• 한국생물공학회:학술대회논문집
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• 한국생물공학회 2000년도 춘계학술발표대회
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• pp.402-405
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• 2000

Batch culture system and continuous culture system were used to investigate the removal of disperse dye using several white rot fungi. White rot fungi used in the study were Coriolus hirsutus IFO 4917, Lenzites betulina IFO 6266, Coriolus versicolor IFO 30340 and Phanerochaete chrysosporium IFO 31249. The results of the batch culture experiment showed that white rot fungi used in this study had excellent dye removal abilities. Phanerochaete chrysosporium IFO 31249 was especially effective on the removal of disperse dyes. And continuous treatment of disperse red-60 was studied under bioreactor with vertical matrix using Phanerochaete chrysosporium IFO 31249. The removal efficiency of disperse red-60 were more than 95% in 0.20 ${\sim} 1.50 $hr^{-1}$ dilution rate and 90% in $1.83h^{-1}$ dilution rate.

• 한국염색가공학회지
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• 제18권5호
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• pp.15-21
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• 2006

Temporarily solubilized azo disperse dyes containing ${\beta}$-sulfatoethylsufonyl group were applied to acetate fabric and the feasibility of dispersant-free dyeing was investigated. The color yields of the dyes on acetate fabric were found to be dependent on dye bath pH as well as dyeing temperature. The optimum results were obtained at pH 6 and $80^{\circ}C$. The dyes showed good exhaustion and levelling properties. Vinylsulfone derivatives of the dyes were prepared and applied to acetate with dispersant. Dyeing properties of the temporarily solubilized disperse dyes were similar to or better than those of the vinylsulfone dyes. The dyes showed moderate to good fastness properties on acetate.

• 한국의류학회지
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• 제27권11호
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• pp.1300-1306
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• 2003

Cotton fibers were treated, with 1, 2, 3, 4-butanetetracarboxylic acid (BTCA) which is formaldehyde-free reagent to impart durable press performance. The dyeability, dyeing rate, and diffusion coefficient, of BTCA treated cottons were compared to prove the changes of pore size structure using direct dyes and disperse dyes. Diffusion coefficients of BTCA treated cotton fibers were determined at acidic conditions to figure out the effect of swelling. Since the dyeability of BTCA treated cotton fibers dyed with direct dyes were reduced, it is considered that the dyeability to direct dyes is related to the quantity of residual large pores. But, the dyeability to disperse dyes were increased due to the less reduction of small pore sizes and the increase of hydrophobicity in BTCA treated cotton cellulose. The dyeability to direct dye and disperse dye were decreased more at acidic conditions than at neutral conditions. It seemed that the swelling of pores in the fiber were inhibited.

• 한국염색가공학회지
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• 제11권5호
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• pp.13-21
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• 1999

In this study, selected cotton fabrics and polyester/cotton(P/C) blended fabrics are treated with a soluble polyurethane(SPU) and then, printed by heat transfer to determine the effect of SPU treatment on dye uptake of the samples. The results obtained are as follows： 1) In heat transfer, dye-uptake gets higher in Vopotion to temperature and time. The optimum printing temperature and printing time of C.I. Disperse Orange 3 and C.I. Disperse Violet 1 are $200^\circ{C}$ and 50sec. 2) Dye-uptake gets higher according to SPU concentration ; both cotton and P/C fabrics show the highest at $100g/\ell$. 3) In color, as temperature, time and SPU concentration increase, P/C fabrics show more yellowish orange color than cotton fabrics in case of C.I. Disperse Orange 3 and P/C fabrics show more reddish violet color than cotton fabrics in case of C.I. Disperse Violet 1. 4) All fastness of cotton and P/C fabrics treated with SPU are good, but color fastness to washing and water of cotton fabrics treated with SPU are not good.

• Korean Chemical Engineering Research
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• 제40권6호
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• pp.715-718
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• 2002

폴리에스터의 염색공정에서 발생하는 폐수문제를 근원적으로 해결하기 위해서 초임계 유체를 이용한 건식염색기술이 관심의 대상이 되고 있다. 본 연구에서는 반 유통형인 초임계유체 평형실험장치를 이용하여 초임계 상태의 HFC-134a에 대한 분산염료인 C. I. disperse red 60의 용해도를 382.2 K와 413.2 K의 온도와 50, 70, 100, 130, 160 bar의 압력에서 측정하였다. 초임계유체를 고압의 액체로 간주하는 확장액체모델에 측정된 데이터들을 상관하면 실험값과 계산값이 잘 일치하였다.

