• Bulletin of the Korean Chemical Society
• /
• v.29 no.4
• /
• pp.772-776
• /
• 2008

Second-order rate constants ($k_N$) have been measured spectrophotometrically for reactions of 3,4-dintrophenyl 2-furoate (2) with a series of secondary alicyclic amines in 80 mol % $H_2O$/20 mol % dimethyl sulfoxide (DMSO) at 25.0 ${^{\circ}C}$. The Bronsted-type plot exhibits a downward curvature for the aminolysis of 2, which is similar to that reported for the corresponding reactions of 2,4-dintrophenyl 2-furoate (1). Substrate 2 is less reactive than 1 toward all the amines studied but the reactivity difference becomes smaller as the amine basicity increases. Dissection of the second-order rate constants into the microscopic rate constants has revealed that the reaction of 2 results in a smaller $k_2/k_{-1}$ ratio but slightly larger $k_1$ value than that of 1. Steric hindrance has been suggested to be responsible for the smaller $k_1$ value found for the reactions of 1, since the ortho-substituent of 1 would inhibit the attack of amines (i.e., the $k_1$ process).

• Particle and aerosol research
• /
• v.9 no.2
• /
• pp.59-67
• /
• 2013

One of purposes in this study was to confirm the behavior of coughed particles under different ventilation conditions. Three types of ventilation systems were applied for this experiment and the properties of coughed particles were measured using computational fluid dynamics (CFD) in an intensive care unit. The changes of total airborne particles for each case showed different trends according to the ventilation type and time, but the deposited particles were similar in all conditions. Although the time taken for 50% of the particles to be deposited was the fastest in case 2, the portion of deposited particles after 300 seconds was only 5% in all conditions. In case 1, a relatively small number of particles were deposited on the wall, but the particle exhaust and deposition on the occupants were the highest. In case 3, the downward ventilation was applied as that recommended by the US Center for Disease Control and Prevention (CDC) and showed different exhaust efficiencies according to the particle size.

• Transactions of the Korean Society of Mechanical Engineers
• /
• v.13 no.3
• /
• pp.508-516
• /
• 1989

The objective of this study is to investigate on the pulsating combustion of a granular coal in a Rijke type pulse combustor. The combustor is made of a 120cm long pipe with a honeycomb as a fire grate in the lower half. A fixed amount of coal is laid on the honeycomb and burned downward after ignition by using propane gas. Then the combustion driven acoustic oscillation occurs and makes the combustion pulsate with a very high amplitude. The effect of the pulsation and the air flow rate on the combustion characteristics is examined in comparison with the normal combustion. The non-pulsating combustion is made possible by placing absorbing material under the honeycomb. The combustion phenomena are observed visually, the burning time is measured in order to evaluate the combustion rate, and the variation of the gas temperatures is recorded. It is found that the fuel particle is greatly agitated like boiling by the flow pulsation and the burning-down velocity is so fast that the fuel is burned almost simultaneously. The combustion rate can be increased as twice as that of non-pulsating combustion with increase of the air flow rate. And the combustion becomes clean with less soot deposit and emission.

• Journal of Astronomy and Space Sciences
• /
• v.36 no.2
• /
• pp.75-86
• /
• 2019

UV Psc is a typical RS CVn type system undergoing dynamic chromosphere activity. We performed photometric observations of the system in 2015 and secured new BVR light curves showing well-defined photometric waves. In this paper, we analyzed the light curves using Wilson-Devinney binary code and investigated the orbital period of the system. The combination of our light curve synthesis with the spectroscopic solution developed by previous investigators yielded the absolute parameters as: $M_1=1.104{\pm}0.042M_{\odot}$, $R_1=1.165{\pm}0.025R_{\odot}$, and $L_1=1.361{\pm} 0.041L_{\odot}$ for the primary star, and $M_2=0.809{\pm}0.082M_{\odot}$, $R_2=0.858{\pm}0.018R_{\odot}$, and $L_2=0.339 {\pm}0.010L_{\odot}$ for the secondary star. The eclipse timing diagram for accurate CCD and photoelectric timings showed that the orbital period may vary either in a downward parabolic manner or a quasi-sinusoidal pattern. If the latter is adopted as a probable pattern for the period change, a more plausible account for the cyclic variation may be the light time effect caused by a circumbinary object rather than an Applegate-mechanism occurring via variable surface magnetic field strengths.

