• Title/Summary/Keyword: Disperse Dye

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각종 white rot fungi에 의한 분산염료의 색제거 비교

  • Lee, Hyeon-Uk;Son, Dong-Chan;Im, Dong-Jun
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.402-405
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    • 2000
  • Batch culture system and continuous culture system were used to investigate the removal of disperse dye using several white rot fungi. White rot fungi used in the study were Coriolus hirsutus IFO 4917, Lenzites betulina IFO 6266, Coriolus versicolor IFO 30340 and Phanerochaete chrysosporium IFO 31249. The results of the batch culture experiment showed that white rot fungi used in this study had excellent dye removal abilities. Phanerochaete chrysosporium IFO 31249 was especially effective on the removal of disperse dyes. And continuous treatment of disperse red-60 was studied under bioreactor with vertical matrix using Phanerochaete chrysosporium IFO 31249. The removal efficiency of disperse red-60 were more than 95% in 0.20 ${\sim} 1.50 $hr^{-1}$ dilution rate and 90% in $1.83h^{-1}$ dilution rate.

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Dispersant-free dyeing of acetate with temporarily solubilized azo disperse dyes

  • Lee, Jung-Jin
    • Textile Coloration and Finishing
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    • v.18 no.5 s.90
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    • pp.15-21
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    • 2006
  • Temporarily solubilized azo disperse dyes containing ${\beta}$-sulfatoethylsufonyl group were applied to acetate fabric and the feasibility of dispersant-free dyeing was investigated. The color yields of the dyes on acetate fabric were found to be dependent on dye bath pH as well as dyeing temperature. The optimum results were obtained at pH 6 and $80^{\circ}C$. The dyes showed good exhaustion and levelling properties. Vinylsulfone derivatives of the dyes were prepared and applied to acetate with dispersant. Dyeing properties of the temporarily solubilized disperse dyes were similar to or better than those of the vinylsulfone dyes. The dyes showed moderate to good fastness properties on acetate.

Effect of the changes in Micropore Structure on the Dyeability of BTCA Finished Cotton Fibers (BTCA로 방추가공된 면섬유의 기공구조 변화가 염색성에 미치는 영향)

  • 최연주;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.27 no.11
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    • pp.1300-1306
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    • 2003
  • Cotton fibers were treated, with 1, 2, 3, 4-butanetetracarboxylic acid (BTCA) which is formaldehyde-free reagent to impart durable press performance. The dyeability, dyeing rate, and diffusion coefficient, of BTCA treated cottons were compared to prove the changes of pore size structure using direct dyes and disperse dyes. Diffusion coefficients of BTCA treated cotton fibers were determined at acidic conditions to figure out the effect of swelling. Since the dyeability of BTCA treated cotton fibers dyed with direct dyes were reduced, it is considered that the dyeability to direct dyes is related to the quantity of residual large pores. But, the dyeability to disperse dyes were increased due to the less reduction of small pore sizes and the increase of hydrophobicity in BTCA treated cotton cellulose. The dyeability to direct dye and disperse dye were decreased more at acidic conditions than at neutral conditions. It seemed that the swelling of pores in the fiber were inhibited.

Studies on Transfer Printing of Cotton and Polyester/Cotton Blended Fabrics Treated with Water Soluble Polyurethane Resin (수용성 폴리우레탄 수지 처리된 면 및 폴리에스테르/면 혼방직물의 전사날염에 관한 연구)

  • 황종호;전병익
    • Textile Coloration and Finishing
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    • v.11 no.5
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    • pp.13-21
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    • 1999
  • In this study, selected cotton fabrics and polyester/cotton(P/C) blended fabrics are treated with a soluble polyurethane(SPU) and then, printed by heat transfer to determine the effect of SPU treatment on dye uptake of the samples. The results obtained are as follows: 1) In heat transfer, dye-uptake gets higher in Vopotion to temperature and time. The optimum printing temperature and printing time of C.I. Disperse Orange 3 and C.I. Disperse Violet 1 are $200^\circ{C}$ and 50sec. 2) Dye-uptake gets higher according to SPU concentration ; both cotton and P/C fabrics show the highest at $100g/\ell$. 3) In color, as temperature, time and SPU concentration increase, P/C fabrics show more yellowish orange color than cotton fabrics in case of C.I. Disperse Orange 3 and P/C fabrics show more reddish violet color than cotton fabrics in case of C.I. Disperse Violet 1. 4) All fastness of cotton and P/C fabrics treated with SPU are good, but color fastness to washing and water of cotton fabrics treated with SPU are not good.

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Solubility Measurement and its Correlation of Disperse Dye in Supercritical HFC-134a (초임계 HFC-134a에 대한 분산염료의 용해도 측정과 모델링)

  • Park, Min-Woo;Bae, Hyo-Kwang
    • Korean Chemical Engineering Research
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    • v.40 no.6
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    • pp.715-718
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    • 2002
  • The supercritical dyeing process has been gaining the increasing importance because of environment reason. For further development of this process, it is needed to measure the solubility in supercritical fluids in the extensive ranges of temperature and pressure. In this study, using the semi-flow type apparatus consisted of supercritical fluid equilibrium cell, the solubility of disperse dye(C.I. disperse red 60) in supercritical HFC-134a has been measured at the temperatures of 383.2 K and 413.2 K, and in the pressure range of 50 bar to 160 bar. The solubility data are, with good agreement, correlated by an expanded liquid model which considers the supercritical fluid as compressed liquid.

