• Textile Coloration and Finishing
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• v.2 no.4
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• pp.231-236
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• 1990

The diffusion coefficient of C.I. Disperse Red 4 in the dyeing of carrier-pretreated poly (ethylene terephthalate) film was Investigated by Sekido's film-rolled method. From the result it was shown that the diffusion coefficient increases exponentially with the content-ration of carrier in the film, and, for the films containing same concentration of carrier, the carrier effect was enhanced with the molar volume of the carriers. The greater carrier effect was accompanied by the decrease in diffusion activation energy and entropy, which shows that the carrier with larger molar volume plasticizes PET film to more extent.

• Textile Coloration and Finishing
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• v.15 no.5
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• pp.321-326
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• 2003

In order for disperse dye based ink to be fitted with the critical requirements of ink jet printing, this study was undertaken to investigate the effects of 6 different dispersants on the milling efficiency of insoluble dye particles and dispersion stability of the final ink. It was found that a polystyrene dispersant with high molecular weight exerted relatively better dispersion stability which may be associated with its steric stabilization effect in the ink solution.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2002.04a
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• pp.9-12
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• 2002

The Dyestuff is fixed to the fiber to color it in a unique way depending on the chemistry between them. Whenever there arose problems in coloring fibers, the chemistry of dyestuff could be adjusted to solve them. That manner new concept dye classes, e.g., reactive dyes, disperse dyes, cationic dyes, have arrived along with the introduction of new fibers. The attempt has made to introduce the new reactive dye to solve this problem.

• Textile Coloration and Finishing
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• v.2 no.1
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• pp.21-30
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• 1990

In order to obtain high dye uptake initially, polyethylene terephthalate (PET) filaments were dyed with C.I.Disperse Orange 3 and Red 1 in mixed solvents of tetrachloroethylene acidic solvent, ethyl alcohol and tetrachloroethylene basic solvent, DMF. The dyeing behavior in the mixed solvent of tetrachloroethylene and basic solvent, DMF, the initial uptake of disperse dyes increased rapidly. The shrinkage of PET increased when the solubility parameter values of PET fiber and mixed solvent approached graduately.

• Textile Coloration and Finishing
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• v.20 no.2
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• pp.53-58
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• 2008

New dyeable PP fiber and several products from it has been developed through dispersing polyester copolymer into PP resin by a Korean synthetic fiber manufacturer and its colleagues. The dyeing properties of PET/dyeable PP double knit fabric were examined with three different types of disperse dye in this study. It was found that the disperse dye, exhausted on dyeable PP at early stage of dyeing, migrated to PET at elevated dyeing temperature when two fibers were dyed in the same dye bath. The ratios of dye distribution between two substrates dyed at $120^{\circ}C$ and $130^{\circ}C$ showed no difference. S type disperse dyes showed good build-up properties and acceptable color fastness while high light fastness type exhibited the lowest amounts of exhaustion but excellent color fastness. It might be concluded that the most appropriate dye for PET/dyeable PP double knit fabric was S type, and that some color difference between PET side and dyeable PP side was unvoidable.

• Journal of the Korean Society of Clothing and Textiles
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• v.30 no.2 s.150
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• pp.255-265
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• 2006

The purpose of this study was to examine the dyeing properties of four kinds of composite yams that were twisted in different processes. The composite yarns consist of acetate and functional polyester in ratio of 70 : 30. The composite yams were dyed at 100$^{circ}C$ and 125$^{circ}C$ using three types of dyes, disperse dyes for acetate fiber, PET fiber and PET-acetate blended fiber, in the three primary colors. The exhaustion($\%$) and K/S value were observed for each case. Also the effects of four different twisting processes to dyeing properties and physical properties were examined. Regardless of twisting methods, the composite yarns that were dyed at 125$^{circ}C$ had higher exhaustion($\%$) than those were dyed at 100$^{circ}C$ with all three types of dyes; However, tendency of the K/S value after reduction cleaning process was measured at 100$^{circ}C$ and the value measured 125$^{circ}C$ had a great difference with disperse dyes for acetate and dyes for PET. The difference of the K/S values of composite yarns, when dyed at 100$^{circ}C$ and 125$^{circ}C$ with disperse dyes for PET-acetate blended fiber, was almost negligible. According to twisting methods K/S values were in the following order: AP1 > AP3 > AP4> AP2. This means that AP1, treated at 220$^{circ}C$, had the highest K/S value and K/S value becomes higher as the yam is higher twisted and becomes lower as lower twisted. On the other hand, the dry shrinkage and wet shrinkage showed low shrinkage rate when the twist was high and steam setting temperature was high.