• 한국의류학회지
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• 제22권1호
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• pp.100-107
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• 1998

Polyester filaments were dyed with disperse dye in dyebath containing water and water miscible organic solvents . acetone, 1,4-dioxane, DMF. In case of Acetone and 1,4-dioxane, the equilibrium dyeuptake was maximun at the volume fraction 0.05. The equilibrium dye uptakes were decreased as volun~e fraction of organic solvents were increased. When the volume fractions of water miscible organic solvents were varied, dye uptake was increased constantly with dyeing time. In dyebath containing water and water miscible organicsolvent, the dyeuptake was increased quickly during initial 40∼ 60 min. and slowly increased there after. The slope of Ct/Coo to t was greater in dyebath containing water and water miscible organic solvents than dyebath containing water. The differences of the slope with volulne fractions of water miscible organic solvent were not shown big.

• 한국염색가공학회지
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• 제20권1호
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• pp.16-21
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• 2008

In this study the effects of swelling and fixing agent for the cotton side of polyester/cotton blended fabrics and the thermosol temperature on the dyeing properties and fastness. were investigated, when the polyester/cotton blended fabrics were dyed with a disperse dye which was able to dye both side of fiber by one bath one step thermosol process. The obtained results are as follows; The dye adsorption decreased with the increase of cotton blend ratio in polyester/cotton blended fabrics, when the ratio of swelling and fixing agent for cotton side was constant. As the thermosol temperature increased up to $210^{\circ}C$, the dye adsorption were increased, but that effect was less significant when the cotton blend ratio was higher.

• 한국염색가공학회지
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• 제20권2호
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• pp.53-58
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• 2008

New dyeable PP fiber and several products from it has been developed through dispersing polyester copolymer into PP resin by a Korean synthetic fiber manufacturer and its colleagues. The dyeing properties of PET/dyeable PP double knit fabric were examined with three different types of disperse dye in this study. It was found that the disperse dye, exhausted on dyeable PP at early stage of dyeing, migrated to PET at elevated dyeing temperature when two fibers were dyed in the same dye bath. The ratios of dye distribution between two substrates dyed at $120^{\circ}C$ and $130^{\circ}C$ showed no difference. S type disperse dyes showed good build-up properties and acceptable color fastness while high light fastness type exhibited the lowest amounts of exhaustion but excellent color fastness. It might be concluded that the most appropriate dye for PET/dyeable PP double knit fabric was S type, and that some color difference between PET side and dyeable PP side was unvoidable.

• 청정기술
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• 제10권1호
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• pp.37-45
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• 2004

본 연구는 섬유산업에서 많이 사용되고 있는 주요염료인 분산성, 반응성, 산성염료를 대상으로 일반적인 수질오염항목인 COD, T-N, TOC, color, SS, TDS, conductivity 등을 분석하여 각각의 염료용액의 성상을 비교 분석하였고, NF막을 투과시켰을 경우 투과 flux와 배제율이 염료용액 종류에 따라서 어떻게 다른 양상을 나타내는지를 연구하였다. 결과적으로, 염료종류별 화학적 성질 및 구조적인 차이에 의하여 염료용액의 용해도 및 유기물부하 등이 달라짐을 알 수 있었고, 특히, 분산성 염료와 반응성염료는 이들 화학적 성질의 차이가 매우 현격하게 달라서 투과 flux 감소현상과 유기물, color, 부유물 및 용존 고형물, 이온성 물질 등의 배제율이 다른 양상을 보임을 알 수 있었다. 반응성염료 용액은 분산성염료 용액에 비하여 투과 flux는 높지만, TDS의 배제율이 낮은 반면, 분산성염료 용액은 부유성 고형물 농도가 높아 투과 flux가 낮고, 유기물질의 배제율이 낮은 특성을 나타낸다.

• 한국의류산업학회지
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• 제10권3호
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• pp.371-376
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• 2008

Poly(ethylene-co-vinylacetate) (EVA) microspheres were prepared by thermally induced phase separation (TIPS) in toluene. The microsphere formation occurred by the nucleation and growth mechanism in metastable region. The effects of the concentration and component of the polymer and cooling rate on microsphere formation were investigated. The microsphere formation and growth were followed by the cloud point of the optical microscope measurement. The microsphere size distribution, which was obtained by particle size analyzer, became broader when the polymer concentration was higher, the content of vinyl acetate in EVA copolymer was higher, the cooling rate of EVA copolymer solution were lower. The content of disperse dye in EVA microsphere was obtained by TGA thermal analysis, the dye content of EVA15 and EVA18 were 3.5 and 2.0 wt% respectively.