• Title/Summary/Keyword: Dispersion Property

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Energy Harvesting System according to Moisture Absorption of Textile and Efficient Coating Method as a Carbon Black (섬유 고분자의 수분 흡수에 따른 에너지 하베스팅 발전 소자 및 이를 위한 카본 블랙의 효율적인 코팅법)

  • Choi, Seungjin;Chae, Juwon;Lee, Sangoh;Lee, Jaewoong
    • Textile Coloration and Finishing
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    • v.33 no.4
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    • pp.280-287
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    • 2021
  • Generating electricity by using water in many energy harvesting system is due to their simplicity, sustainability and eco-friendliness. Evaporation-driven moist-electric generators (EMEGs) are an emergent technology and show great potential for harvesting clean energy. In this study, we report a transpiration driven electro kinetic power generator (TEPG) that utilize capillary flow of water in an asymmetrically wetted cotton fabric coated with carbon black. When water droplets encounter this textile EMEG, the water flows spontaneously under capillary action without requiring an external power supply. First carbon black sonicated and dispersed well in three different solvent system such as dimethylformamide (DMF), sodiumdedecylbenzenesulfonate (SDBS-anionic surfactant) and cetyltrimethylammoniumbromide (CTAB-cationic surfactant). A knitted cotton/PET fabric was coated with carbon black by conventional pad method. Cotton/PET fabrics were immersed and stuttered well in these three different systems and then transferred to an autoclave at 120 ℃ for 15 minutes. Cotton/PET fabric treated with carbon black dispersed in DMF solvent generated maximum current up to 5 µA on a small piece of sample (2 µL/min of water can induce constant electric output for more than 286 hours). This study is high value for designing of electric generator to harvest clean energy constantly.

The mechanical properties of 3D printed denture base resin incorporating essential oil microcapsules

  • Steve An;Jane Lesleigh Evans;Stephen Hamlet;Robert Matthew Love
    • The Journal of Advanced Prosthodontics
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    • v.15 no.4
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    • pp.189-201
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    • 2023
  • PURPOSE. The aim of this study was to investigate the mechanical properties of three-dimensional (3D) printed denture base resin incorporating microcapsules containing plant essential oils. MATERIALS AND METHODS. Denture base specimens containing up to 3% w/v essential oil microcapsule powders (MCPs), i.e., eucalyptus, geranium, lavender, menthol, and tea tree, in two resins (Detax and NextDent 3D+) were 3D printed using two printers (Asiga and NextDent 5100). The dispersion and interaction of the MCPs in the resin were assessed by SEM while the mechanical properties of the incorporated denture base including flexural strength (MPa), flexural modulus (MPa), Vickers hardness (VHN), and surface roughness (Ra) were also subsequently evaluated. Statistical analysis of any differences in mean values was determined using a two-way ANOVA with Tukey's post hoc testing (α = .05). RESULTS. The spherical shape of the MCPs was maintained during the mixing and polymerization/printing process. However, the Detax-Asiga group showed significant agglomeration of the MCPs even at the lowest MCP concentration levels (0.5% w/v). Overall, as the microcapsule concentration increased, the mean flexural strength decreased, though the menthol MCP groups remained compliant with the ISO standard. The flexural modulus and harness remained relatively unchanged, and the flexural modulus complied with the ISO standard regardless of the MCP concentration. Surface roughness increased with the addition of the MCPs but also remained below that required for clinical acceptance. CONCLUSION. Incorporation of microencapsulated plant essential oils into 3D printed denture base resin was successfully achieved. While incorporation negatively influenced flexural strength and surface roughness, little effect on flexural modulus and Vickers hardness was demonstrated.

