• Title/Summary/Keyword: Double-layer

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The Effects of Hot Corrosion on the Creep Rupture Properties of Boiler Tube Material (보일러 管材料의 크리프破斷特性에 미치는 고온부식의 影響)

  • 오세욱;박인석;강상훈
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.13 no.2
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    • pp.236-242
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    • 1989
  • In order to investigate the effects of hot corrosion on the creep rupture properties and creep life of 304 stainless steel being used as tube materials of heavy oil fired boiler, the creep rupture tests were carried out at temperature 630.deg.C, 690.deg.C and 750.deg.C in static air for the specimens with or without coating of double layer corrosives according to the new hot corrosion test method simulating the situation commonly observed on superheater tubes of the actual boiler. The double layer corrosives are 85% V$_{2}$O$_{5}$ + 10% Na$_{2}$So$_{4}$ + 5% Fe$_{2}$O$_{3}$ as the inner layer corrosive being once melted at 900.deg. C and crushed to powder, and 10% V$_{2}$O$_{5}$ + 85% Na$_{2}$SO$_{4}$ +5% Fe$_{2}$O$_{3}$ as the outer layer corrosive. As results, in the specimen coated with the double layer corrosives, the rupture strength was extremely lowered and showed a large difference each other. The rupture ductility also lowered remarkably as a result of the brittle fracture mode due to hot corrosion. These results indicate that hot corrosion could essentially alter the creep fracture mechanism. From the metallographic observation, it was clarified that the rupture life of 304 stainless steel subjected to hot corrosion was chiefly determined by the behavior of the aggressive intergranular penetration of sulfides.des.

Anti-Reflective Coating with Hydrophilic/Abraion-Resistant Properties using TiO2/SiOxCy Double-Layer Thin Film (TiO2/SiOxCy 이중 박막을 이용한 투명 친수성/내마모성 반사방지 코팅)

  • Lee, Sung-jun;Lee, Min-kyo;Park, Young-chun
    • Journal of the Korean institute of surface engineering
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    • v.50 no.5
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    • pp.345-351
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    • 2017
  • A double-layered anti-reflective coating with hydrophilic/abrasion-resistant properties was studied using anatase titanium dioxide($TiO_2$) and silicon oxycarbide($SiO_xC_y$) thin film. $TiO_2$ and $SiO_xC_y$ thin films were sequentially deposited on a glass substrate by DC sputtering and PECVD, respectively. The optical properties were measured by UV-Vis-NIR spectrophotometer. The abrasion-resistance and the hydrophilicity were observed by a taber abrasion tester and a contact angle analyzer, respectively. The $TiO_2/SiO_xC_y$ double-layer thin film had an average transmittance of 91.3%, which was improved by 10% in the visible light region (400 to 800 nm) than that of the $TiO_2$ single-layer thin film. The contact angle of $TiO_2/SiO_xC_y$ film was $6.9^{\circ}$ right after UV exposure. After 9 days from the exposure, the contact angle was $10.2^{\circ}$, which was $33^{\circ}$ lower than that of the $TiO_2$ single-layer film. By the abrasion test, $SiO_xC_y$ film showed a superior abrasion-resistance to the $TiO_2$ film. Consequently, the $TiO_2/SiO_xC_y$ double-layer film has achieved superior anti-reflection, hydrophilicity, and abrasion resistance over the $TiO_2$ or $SiO_xC_y$ single-layer film.

Studies of Electric Double Layer Capacitors Used For a Storage Battery of Dye Sensitized Solar Cell Energy

  • Kim Hee-Je;Jeon Jin-An;Sung Youl-Moon;Yun Mun-Soo;Choi Jin-Young
    • Journal of Electrical Engineering and Technology
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    • v.1 no.2
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    • pp.251-256
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    • 2006
  • To design the effective usage of electric double layer capacitors (EDLCs) used for a storage device of dye sensitized solar cell (DSC) energy, we first investigated the accumulation state of electrical charges and the charge behavior in the EDLCs. Based on the results, the voltage characteristics of EDLCs connected to DSC energy were evaluated. The results showed that the charge accumulation region concentrated on the central part of the carbonaceous electrode in EDLCs and the required times for charging and discharging were almost the same.

Diffusive Double Layer Model of PL Ring in Bacterial Flagellar Motor and Application to Nano-Machines

  • Nakano, T.;Momozono, S.;Aizawa, S.
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.10b
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    • pp.53-54
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    • 2002
  • New lubrication mechanism for nanomachine is proposed. This mechanism utilizes the effect of diffusive double layer observed in hydrophobic colloidal solution. Basic idea of the theory is inspired by the research for possible mechanism of bacterial flagellar motor In this study, formulation of this mechanism is achieved and numerical calculation is performed. It is shown that this mechanism can produce enough load capacitance. Furthermore not only capacitance to sustain driving force of flagellar motor

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Studies of electric double layer capacitors used for a storage battery of dye sensitized solar cell energy (염료감응형 태양전지의 축전지로 사용되는 전기이중층콘덴서에 대한 연구)

  • Choi, Jin-Young;Lee, Im-Geun;Hong, Ji-Tae;Kim, Hee-Je
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.673-676
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    • 2005
  • To design the effective usage of electric double layer capacitors (EDLCs) used for a storage device of dye sensitized solar cell(DSC) energy, we first investigated the accumulation state of electrical charges and the charge behavior in the EDLCs. Based on the results. the voltage characteristics of EDLCs connected to DSC energy were evaluated. The results showed that the charge accumulation region concentrated on central part of the carbonaceous electrode in EDLCs and the required times for charging and discharging were almost the same.

