• Title/Summary/Keyword: Dispersion Degree

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The Quantitative Characterization of the Dispersion State of Single-Walled Carbon Nanotubes (단일벽 탄소나노튜브의 분산도 정량적 평가)

  • Yoon, Do-Kyung;Choi, Jae-Boong;Kim, Young-Jin;Baik, Seung-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.31 no.4
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    • pp.483-489
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    • 2007
  • We have investigated quantitative measurement techniques of the degree of dispersion of single-walled carbon nanotubes (SWNTs). SWNTs were suspended in aqueous media using a sodium dodecyl sulfate (SDS) surfactant. SWNTs with different dispersion states were prepared by controlling the intensity and time of sonication and centrifugation. The laser spectroscopic techniques were employed to characterize the dispersion state; i.e., raman fluorescence and absorption spectroscopic techniques. Raman spectroscopy has been used to probe the dispersion and aggregation state of SWNTs in solution. Individually suspended SWNTs show increased fluorescence peaks and decreased roping peaks at a raman shift 267 $cm^{-1}$ compared with the samples containing bundles of SWNTs. The ultraviolet-visible-near infrared (UV-vis-NIR) absorption spectrum of decanted supernatant samples show sharp van Hove singularity peaks

Heat Energy Diffusion Analysis in the Gas Sensor Body with the Variation of Drain-Source Electrode Distance (드레인-소스 전극 간극의 변화에 따른 Gas Sensor의 열에너지 확산 해석)

  • Jang, Kyung-Uk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.9
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    • pp.589-595
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    • 2017
  • MOS-FET structured gas sensors were manufactured using MWCNTs for application as NOx gas sensors. As the gas sensors need to be heated to facilitate desorption of the gas molecules, heat dispersion plays a key role in boosting the degree of uniformity of molecular desorption. We report the desorption of gas molecules from the sensor at $150^{\circ}C$ for different sensor electrode gaps (30, 60, and $90{\mu}m$). The COMSOL analysis program was used to verify the process of heat dispersion. For heat analysis, structure of FET gas sensor modeling was proceeded. In addition, a property value of the material was used for two-dimensional modeling. To ascertain the degree of heat dispersion by FEM, the governing equations were presented as partial differential equations. The heat analysis revealed that although a large electrode gap is advantageous for effective gas adsorption, consideration of the heat dispersion gradient indicated that the optimal electrode gap for the sensor is $60{\mu}m$.

Properties and particles dispersion of biodegradable resin/clay nanocomposites

  • Okada, Kenji;Mitsunaga, Takashi;Nagase, Youichi
    • Korea-Australia Rheology Journal
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    • v.15 no.1
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    • pp.43-50
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    • 2003
  • In this study, two types of biodegradable resins-based clay nanocomposites, in which organic montmorillonite clay was filled, were prepared by the direct melt blending method. In order to characterize the nanocomposite structure, wide-angle X-ray diffraction (WAXD) and TEM observation were performed. Characterization of the nanocomposites shows that intercalated and partially exfoliated structures were generated by the melt blending method. Mechanical and rheological properties of the nanocomposites were measured respectively. For the mechanical properties, there were improvements in tensile strength and Young's modulus of the nanocomposites due to the reinforcement of nanoparticles. The rheological behaviors of the nanocomposites were significantly affected by the degree of the dispersion of the organoclay. The storage modulus of the nanocomposites was measured and the degree of the dispersion of the organoclay was evaluated from the value of the terminal slope of the storage modulus. In addition, the quantity of the shear necessary for making the nanocomposite for melt intercalation method was estimated from the relationship between the value of the terminal slope of the storage modulus and the applied shear.

A Numerical Method for Dispersion of Unsteady Horizontal Line Source in Turbulent Shear Flow (난류전단 흐름에서의 비정상 수평 선오염원의 확산에 관한 수치해법)

  • 전경수
    • Water for future
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    • v.29 no.4
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    • pp.187-198
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    • 1996
  • A numerical model for unsteady dispersion of horizontal line source in turbulent shear flow is developed. A fractional step finite difference method is used which splits the unsteady two-dimensional advective diffusion equation into the longitudinal advection and the vertical diffusion equations, and solves them alternately for half time intervals by the Holly-Preissmann scheme and the Crank-Nicholson scheme, respectively. The developed numerical model is verified using a semi-analytic solution for steady dispersion in turbulent shear flow. Dispersion of an instantaneous plane source in turbulent shear flow is analyzed using the model. The degree of mixing at the same dimensionless time is almost the same regardless of the friction factor, and the travel distance required to reach a certain degree of mixing is inversely proportional to the square root of the friction factor.