Rheological and Thermal Properties of PLA Nano-composite Modified by Reactive Extrusion (반응압출 공정으로 개질된 PLA 나노복합체의 유변학적 및 열적 물성)

  • Kang, Gyeoung-Soo;Kim, Bong-Shik;Shin, Boo-Young
    • Clean Technology
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    • v.15 no.2
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    • pp.102-108
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    • 2009
  • In this study, poly(lactic acid) (PLA) was modified by reactive extrusion with a functional monomer GMA(glycidyl methacrylate), MMT(montmorillonite), and initiator to enhance the melt strength. Each modified PLA was prepared with different amounts of GMA and MMT and was characterized by measuring thennal- and melt-viscoelastic properties. The degree of dispersion of MMT was measured by X-ray diffraction(XRD) and transmission electron microscopy(TEM). The glass transition temperature($T_g$) of modified PLA-GMA-MMT nanocomposite decreased with increasing GMA content, but was a little affected by the amount of MMT. Surface analysis showed that the nanocomposite became more intercalated than exfoliated as the amount of MMT increases. The complex viscosity and storage modulus of the nano-composite were greatly increased by addition of MMT.

Analysis of Steady and Unsteady Flow Around a Ship Using a Higher-Order Boundary Element Method (고차경계요소법에 의한 선체주위 유동해석)

  • Sa-Y. Hong;Hang-S. Choi
    • Journal of the Society of Naval Architects of Korea
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    • v.32 no.1
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    • pp.42-57
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    • 1995
  • An efficient and accurate scheme has been constructed by taking advantages of the hi-quadratic spline scheme and the higher-order boundary element method selectively depending on computation domains. Boundary surfaces are represented by 8-node boundary elements to describe curved surfaces of a ship and its neighboring free surface more accurately. The variation of the velocity potential complies with the characteristics of the 8-node element on the body surface. But on the free surface, it is assumed to follow that of the hi-quadratic spline scheme. By which, the free surface solution is free from numerical damping and has better numerical dispersion property. As numerical examples, steady and unsteady Neumann-Kelvin problems are considered. Numerical results for a submerged spheroid, Series 60($C_B=0.6$) and a modified support the proposed method. Finally, a new upstream radiation condition is derived using a wave equation operator in order to deal with problems for subcritical reduced frequency. The relevance of this operator has been confirmed in the case of unsteady Kelvin source potential.

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Effect of V and Nb on Mechanical Properties of Non-Heattreated Hot Forging Steels (열간단조용 비조질강의 기계적 성질에 미치는 V, Nb의 영향)

  • Wee, Kyeom-Bok;Jeong, Woon-Tae;Lee, Kyeong-Seop;Wang, Seong-Do
    • Korean Journal of Materials Research
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    • v.2 no.1
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    • pp.65-75
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    • 1992
  • 0.4wt%C steel added with V and/or Nb were forged and followed by air cooling. The structure-property relationships were examined and multiple regression analysis was conducted to quantify the magnitudes of effects of microalloying elements on the properties of the steels. All material's tensile strength are greater than $70kg/\textrm{mm}^2$, so they are equal to or superior to Q/T material's(S45C). Their impact energies are less than 40J, so they are 50% of Q/T material's. Increasing the content of V from 0.10 to 0.15 wt% had brought improvement in UTS about 20% but with some sacrifice of impact energy. These were the results from the precipitation strengthening by fine dispersion of VC in ferrite, increment of pearlite volume fraction and decrement of pearlite interlamellar spacings. However, increasing the content of Nb from 0.05 to 0.l0wt % slightly improved UTS and impact energy. NbC precipitates were more effective in suppression of austenite grain coarsening than VC precipitates. Combined additions of V+Nb were more effective to bring impact toughness than sole addition. Optimum combination of strength and toughness was accomplished wish 0.4C-1. 19Mn-0.05S-0.12V-0.07Nb steel.

