• Title/Summary/Keyword: Dye & pigment

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A Study on the Cold Pad Batch Dyeing of a String Wallcovering with Reactive Dyestuff (반응성염료를 이용한 스트링벽지 패딩염색에 관한 연구)

  • Lee, Joonhan;Kang, Youngwoong;Kim, Sunmee
    • Journal of Fashion Business
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    • v.21 no.2
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    • pp.105-112
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    • 2017
  • A string wallcovering is a kind of textile wallcovering which is made of cellulose fiber yarn laminated on base paper. Compared with normal paper or PVC wallpaper, a string wallcovering is preferred continually in the interior design market, as it is not only environmentally friendly but it also has less cost on mass production without the weaving process and has a natural visual effect, excellent functionality such as thermo keeping, permeability, sound absorption. However, in the dyeing process, it is not appropriate to use plenty of energy such as water, electricity, steam or chemicals considering the environmental trend and the government policy plenty of energy such as water, electricity, steam or chemicals. Currently, a string wallcovering is made of raw white yarn and padding with direct dye or pigment which includes toxic elements, especially the use of direct dye is restricted in a part of the developed country due to inclusion of azo. In this study, we researched dyeing based on cold pad batch dyeing of a string wallcovering with reactive dyestuff. The peel strength and bending depth test confirmed that the optimum adhesive type and spread amount improved the water resistance of the string wallcovering. Also, pad batch dyeing with optimum reactive dyestuff enhanced the color fastness to light and rubbing in dry and wet conditions. Additionally, for improvement of color fastness to rubbing in a wet condition, the additional treatment finishing without soaping process which is used water. The results of this study can be used as basic data for environmentally friendly and energy saving of the textile wallcovering.

Ecotoxicity Assessment of Industrial Effluent in Korea (산업폐수 방류수의 생태독성 평가)

  • Oh, Kyung Taek;Kim, Ji Won;Kim, Woo Kun;Lee, Soon Ae;Yun, Hong Gil;Lee, Sung Kyu
    • Journal of Korean Society on Water Environment
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    • v.22 no.1
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    • pp.37-44
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    • 2006
  • Ecotoxicity assessments of 90 selected effluents of 22 industry types from 2002 to 2004 in Korea were evaluated by a toxic battery of bioassay test using fish Oryzias latipes, invertebrate Daphnia magna, algae Selenastrum capricornutum and bacteria Vibrio fischeri with the physicochemical measurement items and permit concentrations on the present Water Quality Conservation Act in Korea. Total toxic unit (${\Sigma}TU$) of 8 industry types of 22 industry types by the toxic battery appeared in order of the value site as follows; Pigment Dye Manufacturing (${\Sigma}TU$ 217.1) > Textile and Dye (${\Sigma}TU$ 39.3) > Semiconductor Electronic Manufacturing (Small) (${\Sigma}TU$ 25.6) > Wastewater and Sewage Treatment Plants (${\Sigma}TU$ 25.4) > Coating (${\Sigma}TU$ 23.8) > Leather Skin Manufacturing (${\Sigma}TU$ 18.0) > Synthetic Resin Manufacturing (${\Sigma}TU$ 15.6) > Assemble Metal Manufacturing (${\Sigma}TU$ 10.7). Our results demonstrate that ecotoxicity assessment, by bioassay test, is effective and practical for industrial wastewater management for 90 selected effluents with the limitation of the physicochemical permit. Among 90 effluents, 9 samples failed physicochemical permit limitation and 81 passed it. In result of ecotoxicity assessment of 90 effluents by the toxic battery, 76 effluents exhibited ecotoxicity and the others did not. The physicochemical measurement items and permit concentrations on the present Water Quality Conservation Act in Korea were low related to the ecotoxicity value by the toxic battery and appeared limited for water quality management to water-ecosystem and environment-friendly management of water.

Fundamental Cultural Characteristics of Chlorociboria spp. Native to Korea (한국에 자생하는 녹청균류의 기초 배양 특성)

