• Title/Summary/Keyword: Dye analysis

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Study on the Thermal Analysis of Dyed Hair Depending on the Brightness Level (명도 차이에 따른 염색모발의 열분석에 관한 연구)

  • Kim, Moon-Sun;Lee, Gui-Young;Choi, Eun-Young;Kim, Dong-Heui;Chang, Byung-Soo
    • Applied Microscopy
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    • v.38 no.3
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    • pp.159-165
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    • 2008
  • Morphological and physicochemical changes of a woman's virgin hair treated with various dye depths were investigated by using scanning electron microscopy and thermal analyzer. With the hair treated with the dye of the high brightness level, the speed of weight decrease was slower than compared with thermal analysis weight of a normal hair sample. We confirmed that the moisture content and protein composition of hair were changed depending on level depth of coloring agent. Moreover oxidative residues and dye molecules penetrated into the hair cause chemical changes of hair structure. As a result, the heat reaction speed of hair treated with high level coloring agent was made slower than normal hair.

Study of Simultaneous Analysis of Indicator Components of DTP(Digital Textile Printing) Textile Products Using HPLC-MS/MS - Focusing on Natural Dyes - (HPLC-MS/MS를 활용한 DTP(Digital Textile Printing) 제품의 지표성분 동시분석법 연구 - 천연염료를 중심으로 -)

  • Lee, Wonkyoung;Sung, Eunji;Moon, Joung Ryul;Kim, Miji;Kim, Jonghoon
    • Fashion & Textile Research Journal
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    • v.23 no.6
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    • pp.844-851
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    • 2021
  • Due to the increase in consumers' interest about well-being, interest in eco-friendly products has been increasing due to the harmful effects of various harmful substances contained in textile products and environmental issues. As a result, natural dyes of less potential risk than synthetic dyes and digital textile printing(DTP) textile products with less environmental pollution are drawing attention. However, due to the lack of evaluation criteria for DTP textile products with natural ink and the nature of many colors are stacked layer by layer for dying, the need for simultaneous analysis is emerging. To evaluate whether the natural dye is derived from natural ingredients, the biocarbon content is analyzed. However, in the case of ink made using natural dyes and DTP textile products using natural ink, it is difficult to analyze the biocarbon content due to the limitation of the presence of a small amount of dye contained therein. In this study, we were shown the possibility of natural derived verification by cross-checking the analytes of natural dyes (Persicaria tinctoria, an indigo dye; Dactylopius coccus, a light red; and Curcum longa L., i.e., turmeric) and natural ink with HPLC-MS/MS. The coefficient of determination was 0.999 or higher, the limit of quantification was 0.647-3.664 ㎍/L and a %RSD of each indicator material was less than 10. Then, the extraction amount of natural dyes for five patterned fabrics was analyzed.

Surface Temperature Measurement in Microscale with Temperature Sensitive Fluorescence (온도 민감 형광을 이용한 마이크로 스케일 표면온도 측정)

  • Jung Woonseop;Kim Sungwook;Kim Ho-Young;Yoo Jung Yul
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.2 s.245
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    • pp.153-160
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    • 2006
  • A technique for measuring surface temperature field in micro scale is newly proposed, which uses temperature-sensitive fluorescent (TSF) dye coated on the surface and is easily implemented with a fluorescence microscope and a CCD camera. The TSF dye is chosen among mixtures of various chemical compositions including rhodamine B as the fluorescent dye to be most sensitive to temperature change. In order to examine the effectiveness of this temperature measurement technique, numerical analysis and experiment on transient conduction heat transfer for two different substrate materials, i. e., silicon and glass, are performed. In the experiment, to accurately measure the temperature with high resolution temperature calibration curves were obtained with very fine spatial units. The experimental results agree qualitatively well with the numerical data in the silicon and glass substrate cases so that the present temperature measurement method proves to be quite reliable. In addition, it is noteworthy that the glass substrate is more appropriate to be used as thermally-insulating locally-heating heater in micro thermal devices. This fact is identified in the temperature measuring experiment on the locally-heating heaters made on the wafer of silicon and glass substrates. Accordingly, this technique is capable of accurate and non-intrusive high-resolution measurement of temperature field in microscale.

