.06.010
  16. J. R. Lakowicz, J. Malicka, S. Dauria, and I. Gryczynski, Release of the Self-quenching of Fluorescence Near Silver Metallic Surfaces, Analytical Biochemistry, 320, 13(2003). https://doi.org/10.1016/S0003-2697(03)00351-8