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A Study on School Facilities Build Transfer Lease Project - Centering on the improvement of the assessment - (학교시설 임대형민자사업의 평가기준 개선연구)

  • Kwon, Byoung-Koo;Lee, Jae-Rim;Jo, Jin-Il
    • The Journal of Sustainable Design and Educational Environment Research
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    • v.7 no.2
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    • pp.30-46
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    • 2008
  • In this study, were prepared after statistical analysis was conducted of assessment items and marks distribution for the selection of executors of the BTL project. When tests of the degree of dispersion and degree of appropriateness for each assessment item were analyzed, it was found that the degree of dispersion among assessment points has the power of discrimination since it is highly marked in the design field and operation management field. In contrast, 'business management plan' and 'investment composition for economic quality assessment' have a low level of the power of discrimination since points given to them have smaller difference between business projects.

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An Empirical Study of the Effect of Oil Prices on International Price Dispersion (원유가격이 국가 간 가격분산에 미치는 영향에 대한 실증 연구)

  • Lee, Inkoo
    • Korea Trade Review
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    • v.43 no.2
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    • pp.69-86
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    • 2018
  • The paper studies the degree of international price dispersion for 300 individual goods and services between cities of three country groups over 1999 and 2013, focusing on the role of oil prices in generating deviations from the law of one price. We find that while oil prices did not contribute to the trend in cross-country price dispersion, it does account for within-country price dispersion. Once the oil price effect is subtracted out, the remaining price dispersion between U.S. cities no longer exhibits a noticeable upward trend. If oil prices increase transportation costs, they should increase the deviations from the law of one price, raising price dispersion. Our findings indicate that this effect is more pronounced within a country, while factors such as elasticity of substitution and other trade barriers are likely to matter more in price dispersion across borders. We view our results as complementary to those that emphasize the role of time-varying factors in accounting for price dispersion.

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Near-elliptic Core Triangular-lattice and Square-lattice PCFs: A Comparison of Birefringence, Cut-off and GVD Characteristics Towards Fiber Device Application

  • Maji, Partha Sona;Chaudhuri, Partha Roy
    • Journal of the Optical Society of Korea
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    • v.18 no.3
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    • pp.207-216
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    • 2014
  • In this work, we report detailed numerical analysis of the near-elliptic core index-guiding triangular-lattice and square-lattice photonic crystal fiber (PCFs); where we numerically characterize the birefringence, single mode, cut-off behavior and group velocity dispersion and effective area properties. By varying geometry and examining the modal field profile we find that for the same relative values of $d/{\Lambda}$, triangular-lattice PCFs show higher birefringence whereas the square-lattice PCFs show a wider range of single-mode operation. Square-lattice PCF was found to be endlessly single-mode for higher air-filling fraction ($d/{\Lambda}$). Dispersion comparison between the two structures reveal that we need smaller lengths of triangular-lattice PCF for dispersion compensation whereas PCFs with square-lattice with nearer relative dispersion slope (RDS) can better compensate the broadband dispersion. Square-lattice PCFs show zero dispersion wavelength (ZDW) red-shifted, making it preferable for mid-IR supercontinuum generation (SCG) with highly non-linear chalcogenide material. Square-lattice PCFs show higher dispersion slope that leads to compression of the broadband, thus accumulating more power in the pulse. On the other hand, triangular-lattice PCF with flat dispersion profile can generate broader SCG. Square-lattice PCF with low Group Velocity Dispersion (GVD) at the anomalous dispersion corresponds to higher dispersion length ($L_D$) and higher degree of solitonic interaction. The effective area of square-lattice PCF is always greater than its triangular-lattice counterpart making it better suited for high power applications. We have also performed a comparison of the dispersion properties of between the symmetric-core and asymmetric-core triangular-lattice PCF. While we need smaller length of symmetric-core PCF for dispersion compensation, broadband dispersion compensation can be performed with asymmetric-core PCF. Mid-Infrared (IR) SCG can be better performed with asymmetric core PCF with compressed and high power pulse, while wider range of SCG can be performed with symmetric core PCF. Thus, this study will be extremely useful for designing/realizing fiber towards a custom application around these characteristics.