Immediate Effects of Low-Dye Taping on the Ankle Motion and Ground Reaction Forces in the Pronated Rear-Foot During Gait

  • Kim, Sung-shin;Chung, Jae-yeop
    • Physical Therapy Korea
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    • v.23 no.1
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    • pp.72-79
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    • 2016
  • Background: Increased foot pronation causes biomedchanical changes at the lower limbs, which may result in musculoskeletal injuries at the proximal joints. Pronation rear-foot leads to plantar fasciitis, Achilles tendonitis, and posterior tibial tendonitis pathologically. According to the recent meta-analysis, They showed that therapeutic adhesive taping is more effective than foot orthoses and motion control footwear, low-Dye (LD) taping has become the most popular method used by physiotherapists. Objects: The purpose of this study was to determine the immediate effects of LD taping results in different ankle motion and ground reaction force (GRF) as before and after applied LD taping on pronated rear-foot during gait. Methods: Twenty-four participants were recruited for this study. The gait data were recorded using an 8-camera motion capture system and two force platforms. At first, the experiments were carried out that participants walked barefoot without LD taping. And then they walked both feet was applied LD taping. Results: The ankle inversion minimum was significantly greater after LD taping than before LD taping (p=.04); however, in the GRF, there were no significant differences in the inversion maximum or total motion of the stance phase (p=.33, p=.07), or in the vertical (p=.33), posterior (p=.22), and lateral (p=.14) peak forces. Conclusion: The application of taping to pronation rear-foot assists in increased ankle inversion.

Properties of the Dye Sensitized Solar Cell with Localized Surface Plasmon Resonance Inducing Au Nano Thin Films

  • Noh, Yunyoung;Kim, Kwangbae;Choi, Minkyoung;Song, Ohsung
    • Korean Journal of Materials Research
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    • v.26 no.8
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    • pp.417-421
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    • 2016
  • We improve the energy conversion efficiency (ECE) of a dye sensitized solar cell (DSSC) by preparing a working electrode (WE) with localized surface plasmon resonance (LSPR) by inducing Au thin films with thickness of 0.0 to 5.0 nm, deposited via sputtering. Field emission scanning electron microscopy and atomic force microscopy were used to characterize the microstructure of the blocking layer (BL) of the Au thin films. Micro-Raman measurement was employed to confirm the LSPR effect, and a solar simulator and potentiostat were used to evaluate the photovoltaic properties, including the impedance and the I-V of the DSSC of the Au thin films. The results of the microstructural analysis confirmed that nano-sized Au agglomerates were present at certain thicknesses. The photovoltaic results show that the ECE reached a value of 5.34% with a 1-nm thick-Au thin film compared to the value of 5.15 % without the Au thin film. This improvement was a result of the increase in the LSPR of the $TiO_2$ layer that resulted from the Au thin film coating. Our results imply that the ECE of a DSSC may be improved by coating with a proper thickness of Au thin film on the BL.

Photocatalytic Activity of EG-TiO2 Composite for Various Dye Solutions Under UV Light and Visible Light

  • Go, Yu-Gyoung;Kwon, Ho-Joung;Chen, Ming-Liang;Zhang, Feng-Jun;Oh, Won-Chun
    • Korean Journal of Materials Research
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    • v.19 no.10
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    • pp.555-561
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    • 2009
  • Expanded graphite (EG) is synthesized by chemical intercalation of natural graphite (NG) and rapid expansion at high temperature, with titanium n-butoxide (TNB) used as titanium source by a sol-gel method to prepare EG-TiO$_2$ composite. The performances of the prepared EG-TiO$_2$ composite are characterized by BET surface area measurement, scanning electron microscopy (SEM), X-ray diffraction patterns (XRD) and energy dispersive X-ray analysis (EDX). To compare the photocatalytic activities of the EG-TiO$_2$ composite, three kinds of dye solutions, methylene blue (MB), methylene orange (MO) and rhodamine B (RhB), and two kinds of light source, UV light and visible light (VL), are used. Comparing the results, it can be clearly seen that the degradation of all of the dye solutions under irradiation by UV light is much better than that under irradiation by visible light, and the decomposition of MB solution was better than that of both of MO and RhB solution.

