• Journal of the Korean Applied Science and Technology
• /
• v.11 no.1
• /
• pp.79-85
• /
• 1994

All the activities and physical properties including surface tension' foaming power, foam stability, emulsifying power, dispersion effect of 3-(N, N-dimethyl N-alkylammonio)-2-hydroxyY-1-propane sulfonate (HSB)류와 3-CN-alkylamidopropyl-N,N-dimethylamm-onjo)-2-hydroxy-1-propane sulfonate (APSB) aquous solution were measured and critical micelle concentration was evaluated. Their cmc of hydroxy sulfobetaine derivatives evaluated by the surface tension method was $1.0{\times}10^{-3}{\sim}1.0{\times}10^{-4}$ mol/l, and surface tension of the aquous solution was decreased to $27{\sim}38dyne/cm$. The experimental results for foaming power, foam stability, emulsifying power in liquid paraffin showed a good surface active properties, especially, dispersion effect in ferric oxide exhibited some efficient surface active properties, and then it would be expected to application as detergent and dispersion agent.

• Journal of the Korean Society for Nondestructive Testing
• /
• v.32 no.1
• /
• pp.34-40
• /
• 2012

In this study, effects of bonding agent, e.g. epoxy, on the behavior of fundamental guided wave modes propagated in FRP plate bonded on a concrete, are investigated. Global matrix model of multilayered FRP-epoxy-concrete system was constructed to obtain the velocity and attenuation dispersion curves of the fundamental A0 and S0 modes. Two variables, thickness and elastic modulus of epoxy layer, were considered in the dispersion analysis. It was found that both the thickness and the elastic modulus of epoxy layer greatly affect the phase velocity and attenuation of S0 mode while those are negligible for A0 mode. Based on the results, it was concluded that S0 mode is more effective than A0 mode for bonding condition assessment for FRP plate bonded concrete.

• Polymer(Korea)
• /
• v.30 no.6
• /
• pp.505-511
• /
• 2006

We tried to prepare polystyrene composite particles containing carbon black by suspension polymerization with water as a reaction medium. Hydrophobic silica was selected as a stabilizer and oil-soluble azobisisobutyronitrile (AIBN), as an initiator. All polymerization reactions were carried out at a fixed temperature of $75^{\circ}C$. Stabilizer concentration was varied from $0.17{\sim}3.33wt%$ compared to water, where particles with $7.96{\mu}m$ in average diameter were obtained at 1.57 wt% of stabilizer. Increase in divinylbenzene concentration, as a crosslinking agent, from $0.1{\sim}1.0 wt%$ compared to monomer exhibited a large increase in average particle diameter Incorporation of 1wt% of carbon black compared to monomer produced an increase in average diameter It is speculated that viscosity lower than that necessary to induce even dispersion of carbon black particles led to poor dispersion, and as a result, large particles. For a styrene mixture containing 3 wt% carton black compared to monomer, enhanced dispersion due to an increase in carbon black concentration reduced average particle diameters. For styrene mixtures containing 1 and 3 wt% carbon black compared to monomer, preparticles before polymerization and polymer composite particles after polymerization showed a similar tendency towards particle formation. When carbon black concentration compared to monomer was increased to 5 and 7 wt%, styrene mixtures exhibited a large increase in viscosity and thus better dispersion of carbon black particles, which led to a decrease in preparticle diameters. However, these particles experienced agglomeration in the polymerization process, and polystyrene composite particles increased in average diameter.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2005.11a
• /
• pp.91-94
• /
• 2005

Polypropylene as a matrix has been used for wood polymer composites(WPC). In preparing WPC, the coupling agent, Polypropylene grafted Maleic Anhydride(PP-G-MA) was used in order to obtain a good interfacial bonding force between matrix and fillers and dispersion of wood powders. In this study, the effects of wood powder contents and water absorption on the mechanical properties were experimentally investigated. The tensile strength and flexural strength of composites reached its peak value when the wood powder content was around 60 wt%. However, the peak value of the impact was observed about 30 wt% of wood powder content. The tensile strength and flexural strength increase with increasing the wood power contents. But the impact strength decrease with increasing the wood powder contents. The slight change was observed with the water absorption in the WPC. The optimal condition of the compositions such as Anti-oxidant and UV stabilizers for the outdoor application was suggested in this research.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2003.05a
• /
• pp.261-266
• /
• 2003

This study is to investigate the heating value and noxious gases generation such as CO, NO and $SO_2$ known as dangerous gas for human from specimen made of cement and lightweight aggregate. The most quanity of CO gas is generated in EPS(Expanded Poly Styrene), core of commercial sandwich panel. Although specimens mainly composed of cement discharged the relatively less CO gas than organic core such as EPS, specimens which SBR was added discharged the very much amount of CO gas similar to EPS and especially, specimens including foaming agent, gas foaming agent or redipersible powder of VA/VeoVa showed the good properties in the generation of CO gas. From the standpoint of the generation of NO and $SO_2$ gas, both the core of commercial sandwich panel such as EPS, Glass wool and specimens made with polymer dispersion such as St/BA and SBR discharge the very much amount of NO and $SO_2$ gas in comparison of the other specimens. From this study, it was confirmed that organic materials such as core of commercial sandwich panel dischared much more noxious gas than specimens composed of cement and inorganic lightweight aggregate.