• Bulletin of the Korean Chemical Society
• /
• v.29 no.7
• /
• pp.1359-1363
• /
• 2008

Second-order rate constants have been determined spectrophotometrically for reactions of 2,4-dinitrophenyl 2- thiophenecarboxylate (2) with a series of alicyclic secondary amines in 80 mol % $H_2O$/20 mol % DMSO at 25.0 ${\pm}$ 0.1 ${^{\circ}C}$. The Brønsted-type plot exhibits a downward curvature, i.e., the slope decreases from 0.74 to 0.34 as the amine basicity increases. The $pK_a$ at the center of the Brønsted curvature, defined as $pK_a^o$, has been determined to be 9.1. Comparison of the Brønsted-type plot for the reactions of 2 with that for the corresponding reactions of 2,4-dinitrophenyl 2-furoate (1) suggests that reactions of 1 and 2 proceed through a common mechanism, although 2 is less reactive than 1. The curved Brønsted-type plot has been interpreted as a change in RDS of a stepwise mechanism. The replacement of the O atom in the furoyl ring by an S atom (1 $\rightarrow$ 2) does not alter the reaction mechanism but causes a decrease in reactivity. Dissection of the apparent second-order rate constants into the microscopic rate constants has revealed that the $k_2/k_{-1}$ ratio is not influenced upon changing the nonleaving group from furoyl to thiophenecarbonyl. However, $k_1$ has been calculated to be smaller for the reactions of 2 than for the corresponding reactions of 1, indicating that the C=O bond in the thiophenecarboxylate 2 is less electrophilic than that in the furoate 1. The smaller k1 for the reactions of 2 is fully responsible for the fact that 2 is less reactive than 1.

• The korean journal of orthodontics
• /
• v.22 no.3 s.38
• /
• pp.531-556
• /
• 1992

The majority of the commonly used protraction headgears for the protraction of small and/or retropositioned maxilla not allow a change in the point of force application or direction of the force delivery to attain predictable results because of the position of the upper and lower lips to avoid discomfort to the patient. The purpose of this study was to investigate the initial reaction of maxillofacial complex according to the change of force variables such as direction and point of force application with designing an antenna type-modified protraction head gear. A macerated human skull with well aligned upper teeth was used to experimental model and the investigation was done by double exposure holographic interferometry. Fringe patterns of each protraction conditions were compared and analized. The results were as follows. (Frontal view) 1. The Counterclockwise rotation of the maxilla was showed by parallel protraction to occlusal plane and the fringe was decreased in number as higher point of force application. 2. Generally, the number of fringe was increased in 500gm of protraction force than in 300gm. 3. When apply the protraction force to the maxilla with rapid palatal expansion, the direction of fringe patterns was differed from the protraction without expansion. 4. In most of cases, the counterclockwise rotation was decreased in case of the direction of the force is $20^{\circ}$ downward to occlusal plane compared to the parallel direction. 5. At the point of force application is 15mm above and the direction of force is 20 downward to occlusal plane , the translation of the maxillary complex was showed. (Lateral view) 6. The direction of fringe patterns of the facial bones were differed each other by the sutures, and showed almost parallel when apply the 300gm and 500gm of protraction force. 7. In case of rapid palatal expansion with protraction of the maxilla, the fringe patterns between the maxillary area and the area from the posterior of the maxillary first molar to the pterygomaxillary fissure were differed. In case without rapid palatal expansion, the changes of direction and point of the force application did not affect to the direction and the number of the fringe patterns.

• Journal of the Korean Society of Clothing and Textiles
• /
• v.14 no.3 s.35
• /
• pp.183-195
• /
• 1990

The author has studied the effect of clothes design to mask the dorsal curvature that is one of the commonest changes in elderly women. Body measurements including the body type and the status of dorsal curvature were perfor-med on 153 women of over 60 years of age, and then a body form to fit to the mean measure-ments was made to evaluate the effects of various designs to it. With 31 pattern designs modified by changing in their slash lines and gathers using darts, the diminishing effect of the rounded back were evaluated by means of sensory test. The results of this study can be summarized as follows: I . Results from the body measurements 1) The mean body type in elderly women was that of obesity. 2) With the advancement of age, the angle to indicate the degree of dorsal curvature as well as the angle to indicate the posture are increased. II . Concerning to the clothes design to diminish the shape of dorsal curvature 1) Among the designs by the position of darts, the basic pattern (Fig. 5-1-(1)) showed the best effect to mask the shape of dorsal curvature. 2) Out of the applied designs of princess lines, that in which the slash line is pointing toward the shoulder point (Fig. 5-2-(1)) seemed to be most effective. 3) What has angled princess line (Fig. 5-3-(1)) had the most diminishing effect among the waist darts and armhole princess lines. 4) Among the V-shaped designs, the slashed at the shoulder point (Fig. 5-4-(1)) had the best effect to lessen the shape of the dorsal cuuature. 5) Wider angle yoke had better effect to the narrow angle one among the designs with straight yoke, and that with downward direction (Fig. 5-5-(1)) showed the best effect. 6) Between straight wide angle yoke and curved yoke, that of curved one with downward direction (Fig. 5-6-(1)) had better effect as far as the masking effect of dorsal curvature is concerned. 7) Gathers around the neck showed better effect to those around the shoulder, and the more amount of gathers (Fig. 5-7-(1)), there was better effect. 8) The design with midline gathers at the level of horizontal slash line of armhole (Fig. 5-8-(1)) showed better effect to that with seperated gathers. 9) In case of design with gathers at the horizontal line of armhole, it showed the better effect with less amount of gathers in midline ones, but with more amount in the side ones. 10) Considering all 7 different designs with better effect in covering the shape of dorsal curvature, it was evident that the design with gathers was far better than the design with application of slash lines.