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Synthesis and Properties of Polyurethane/Clay Nanocomposites Containing Siloxane Segment (실록산 세그먼트를 가진 폴리우레탄/점토 나노복합체의 제조 및 물성에 관한 연구)

  • Lee Jung Eun;Kim Hyung Joong
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.177-182
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    • 2005
  • Montmorillonite (MMT) modified with siloxane diamine was reacted with a reactant obtained from 4,4'-diphenyl methane diisocyanate (MDI) and polyester type polyol, $Nippollan4010(\bar{M}_n2000)$. Finally, polyurethane (PU)/MMT composites were prepared by using 1,4-butane diol as a chain extender in $25\;wt\%$ solution of N,N-dimethyl acetamide (DMAc). It was expected that these nanocomposites had superior exfoliation property to that of MMT dispersed polyurethanes produced by simple mixing due to insertion of siloxane main chain to the silicate interlayer of MMT. Extent of reaction and formation of final products were analysed by using FT-IR spectroscopy. Dispersion into the PU and intercalation of MMT were identified by applying X-ray diffraction (XRD) and transmission electron microscopy (TEM). Tensile data were acquired by universal test machine (UTM). Thermal stability and variation of surface energy were characterized by thermal gravimetric analysis (TGA) method and measurement of contact angle on the synthesized composites, respectively. As the results the organo-MMT modified with siloxane diamine in the PU composites has an intercalated structure relatively well-expanded rather than a completely exfoliated structure. The tensile strengths and the moduli for the PU/organo-MMT composites were drastically enhanced in comparison to those of $PU/Na^+-MMT$ composites.

Mechanical Properties of an ECC(Engineered Cementitious Composite) Designed Based on Micromechanical Principle (마이크로역학에 의하여 설계된 ECC (Engineered Cementitious Composite)의 역학적 특성)

  • Kim Yun-Yong;Kim Jeong-Su;Kim Hee-Sin;Ha Gee-Joo;Kim Jin-Keun
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.709-716
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    • 2005
  • The objective of this study is to develop a high ductile fiber reinforced mortar, ECC(Engineered Cementitious Composite) with using raw material commercially available in Korea. A single fiber pullout test and a wedge splitting test were employed to measure the bond properties in a matrix and the fracture toughness of mortar matrix respectively, which are used for designing mix proportion suitable for achieving strain-hardening behavior at a composite level. Test results showed that the properties tended to increase with decreasing water-cement ratio. A high ductile fiber reinforced mortar has been developed by employing micromechanics-based design procedure. Micromechanical analysis was initially peformed to properly select water-cement ratio, and then basic mixture proportion range was determined based on workability considerations, including desirable fiber dispersion without segregation. Subsequent direct tensile tests were performed on the composites with W/C's of 47.5% and 60% at 28 days that the fiber reinforced mortar exhibited high ductile uniaxial tension property, represented by a maximum strain capacity of 2.2%, which is around 100 times the strain capacity of normal concrete. Also, compressive tests were performed to examine high ductile fiber reinforced mortar under the compression. The test results showed that the measured value of compressive strength was from 26MPa to 34 MPa which comes under the strength of normal concrete at 28 days.

Physical-chemical Properties and Phosphorus Adsorption Characteristics of Soils in Baicheng, China (중국 길림성 백성지역 흑개토의 이화학성 및 인산 흡착 특성)

  • Jin, Sheng-Ai;Lee, Sang-Mo;Choi, Woo-Jung;Yoo, Sun-Ho
    • Applied Biological Chemistry
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    • v.44 no.2
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    • pp.92-96
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    • 2001
  • Soil physical-chemical properties and phosphorous adsorption characteristics were investigated to obtain the informations of the appropriate fertilization and soil management in Baicheng region, China, where agricultural circumstances at present forces to consider the use of land for crop production. Soils were collected from one uncultivated and three cultivated lands on August 1993. Soil $_PH$ was very higher in uncultivated land than in cultivated land, their values were 10.2 and 7.4, respectively. Regardless of cultivation, soil organic matter contents were below 2%, and concentrations of available soil phosphorus expressed as Bray 1 P and Olson P were less than 10 mg P $kg^{-1}$, however, cation exchange capacity was higher than 20 cmol(+) $kg^{-1}$. For uncultivated soil, the values of exchangeable sodium percent and calcium saturation percent were higher than 100%. The major cation of soil saturation paste extracts was Na regardless of land use type. Based on electrical conductivity and sodium adsorption ratio of saturation paste extracts, uncultivated soil was classified as saline-sodic soil and cultivated soil was classified as sodic or normal soil. The maximum adsorption capacity of phosphorus calculated by Langmuir isotherm ranged from 406 to 521 mg P ,$kg^{-1}$. The constraints of soils in Baicheng regions for agricultural cops werw high salt concentration, unfavorable soil chemical composition such as low concentration of available phosphorous, and poor drainage due to soil dispersion by high Na concentration. Therefore, the soil in Baicheng region, need the application of phosphorus fertilizer to increase the soil fertility and the proper soil management to improve the soil physical property especially permeability and soil structure.