• Journal of the Korean Applied Science and Technology
• /
• v.26 no.3
• /
• pp.288-296
• /
• 2009

In this study, the silica-based hybrid material with high barrier property was prepared by incorporating ethylene-vinyl alcohol (EVOH) copolymer, which has been utilized as packaging materials due to its superior gas permeation resistance, during sol-gel process. In preparation of this EVOH/$SiO_2$ hybrid coating materials, the (3-glycidoxy-propyl)-trimethoxysilane (GPTMS) as a silane coupling agent was employed to promote interfacial adhesion between organic and inorganic phases. As confirmed from FT-IR analysis, the physical interaction between two phases was improved due to the increased hydrogen bonding, resulting in homogeneous microstructure with dispersion of nano-sized silica particles. However, depending on the range of content of added silane coupling agent (GPTMS), micro-phase separated microstructure in the hybrid could be observed due to insufficient interfacial attraction or possibility of polymerization reaction of epoxide ring in GPTMS. The oxygen barrier property of the mono-layer coated BOPP (biaxially oriented polypropylene) film was examined for the hybrids containing various GPTMS contents. Consequently, it is revealed that GPTMS should be used in an optimum level of content to produce the high barrier EVOH/$SiO_2$ hybrid material with an improved optical transparency and homogeneous phase morphology.

• Korean Chemical Engineering Research
• /
• v.52 no.1
• /
• pp.63-67
• /
• 2014

The effects of reactant composition on the particle size distribution, synthetic yield, and density of Phenol-formaldehyde bead were examined in the synthesis of resol-type phenolic resin. Decrease of the content of DI water as dispersion media can increase the viscosity of suspension, which may cause the difference of particle size distribution and aggregation. The average particle size of synthesized beads was also decreased with the increasing content of stabilizer which can affect the interfacial area. The amount of crosslinking agent showed no effect on the size distribution and synthetic yield, but it made a decrease in the density of synthesized bead due to the macropore in the bead.

• Journal of the Korean Society of Safety
• /
• v.28 no.3
• /
• pp.118-122
• /
• 2013

For safe evacuation in the fire disaster, the evacuees must find the exit and evacuate quickly. Especially, if the evacuees don't know the location of the exit, they have to depend on the evacuation guidance system. Because the more smoke spread, the less visibility is decreasing, it is difficult to find the way to the exit by the naked eye. For theses reasons, the evacuation guidance system is highly important. However, the evacuation guidance system without change of direction has the risk that introduce to the dangerous area. In the evacuation safety assessment scenario by the evacuation simulation has the same problem. Because the evacuee in the simulation evacuate by the shortest route to the exit, the simulation result is same like the evacuation without the evacuation guidance system. In this study, it was used with MAS (Multi Agent System)-based simulation program including the evacuation guidance system to implement the change of evacuation by fire. Using this method, confidence of evacuation safety assessment can be increase.

• Elastomers and Composites
• /
• v.36 no.4
• /
• pp.237-245
• /
• 2001

A study was made on the chemical treatment of silica and silane coupling agents, bistriethox ysilylpropyltetrasulfide(Si 69) and ${\gamma}$-mercaptopropyltrimethoxy silane (MPS) for reinforcement of silica formulation. The effects of chemical treatment method and the most popular two coupling agents were examined. The results clearly indicate that the wet method, coupling agent is combined chemically with the silica prior to mixing, has more dispersion, wetting ability, dynamic properties and stability than the dry method, coupling agent is premixed directly with the silica. The mixing was done using a bench-type kneader having two mixing cam and a two-roll mill, under approximately similar conditions. The physical properties of SBR vulcanizates give rise to marked improvements by addition of Si 69 and MPS in comparison with without silane coupling agents. The optimum amount of Si 69 and MPS was 2 w/w% by experiments in the dry method but was 4 w/w% by EA and TGA analysis in the wet method.

• Journal of the Korean Wood Science and Technology
• /
• v.42 no.4
• /
• pp.483-490
• /
• 2014

The effect of microfibrillated cellulose (MFC) content and coupling agent (polymeric methylene diphenyl diisocyanate, pMDI) on the properties of MFC-reinforced polybutylene succinate (PBS) nanocomposite. With increasing MFC content, tensile strength and elastic modulus were increased. More than 1.5 times in tensile strength of PBS/MFC(70/30) nanocomposite was improved by the addition of pMDI (1 phr), compared to the nanocomposite without pMDI. This trend was being significant in nanocomposite with higher MFC content. Thermal stability of the nanocomposite was increased by the addition of pMDI. These improvements is considered to be due to the improvement of MFC dispersion and interfacial adhesion between MFC and PBS matrix.