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Characteristics Analysis of Double-layer AFPM Motor (Double-layer AFPM 전동기의 특성해석)

  • Kong, Jeong-Sik;Yoo, Hyune-O;Oh, Chul-Soo
    • Proceedings of the KIEE Conference
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    • 1999.11a
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    • pp.24-27
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    • 1999
  • This paper proposed a method to reduce torque ripple of double-layer axial flux permanent magnet motor. Torque is generated by interacting between current of stator winding and airgap flux. In the case of slotless axial flux permanent magnet motor, only commutation torque component is significant. Hence, cogging and reluctance torque will not be considered. For this propose, we were supplied differential phase current in each winding and shifted rotor magnet. According to shifted rotor magnet and flux and phase of current were shifted, phase of developed torque in each side is difference. As a result, we could reduce the total torque ripple in motor and obtain minimum torque ripple in the case of 7.5 degree shifting angle between two rotors.

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An Overview of the Activated Carbon Fibers for Electrochemical Applications

  • Lee Gyoung-Ja;Pyun Su-Il
    • Journal of the Korean Electrochemical Society
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    • v.9 no.1
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    • pp.10-18
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    • 2006
  • This article is concerned with the overview of the activated carbon fibers. Firstly, this review provides a comprehensive survey of the overall processes for the synthesis of the activated carbon fibers from the carbonaceous materials. Subsequently, the physicochemical properties such as pore structures and surface oxygen functional groups of the activated carbon fibers were discussed in detail. Finally, as electrochemical applications of the activated carbon fibers to electrode materials for electric double-layer capacitor (EDLC), the electrochemical characteristics of the activated carbon fiber electrodes and the various methods to improve the capacitance and rate capability were introduced. In particular, the effect of pore length distribution (PLD) on kinetics of double-layer charging/discharging was discussed based upon the experimental and theoretical results in our work. And then we discussed in detail the applications of the activated carbon fibers to adsorbent materials for purification of liquid and gas.

Fabrication of Electrochromic Devices Using Double Layer Conducting Polymers for Infrared Transmittance Control

  • Kim, Jin Kyu;Koh, Jong Kwan;Kim, Bumsoo;Jeon, Seokwoo;Ahn, Joonmo;Kim, Jong Hak
    • Rapid Communication in Photoscience
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    • v.3 no.2
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    • pp.32-34
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    • 2014
  • We report the performance improvement of electrochromic devices for modulating the transmittance contrast of long wavelength infrared light between 1.5 and 5.0 ${\mu}m$ based on a double layer of conducting polymers. The device, fabricated with poly(3-hexylthiophene) (P3HT) and poly(3,4-ethylenedioxythiophene) (PEDOT) as the first and second layers, respectively, showed an transmittance contrast of 60% with a response rate under 5 s, which is greater than the transmittance contrast of cells based on only P3HT or PEDOT (approximately 40%).

An Analytical Model for Breakdown Voltage of the Schottky diode with Double Epitaxial Layer (이중 에피층을 갖는 쇼트키 다이오드의 항복전압 모형)

  • Jung, Jin-Young;Han, Seung-Youp;Chung, Sang-Koo;Choi, Yearn-Ik
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1612-1614
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    • 1996
  • Analytical expression for the breakdown voltage of the Schottky diode with double epitaxial layer has been obtained. Analytical results agree reasonably with the numerical simulations using MEDICI. It is expected that our results can be used for the optimum design of power MOSFET as well as the Schottky diodes with double epitaxial layer.

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Electrochemical Characterization of Electric Double Layer Capacitors Assembled with Pyrrolidinium-Based Ionic Liquid Electrolytes

  • Cho, Jinhyun;Shin, Won-Kyung;Kim, Dong-Won;Kim, Young Rae;Lee, Byung Jun;Kim, Sang-Gil
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.199-205
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    • 2016
  • We present the electrochemical performance of electric double layer capacitors (EDLCs) assembled with pyrrolidinium (Pyr)-based ionic liquid electrolytes at 55 ℃. Cations with various alkyl chain lengths were employed in Pyr-based ionic liquids to investigate the effect of cation structure on the cycling stability of EDLCs. The EDLCs exhibited initial specific capacitances ranging from 122.4 to 131.6 F g−1 based on activated carbon material at 55 ℃. Cycling data and XPS results demonstrate that Pyr-based ionic liquid with longer alkyl chain is more effective for enhancing the cycling stability of EDLC by suppressing the reductive decomposition of pyrrolidinium cations during cycling at high temperatures.