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A Study on the Antioxidative Effects of Zostera marina and its Application in Cosmatics (잘피(Zostera marina)의 항산화 효능과 화장품 응용에 관한 연구)

  • Lee, So-Yeon;Yang, Jae-Chan;Kim, Bo-Ae
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.3
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    • pp.534-544
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    • 2017
  • In order to use the sea flowering plant, Zostera marina, as a cosmetic ingredient, this study was conducted to evaluate its antioxidant effect. We confirmed the formulation stability of the emulsion containing Zostera marina extracts. We studied the antioxidant activity of the dissolved Zostera marina extracts through the DPPH (1,1-Diphenyl-2-picrylhydrazy) radical scavenging activity assay and SOD (superoxide dismutase)-like activity assay. Also, the pH, viscosity and particle dispersion of the emulsion containing Zostera marina extracts were measured using a Turbiscan LAB. The emulsions were measured at one-week intervals in a thermostat chamber ($25^{\circ}C{\pm}1^{\circ}C$, $40^{\circ}C{\pm}1^{\circ}C$) for 28 days. The extracts of Zostera marina showed a DPPH radical scavenging rate of 86.21% and SOD-like activity of 99.24% at 5.00 mg/ml and exhibited a dose-dependent increase in their antioxidant activity. We measured the stability of the pH, viscosity and emulsion particles using the Turbiscan LAB in a thermostat chamber for 28 days. The formulations to which the Zostera marina extracts were added were considered to be stable, due to their negligible physical property changes over time during storage. The results suggest that the Zostera marina extracts with 70% ethanol (v/v) could be used in cosmetics as an antioxidant for the anti-aging of skin.

Autohesion Behavior of Brominated-Isobutylene-Isoprene Gum Nanocomposites with Layered Clay (층상점토 충전 브롬화 이소부틸-이소프렌 검 나노복합체의 점착거동)

  • Mensah, Bismark;Kim, Sungjin;Lee, Dae Hak;Kim, Han Gil;Oh, Jong Gab;Nah, Changwoon
    • Elastomers and Composites
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    • v.49 no.1
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    • pp.43-52
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    • 2014
  • The effect of nanoclay (Cloisite 20A) on the self-adhesion behavior of uncured brominated-isobutylene-isoprene rubber (BIIR) has been studied. The dispersion state of nanoclay into the rubber matrix was examined by SEM, TEM and XRD analysis. The thermal degradation behavior of the filled and unfilled samples was examined by TGA and improvement in the thermal stability of the nanocomposites occurred based on the weight loss (%) measurements. Also, addition of nanoclay enhanced the cohesive strength of the material by reinforcement action thereby reducing the degree of molecular diffusion across the interface of butyl rubber. However, the average depth of penetration of the inter-diffused chains was still adequate to form entanglement on either side of the interface, and thus offered greater resistance to peeling, resulting in high tack strength measurements. The improvement in tack strength was only achieved at critical nanoclay loading above 8 phr. Contact angle measurement was also made to examine the surface characteristics. There was no significant interfacial property change by employing the nanoclay.