  • Jeon, Sung-Min;Ka, Kang-Hyeon;Wang, Eun-Jin;Ryoo, Rhim;Jang, Yeongseon
    • The Korean Journal of Mycology
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    • v.46 no.2
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    • pp.145-160
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    • 2018
  • Members of Chlorociboria are soft-rot ascomycetes that produce blue-green pigment. We investigated the growth characteristics of two Korean species of Chlorociboria, eight strains of Chlorociboria aeruginascens and Chlorociboria poutoensis, under various culture conditions (solid media, temperature, pH) and screened them for extracellular enzyme activity. Although the growth rate was slow, all tested strains of Chlorociboria spp. grew well on potato dextrose agar (PDA; 16.3~42.6 mm after 60 days) or Sabouraud dextrose agar (SDA), but not on malt extract agar (MEA). Compared with C. aeruginascens strains, C. poutoensis strains exhibited higher expression of blue-green pigments on both PDA and SDA media. The optimal temperature for mycelial growth was $20{\sim}25^{\circ}C$, and mycelial growth was lower at $30^{\circ}C$ than at $10^{\circ}C$. All strains tended to have increased mycelial growth as the incubation temperature increased in the range of 10 to $20^{\circ}C$. The optimal pH of potato dextrose broth (PDB) for mycelial growth varied according to the strain under static culture conditions. Maximum biomass production was obtained at pH 6.0 for NIFoS 579 ($114.3{\pm}5.1mg/60days$), but it maintained a stable pigment expression under a broad pH spectrum. The activities of both cellulase and laccase were observed in all tested strains of Chlorociboria spp. Enzyme activities of NIFoS 579 were remarkably higher than those of the other strains. From these results, we suggest that C. poutoensis NIFoS 579 is a potential candidate for use as a source of natural blue-green dye.

Dyeing Properties of Natural Red Colorants Extracted from Phytolacca americana Linne against Wool Fabrics (미국자리공으로부터 추출한 홍색색소의 모섬유에 대한 염색성)

  • 홍경옥;오태광;배순이;신인수
    • Textile Coloration and Finishing
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    • v.11 no.2
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    • pp.38-45
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    • 1999
  • Natural red colorants were extracted from Phytolacca americana Linne by using 50% ethanol solution at room temperature for 12 hours. The colorant components were partially purified as yellow and deep red colorants by thin layer chromatography. Natural red colorants were consisted of major water-soluble red colorant, having maximum absorbance at 538nm and alcohol-soluble yellow colorant, having maximum absorbance at 664nm. Concentration of red colorants were calibrated by the equation of dye(mg/ml) $A_{538nm}\times{1.284}$. Red colorants were changed to yellow at extreme alkali pH and repaired 55% color intensity by neutralization of pH and stabled below $55^\circ{C}$. Dyeability of red colorants against wool fabrics was mainly operated by red pigment having 538nm absorbance without big color differences. Below $55^\circ{C}$, color differences $(\Delta{E}^*_{ab})$ were not changed in spite of big difference of chroma$(c^*)$, having higher scores at higher temperature. The effect of mordants were not drastically changed parameters of color difference without copper ion. Citric acid was big changes of color difference$(\Delta{E}^*_{ab})$ in spite of similar chroma$(c^*)$ values. From these experimental results, red colorants from Phytolacca americana Linne is available for wool fabric dyeing.

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Studies on the Dyeing of Hanji by Natural Dye-stuffs(III) - With a focus on the mugwort - (천연염료를 이용한 한지염색에 관한 연구(III) - 쑥을 중심으로 -)

  • Jeon, Cheol;Ahn, Young-Hwan;Jeon, Hyung-Ja
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.38 no.3 s.116
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    • pp.61-65
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    • 2006
  • The objective of this study was to find in what color Korean handmade paper(Hanji) is dyed when it is dyed with a pigment extracted from mugworts using different kinds of mordant, and how the paper is discolored and variety of strength under the condition of accelerated aging test. The results of this experiment are as follows. Among mugwort mordants, only ferrous sulfate mordant produced unique khaki color with a slightly lower degree of discoloration, so it is considered to be applicable in dyeing Korean paper. Bright yellow and light green colors were obtained using mugwort but their chroma was too low for actual use. With regard to water used, colors obtained using underground water had high chroma, but when distilled water was used paper was colored in useless light green. Mordant was found to lower the strength of Korean handmade paper, and the lowering of strength was even more serious under the condition of forced deterioration.

The study of Phellodendron amurense Rupr. Dyeing (황벽의 염색성에 관한연구)

  • 소황옥
    • Journal of the Korean Society of Costume
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    • v.27
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    • pp.121-132
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    • 1996
  • This study showed the proper pigment extract in the Phe. Dyeing which is the basic dye of the natural plants dyeing,. Also it compared and examined the K/S the promotion of the color fastness and the effect of color difference change were attended by mordants and method of mordanting. 1. The most absorbance of Phellodendron. sol-ution is 330nm berberine is 430nm. 2. The best and proper temperature to extrat Phe,. was 80 and dyeing solution for 24 hours. 3. The pH effect was stable in the absorbances and color differences change. 4. Mordanted group increased the absorbances compared to non-mordanted sample. In case depth the most absorbance of Al. Sn. K. Cu and C. A solution were in 3% Fe and Cr were in 5%. In the color difference change they became dark reduced greenish and increased yellowish when their absorbances were in 3% 5. K./S was recoginzed by tainnin and fe, K/S was more increased pre-mordants than post-mordants. 6. Fe is the unchangable mordant in the color difference change and pre-mordants is more stable than post-mordants in the difference color. 7. Generally light C. F indicated more than grade 2 and light C. F, was much improved in post-mordanted by alumium potassium potass-ium dichromate. Washing C.F was improved in mordanted by tainnin and ferrous suulfate mordanted group was better than non-mordanted sample. Perspir-ation C,F was more stable in acid than alkali. Dry cleaning C.F indicated more than grade. 4.