• The korean journal of orthodontics
• /
• v.30 no.4 s.81
• /
• pp.491-507
• /
• 2000

The purpose of this study was to investigate if there were a significant differences in mandibular position between cephalometric measurements from a centric occlusion tracing compared to those of a acquired centric relation by stabilization splint on malocclusion patient with TMD. 60 malocclusion patients, who had TMD and CO-CR discrepancy beyond normal range, were selected and subdivided into Class I, II, III by Angle's classification and also subdivided into clockwise, straight downward, and counterclockwise group by Jarabak's posterior facial height/anterior facial height ratio. Lateral cephaolmetric radiographs with the mandible in centric occlusion were taken and measured, and for each Patient the stabilization splint with mutually protected occlusal scheme was applied for minimum 3months. After each patient's CO-CR discrepancy was in normal range, lateral cephalometric radiographs were retaken and measured. The comparison of the difference between CO-CR cephalometric measurements in all sample, Class I, II, III groups, and Clockwise, Straight downward, Counterclockwise groups were studied. The finding of this study can be summarized as follows: 1 In all sample, the value of cephalometric measurements was significantly different between CO-CR. The mandible rotated to down and posterior position and the vertical change was greater than the horizontal change (overjet-1.3mm increase, overbite-1.9mm decrease). 2. In Class II malocclusion group, most of the mean difference value between CO-CR is higher than that of the other groups and more measurements was statically significant. 3. In clockwise and counterclockwise group, some of the mean difference value is higher than that of straight downward group and more measurements was statically significant. 4. There ware no measurements that explain centric relation measurements from the type of malocclusion, facial pattern and centric occlusion measurements. Henceforth, it is strongly recommended that stabilization splint therapy for orthodontic treatment on TMD patient should be excuted upon overall facial types prior to orthodontic diagnosis and treatment planning.

• Bulletin of the Korean Chemical Society
• /
• v.35 no.2
• /
• pp.471-476
• /
• 2014

A kinetic study on aminolysis of 2-chloro-4-nitrophenyl X-substituted-benzoates (2a-k) in 80 mol % $H_2O/_20mol%$ DMSO at $25.0^{\circ}C$ is reported. The Br${\emptyset}$nsted-type plot for the reactions of 2-chloro-4-nitrophenyl benzoate (2g) with a series of cyclic secondary amines curves downward (e.g., ${\beta}_1=0.25$, ${\beta}_2=0.85$ and $pK_a^o=10.3$), which is typical of reactions reported to proceed through a stepwise mechanism with a change in ratedetermining step (RDS). The Hammett plot for the reactions of 2a-k with piperidine consists of two intersecting straight lines, while the corresponding Yukawa-Tsuno plot exhibits an excellent linear correlation with ${\rho}_X=1.15$ and r = 0.59. Thus, it has been concluded that the nonlinear Hammett plot is not due to a change in RDS but is caused by stabilization of substrates through resonance interactions between the electron-donating substituent and the C=O bond. Substrates possessing a substituent at the 2-position of the leaving aryloxide deviate negatively from the curved Br${\emptyset}$nsted-type plot for the reactions of Y-substituted-phenyl benzoates (3a-i), implying that the steric hindrance exerted by the substituent at the 2-position is an important factor which governs the reactivity of Y-substituted-phenyl benzoates.

• Fashion & Textile Research Journal
• /
• v.11 no.1
• /
• pp.103-111
• /
• 2009

This study is to help make-up and coordination for image-making after analysis of facial color and shape of elderly women. The data was analyzed 55-75 years old 212 elderly women's face color and pictures by means of SPSS 12.0 statistics package. On the basis of the colorimetric data on face by Minolta CM2500D, this research considered the analysis of facial color, patternization of facial color and its analysis by age group; for the analysis of facial shape, this research patternized facial shape and analyzed its characteristic using both contour-based facial shape analysis and Kamata facial shape analysis. As for facial color, it was found that the lower age bracket has bright and reddish face, looking fine, while the higher age bracket has a conspicuously yellowish face, looking bad. The community of facial color is classified as 3 types and it was found out that the facial color of the subjects belonging to Type 3, whose L value is the largest, looked the brightest; the face of the subjects belonging to Type 2, whose a value is the largest, was much tinged with red, and the face of the subjects belonging to Type 1, whose b value is the largest were tinged with yellow. According to the analysis of facial shape, there appeared oval & long forms in the classification by contour, while there appeared a lot of downward-directed power and inner-directed power in the classification by Kamata, which is believed to reflect the phenomenon that their chin line becomes roundish and the facial length also tend to be longer due to aging.