• Journal of the Korean Ceramic Society
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• v.42 no.10 s.281
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• pp.649-653
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• 2005

A mono-disperse Ni powders for multilayer ceramic capacitors were prepared in a large scale by solution reduction method using $NiSO_{4}$ $N_{2}$$H_{4}$and NaOH. The exothermic reactions such as Ni-complex formation between highly concentrated $NiSO_{4}$ and $N_{2}$$H_{4}$ and the reduction of $Ni^{2+}$ into Ni provided thermal energy sufficient for spontaneous solution-reduction reaction. Because well-defined Ni particles could be prepared without external heating, the present method was named as 'auto-thermal method'. The formation of Ni­complex, the precipitation of $Ni(OH)_{2}$ gel triggered by NaOH addition, and its reduction into Ni by dissolution-recrystallization route were the reaction mechanism. The preparation of mono-disperse and spherical Ni powder was attributed to uniform distribution of reducing agent $N_{2}$$H_{2}$ within $Ni(OH)_{2}$ gel due to the decomposition of$NiSO_{4}$-$N_{2}$ $H_{4}$ complex.

• Textile Coloration and Finishing
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• v.10 no.1
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• pp.25-32
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• 1998

In the prior study, we found that the dye uptakes of C. I. Disperse Violet 1 on PET in hexane and cyclohexane were higher than those in the other solvents. Therefore, in this study, the dye uptakes and the partition coefficients in alkanes having different number of carbon atoms were obtained and their relationship to the solubilities of the dye in alkanes was also investigated. As the number of carbon atoms of alkanes increases, solubility of the dye increases but the dye uptake decreases. This is due to the fact that the hydrophobicity of alkanes become relatively strong as increasing the number of carbon atoms. It was also found that the dye uptakes in iso-alkanes were larger than those in normal alkanes. This is because that the branched alkanes(iso-alkanes), judging from the tendency of lowering solubility and increasing dye uptake as decreasing the number of carbon atoms of alkanes, behave like the alkanes with less number of carbon atoms rather than the alkanes with the same number of carbon atoms. The logarithmic plot of the dye uptakes vs. the solubilities of the dye showed that the dye uptakes are linearly and inversely proportional to the solubilities. This is in good accordance with the results of the prior study. The heat of dyeing was also calculated from the equilibrium adsorptions at various temperatures. It seemed that the dyeings of PET by C. I. Disperse Violet 1 in nonane, decane, iso-pentane and iso-octane were rather endothermic processes. Dyeing rates in alkanes were somewhat delayed unlike general appearances in solvent dyeing.

• Textile Coloration and Finishing
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• v.31 no.3
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• pp.135-146
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• 2019

A series of azo based disperse dyes were synthesized and applied to polyester(PET) fiber in supercritical carbon dioxide($ScCO_2$). Various aniline derivatives were used as diazo component and coupled with glycine ethylester or carbonic acid ethylester derivatives to give azo based disperse dyes. Depending on the various diazo substituents, absorption maxima varied from 415 to 529nm in acetone. Dyeing in $ScCO_2$ was carried out at $120^{\circ}C$ and 250bar pressure for 2hrs with 0.5% o.w.f. of dye concentration. Dyed PET fiber had excellent brightness and good light, washing and perspiration(acid/alkali) fastness properties.

• Journal of Electrochemical Science and Technology
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• v.12 no.1
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• pp.82-91
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• 2021

This study was conducted to investigate the effect of initial pH, current density, and electrolysis time on process performance in terms of decolorization and chemical oxygen demand (COD) removal from disperse dyebath wastewater (DDW) by mono-polar parallel laboratory scale electrocoagulation (EC) process. COD reduction of 51.3% and decolorization of 92.8% were obtained with operating cost of 0.19 €/㎥ treated wastewater for Al-Al electrode pair, while 90.5% of decolorization and 49.2% of COD reduction were obtained with operating cost of 0.20 €/㎥ treated wastewater for an Fe-Fe electrode pair. The amount of sludge production were highly related to type of the electrode materials. At the optimum conditions, the amount of sludge produced were 0.18 kg/㎥ and 0.28 kg/㎥ for Al-Al and Fe-Fe electrode pairs, respectively. High decolorization can be explained by the hydrophobic nature of the disperse dye, while limited COD removal was observed due to the high dissolved organic matter of the DDW based on auxiliary chemicals. Energy, electrode, and chemical consumptions and sludge handling were considered as major cost items to find a cost-effective and sustainable solution for EC. The contribution of each cost items on operating cost were determined as 10.0%, 51.1%, 30.5% and 8.4% for Al-Al, and they were also determined as 9.0%, 38.0%, 40.5% and 12.5% for Fe-Fe, respectively. COD reduction and decolorization were fitted to first-order kinetic rule.