Analyses of the Output Characteristics and the Change of Internal Impedance of Dye-sensitized Solar Cell According to the Adsorption Time (염료흡착 시간에 따른 염료감응형 태양전지의 출력 특성 및 내부 임피던스 분석)

  • Kim, Hee-Je;Lee, Jeong-Gee;Seo, Hyun-Woong;Son, Min-Kyu;Shin, In-Young;An, Tae-Pung;Kim, Jin-Kyoung
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.1
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    • pp.102-107
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    • 2010
  • Dye-sensitized solar cell (DSC) has been expected to be an alternative to the conventional silicon solar cell due to simple manufacturing process and low fabrication casts. In order to improve productivity of DSC, we attempted to optimize the required time of the adsorption process. According to the change in the adsorption time from 1 to 24h, We analyzed the output characteristics and the change of internal impedance. As a result, The outputs of DSC were continuously increased until 12h of the adsorption time and remained the same after that. Also, We reconfirmed this result that 12h was optimum adsorption by the analysis of the electrochemical impedance spectroscope because the internal impedance was similar to the output.

Analysis of characteristics and Dyeing Properties of Gromwell Colorants(Part II) - Dyeing Properties of Silk on Gromwell Colorants - (자초색소의 특성분석 및 염색성(제2보) -견섬유에 대한 자초색소의 염색성-)

  • Choi, Hee;Shin, Youn-sook
    • Journal of the Korean Society of Clothing and Textiles
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    • v.26 no.1
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    • pp.124-132
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    • 2002
  • Dyeing properties of silk fabric on gromwell roof colorants were studied for the effect of dyeing conditions, such as methanol ratio, colorants concentration, pH, temperature and time etc. on the dye uptake and effect of mordants and mordanting methods on color change and dye uptake. And various colorfastnesses of dyed fabrics were evaluated far practical use. Gromwell colorants showed high affinity to silk and its isotherm adsorption curve was Freundlich type close to Nernst type. Therefore, it is considered that hydrogen bonding and Van der Waals force were involved in the adsorption of cromwell colorants to silk fabric. Post-mordanting method gave higher K/S value than other methods, but it was not significantly different color values from unmordanted one. Gromwell colorants produced mainly R and RP color depending on mordants and mordanting method. Dyed fabrics showed high colorfastness irrespective of mordanting treatment. Light colorfastness was increased for repeatedly dyed and Fe mordanted dyed fabrics.

Microstructure Characterization of TiO2 Photoelectrodes for dyesensitized Solar Cell using Statistical Design of Experiments

  • Lee, Sung-Joon;Cho, Il-Hwan;Kim, Hyun-Wook;Hong, Sang-Jeen;Lee, Hun-Yong
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.5
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    • pp.177-181
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    • 2009
  • Employing statistical design of experiments, we have performed studies on the characterization of electrodes using $TiO_2$ and process variables in the fabrication process of nanocrystalline dye sensitized solar cell. Systematic experiment to identify the effects of process variables on cell's efficiency has based on broad-band absorption of light by tailor made organometallic dye molecules dispersed on a high surface of $TiO_2$. Employing statistical design of experiment on $TiO_2$ photoelectrode forming process, structural characterization of electrodes and process variable have been investigated. Through the statistical analysis we have found that the particle size of $TiO_2$ and the amount of PEG/PEO are significantly affecting on the cell efficiency. In addition, a significant amount of interaction exists between the particle size and the amount of PEG/PEO.