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New Evaluation Method for the Lightfastness of Colored Papers by Radiant Energy (광방사에 의한 채색지의 새로운 내광성 평가 방법)

  • Kim, Hoon;Kim, Hong-Bum;Kwon, Sae-Hyuk
    • The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.11 no.6
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    • pp.37-43
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    • 1997
  • Density of a dye or pigment teduces by radiant energym and dinsity change induces color change. In this paper, we habe worked out an equation to predict the color change by the radiant energy under the assumption of colorant density changing pattern by radiant energy and the color changing pattern by colorant density chane. And the damaging factors in the equation was established by experiments. To evaluate the efectiveness of the equation and the method, several samples were irradiated by common light source and color change was measured. Good coincidence between the ceasured and the calculated color change was found. And it was also found that there is a close relationhaip between the spectral damaging factor and the spectral absorptance in visible wavelength range.

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Synthesis and Characterization of Hybrid Azo Colorants for LCD Color Filter (LCD Color Filter용 Hybrid Azo Colorants 합성 및 특성 연구)

  • Choi, Woo-Geun;Jeong, Yeon Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.7
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    • pp.528-533
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    • 2013
  • We focused on the development of red azo colorants with high thermal stability and good solubility for LCD color filter in this research. For the synthesis of hybrid azo colorants, we used the couplers of aniline, naphthol and benzoimidazol functional group. The synthesized hybrid azo colorants were charaterized by using NMR, UV/visible spectroscopy, FT-IR, EA and TGA. They represented the maximum absorption wavelengths which are longer than 500 nm in UV/visible spectrum. So they were confirmed to be suitable for red colorants of LCD color filter. Azo compound (1a, 1b) with aniline functional group had good solubility in organic solvents such as acetone, methanol, chloroform and PGMEA. Moreover azo compounds (1c, 1d and 1e) with naphthol and benzoimidazolone functional group gave excellent thermal stability higher than $250^{\circ}C$ in TGA thermograms.

Natural Dyeing of Silk, Cotton and Rayon Fabrics using Tea Leaves -Focusing on Green Tea, Oolong Tea, Black Tea, Dark Tea- (차에 의한 천연염색 연구 -녹차, 우롱차, 홍차, 흑차를 중심으로-)

  • Wang, Tian Tian;Kim, Jongjun
    • Journal of Fashion Business
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    • v.23 no.1
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    • pp.64-73
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    • 2019
  • The objective of this study was to investigate dyeing characteristics of silk, cotton and rayon fabrics using dyeing solution extracted from different varieties of tea. Comparative results of CIE Lab values of 360 pieces of dyed fabrics were studied to quantify the effects of dye concentrations (100%, 150%, and 200%) and mordants (Fe, Cu, Sn, Al). In addition, the color difference values (${\Delta}E$) of the dyed and mordanted fabrics were evaluated. The results of the study were as follows: First, among all of the 360 pieces of silk, cotton and rayon fabrics, the best dyeing effects was observed on silk fabrics. Second, the dyeing effect of the eight different types of tealeaves belonging to green tea, oolong tea, black tea, and dark tea tended to enhance as the degree of fermentation increased. Third, when the fabrics were mordanted with Fe, Cu, Sn, Al mordants, various colors such as brown, brownish red, brownish yellow, gray, and reddish brown were obtained.

Scientific Study on Materials and Painting Techniques of Portrait of Sim Huisu (심희수 초상의 재료와 제작기법에 대한 과학적 조사)

  • Chang, Yeonhee;Yun, Eunyoung;Kim, Sooyeon
    • Conservation Science in Museum
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    • v.15
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    • pp.96-121
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    • 2014
  • Portrait of Sim Huisu is a seventeenth-century Joseon portrait of a meritorious vassal. The National Museum of Korea currently owns two portraits of Sim Huisu, which are the eldest son's family and by the eldest grandson of the family's second eldest son. Both were donated in 1980. Portraits were still in its original mounting, but the supporting silk had been damaged and stained in a flood. Conservation treatment was undertaken to restore the original style, and scientific analysis, such as, X-ray, XRD, XRF and Graff "C" stain, was conducted to study the materials and painting techniques. The support silk was found to be refined fibroin and a plain weave consisting of two weft threads and one warp thread. The lining papers were found to be bamboo fiber paper of first layer in China and Korean traditional mulberry paper in second. Various pigments were identified in the painting, including white lead, cinnabar, atacamite, ink stick, azurite, silver, and gold. The study also confirmed the use of the back painting, with colors such as white White Lead, green Atacamite, orange Minium, black Ink Stick, and yellow Dye. Also, it was found that stick ink or dye was used with white lead.