Modeling of rheological behavior of nanocomposites by Brownian dynamics simulation

  • Song Young Seok;Youn Jae Ryoun
    • Korea-Australia Rheology Journal
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    • v.16 no.4
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    • pp.201-212
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    • 2004
  • Properties of polymer based nanocomposites depend on dispersion state of embedded fillers. In order to examine the effect of dispersion state on rheological properties, a new bi-mode FENE dumbbell model was proposed. The FENE dumbbell model includes two separate ensemble sets of dumbbells with different fric­tion coefficients, which simulate behavior of well dispersed and aggregated carbon nanotubes (CNTs). A new parameter indicating dispersion state of the CNT was proposed to account for degree of dispersion quantitatively as well as qualitatively. Rheological material functions in elongational, steady shear, and oscillatory shear flows were obtained numerically. The CNT/epoxy nanocomposites with different dis­persion state were prepared depending on whether a solvent is used for the dispersion of CNTs or not. Dis­persion state of the CNT in the epoxy nanocomposites was morphologically characterized by the field emission scanning electronic microscope and the transmission electron microscope images. It was found that the numerical prediction was in a good agreement with experimental results especially for steady state shear flow.

Structural and Dielectric Properties of Epoxy-Organoclay Nanocomposites using Power Ultrasonic Dispersion (초음파 분산을 이용한 Epoxy-Organoclay 나노콤포지트 구조적 그리고 유전특성에 관한 연구)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.57 no.9
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    • pp.1572-1578
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    • 2008
  • The effect of the organoclay_10A nanoparticles on the DSC and Structural and Dielectrics Properties(1Hz-1MHz) for epoxy/Organoclay_10A Nanocomposites has been studied. Dielectric properties of epoxy-Organoclay nanocomposites were investigated at 1, 3, 5, 7, 9 filler concentration by weight. Epoxy nanocomposites samples were prepared with good dispersion of layered silicate using power ultrasonic method in the particles. As structural analysis, the interlayer spacing have decreased with filled nanoparticles contents increase using power ultrasonic dispersion. The maximum increase interlayered spacing was observed to decease for above 5wt% clay loading. The other hand, as decrease with concentration filler of the layered silicate were increased dispersion degree of nanoparticles in the matrix. The interesting dielectric properties for epoxy based nanocomposites systems are attributed to the large volume fraction of interfacesin the bulk of the material and the ensuring interactions between the charged nanoparticle surface and the epoxy chains.

How Does Corporate Social Responsibility Affect Asymmetric Information: Evidence from Korean Retail Industry

  • Kim, Sang-Su;Lee, Jeong-Hwan
    • Journal of Distribution Science
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    • v.17 no.2
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    • pp.5-11
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    • 2019
  • Purpose - This paper examines how corporate social responsibility of the Korean retail industry affects the degree of asymmetric information. Recent theories predict that a firm's active engagement in socially responsible activities lowers the degree of asymmetric information of the firm. Research design, data, and methodology - This paper uses the sum of environmental and social scores (ES), published by the Korean Corporate Governance Service in order to proxy the degree of socially responsible management practices of Korean retail firms. This paper uses the ordinary least square method to investigate the above predictions. The publicly traded Korea retail firms listed in the Korean Exchange are analyzed from 2011 to 2016. To measure the degree of asymmetric information, this paper adopts the analyst dispersion and price impact measures. Results - This paper shows that the ES score has significantly positive relationships with these two measures of information asymmetry. The environmental score seems to increase the analyst dispersion measure and the social score appears to raise the price impact measure mores significantly. Conclusions - The results do not support the prior theory expecting a negative relationship between corporate social responsibility and the degree of asymmetric information. Environmental and social scores are found to affect the measures of information asymmetry differently.