Dyeing Property of Polyester in Byebath Containing Water and Water Miscible Organic Solvents (물/극성유기용매 혼합욕에서 폴리에스테르의 염색)

  • 김은아;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.1
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    • pp.100-107
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    • 1998
  • Polyester filaments were dyed with disperse dye in dyebath containing water and water miscible organic solvents . acetone, 1,4-dioxane, DMF. In case of Acetone and 1,4-dioxane, the equilibrium dyeuptake was maximun at the volume fraction 0.05. The equilibrium dye uptakes were decreased as volun~e fraction of organic solvents were increased. When the volume fractions of water miscible organic solvents were varied, dye uptake was increased constantly with dyeing time. In dyebath containing water and water miscible organicsolvent, the dyeuptake was increased quickly during initial 40∼ 60 min. and slowly increased there after. The slope of Ct/Coo to t was greater in dyebath containing water and water miscible organic solvents than dyebath containing water. The differences of the slope with volulne fractions of water miscible organic solvent were not shown big.

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A Study on the One Bath One Step Thermosol Dyeing of Polyester/Cotton Blended Fabrics (폴리에스터/면 혼방직물의 1욕 1단 서모졸 염색에 관한 연구)

  • Ro, Duck-Kil
    • Textile Coloration and Finishing
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    • v.20 no.1
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    • pp.16-21
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    • 2008
  • In this study the effects of swelling and fixing agent for the cotton side of polyester/cotton blended fabrics and the thermosol temperature on the dyeing properties and fastness. were investigated, when the polyester/cotton blended fabrics were dyed with a disperse dye which was able to dye both side of fiber by one bath one step thermosol process. The obtained results are as follows; The dye adsorption decreased with the increase of cotton blend ratio in polyester/cotton blended fabrics, when the ratio of swelling and fixing agent for cotton side was constant. As the thermosol temperature increased up to $210^{\circ}C$, the dye adsorption were increased, but that effect was less significant when the cotton blend ratio was higher.

Dyeing Properties of PET/Dyeable PP Double Knit Fabric (PET/가염PP 이종 편성물의 염색 특성)

  • Chang, Young-Min;Lee, Jin-Ah;Park, Jong-Ho;Koh, Joon-Seok;Jung, Young-Jin;Kim, Sung-Dong
    • Textile Coloration and Finishing
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    • v.20 no.2
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    • pp.53-58
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    • 2008
  • New dyeable PP fiber and several products from it has been developed through dispersing polyester copolymer into PP resin by a Korean synthetic fiber manufacturer and its colleagues. The dyeing properties of PET/dyeable PP double knit fabric were examined with three different types of disperse dye in this study. It was found that the disperse dye, exhausted on dyeable PP at early stage of dyeing, migrated to PET at elevated dyeing temperature when two fibers were dyed in the same dye bath. The ratios of dye distribution between two substrates dyed at $120^{\circ}C$ and $130^{\circ}C$ showed no difference. S type disperse dyes showed good build-up properties and acceptable color fastness while high light fastness type exhibited the lowest amounts of exhaustion but excellent color fastness. It might be concluded that the most appropriate dye for PET/dyeable PP double knit fabric was S type, and that some color difference between PET side and dyeable PP side was unvoidable.

Study on the Nanofiltration of Various Dye Solutions (NF막에 의한 다양한 염료용액의 막분리 특성)

  • Yang, Jeongmok;Kim, Tak-Hyun;Park, Cheolhwan;Kim, Jeehyeong;Kim, Sangyong
    • Clean Technology
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    • v.10 no.1
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    • pp.37-45
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    • 2004
  • This study examined the separation characteristics of some of the most commonly used disperse, reactive and acid dyes by nanofiltration membrane. The chemical characteristics of three major dye solutions such as chemical oxygen demand, total nitrogen, total organic carbon, color, suspended solids, total dissolved solids, conductivity were investigated in this work. Experiments showed that the types of dye had a significant effect on both permeate flux and rejection efficiencies mainly due to the differences among their chemical structures and natures. Especially, the nanofiltration of reactive dye solutions showed higher permeate flux, lower total dissolved solid rejection efficiency and higher organics rejection efficiency than those of disperse dye solutions.

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Preparation and Application of Functional Microsphere (II) Formation and Characteristics of Poly(ethylene-co-vinylacetate) Microsphere with Disperse Dye (기능성 마이크로스피어의 제조와 응용(II) 분산염료를 함유한 에틸렌-비닐아세테이트 중합체의 마이크로스피어 제조와 특성)

  • Lee, Shin-Hee;Cho, Hyun;Park, Soo-Min
    • Fashion & Textile Research Journal
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    • v.10 no.3
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    • pp.371-376
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    • 2008
  • Poly(ethylene-co-vinylacetate) (EVA) microspheres were prepared by thermally induced phase separation (TIPS) in toluene. The microsphere formation occurred by the nucleation and growth mechanism in metastable region. The effects of the concentration and component of the polymer and cooling rate on microsphere formation were investigated. The microsphere formation and growth were followed by the cloud point of the optical microscope measurement. The microsphere size distribution, which was obtained by particle size analyzer, became broader when the polymer concentration was higher, the content of vinyl acetate in EVA copolymer was higher, the cooling rate of EVA copolymer solution were lower. The content of disperse dye in EVA microsphere was obtained by TGA thermal analysis, the dye content of EVA15 and EVA18 were 3.5 and 2.0 wt% respectively.