• Journal of Electrochemical Science and Technology
• /
• 제6권4호
• /
• pp.121-130
• /
• 2015

The micro emulsion method has been successfully used for preparing perovskite LaCoO₃ with uniform, fine-shaped nanoparticles showing high activity as electro catalysts in oxygen reduction reactions (ORRs). They are, therefore, promising candidates for the air-cathode in metal-air rechargeable batteries. Since the activity of a catalyst is highly dependent on its specific surface area, nanoparticles of the perovskite catalyst are desirable for catalyzing both oxygen reduction and evolution reactions. Herein, LaCoO₃ powder was also prepared by sol-gel method for comparison, with a broad particle distribution and high agglomeration. The electro catalytic properties of LaCoO₃ and LaCoO₃-carbon Super P mixture layers toward the ORR were studied comparatively using the rotating disk electrode technique in 0.1 M KOH electrolyte to elucidate the effect of carbon Super P. Koutecky-Levich theory was applied to acquire the overall electron transfer number (n) during the ORR, calculated to be ~3.74 for the LaCoO₃-Super P mixture, quite close to the theoretical value (4.0), and ~2.7 for carbon-free LaCoO₃. A synergistic effect toward the ORR is observed when carbon is present in the LaCoO₃ layer. Carbon is assumed to be more than an additive, enhancing the electronic conductivity of the oxide catalyst. It is suggested that ORRs, catalyzed by the LaCoO₃-Super P mixture, are dominated by a 2+2-electron transfer pathway to form the final, hydroxyl ion product.

• 한국자동차공학회논문집
• /
• 제13권5호
• /
• pp.134-141
• /
• 2005

Semi-Spherical Continuously Variable Transmission(SS-CVT) is the CVT which transmits power by rolling friction between dry metals, and its outstanding advantage is the ability of realizations of neutral, forward and reverse states without relying on any other devices. A spherical shaped variator transmits power and also changes gear ratio where keeping contact with a output disk. The frictional direction to transmit power and the other direction to change gear ratio are perpendicular to each other, so we can describe that two dimensional rolling friction is occurred in the contact point between the variator and the disk. Since magnitudes or relations of the two forces are completely unknown, they were analyzed by the experiments in this study. We determined the variables related with the friction phenomena by the dimensional analysis, and manufactured the SS-CVT test bench which could measure the related variables. Finally, the empirical formula for evaluating the two friction forces was proposed based on the experimental results.

• Restorative Dentistry and Endodontics
• /
• 제38권1호
• /
• pp.26-30
• /
• 2013

Objectives: The aim of this study was to investigate the relationship between the apical foramen morphology and the length of merged canal at the apex in type II root canal system. Materials and Methods: This study included intact extracted maxillary and mandibular human premolars (n = 20) with fully formed roots without any visible signs of external resorption. The root segments were obtained by removing the crown 1 mm beneath the cementum-enamel junction (CEJ) using a rotary diamond disk. The distance between the file tip and merged point of joining two canals was defined as Lj. The roots were carefully sectioned at 1 mm from the apex by a slow-speed water-cooled diamond saw. All cross sections were examined under the microscope at ${\times}50$ magnification and photographed to estimate the shape of the apical foramen. The longest and the shortest diameter of apical foramen was measured using ImageJ program (1.44p, National Institutes of Health). Correlation coefficient was calculated to identify the link between Lj and the apical foramen shape by Pearson's correlation. Results: The average value of Lj was 3.74 mm. The average of proportion (P), estimated by dividing the longest diameter into the shortest diameter of the apical foramen, was 3.64. This study showed a significant negative correlation between P and Lj (p < 0.05). Conclusions: As Lj gets longer, the apical foramen becomes more ovally shaped. Likewise, as it gets shorter, the apical foramen becomes more flat shaped.

• Tribology and Lubricants
• /
• 제35권6호
• /
• pp.330-336
• /
• 2019

Conditioning is a process involving pad surface scraping by a moving metallic disk that is electrodeposited with diamond abrasives. It is an indispensable process in chemical-mechanical planarization, which regulates the pad roughness by removing the surface residues. Additionally, conditioning maintains the material removal rates and increases the pad lifetime. As the conditioning continues, the pad profile becomes unevenly to be deformed, which causes poor polishing quality. Simulation calculates the density at which the diamond abrasives on the conditioner scratch the unit area on the pad. It can predict the profile deformation through the control of conditioner dwell time. Previously, this effect of the diamond shape on conditioning has been investigated with regard to microscopic areas, such as surface roughness, rather than global pad-profile deformation. In this study, the effect of diamond shape on the pad profile is evaluated by comparing the simulated and experimental conditioning using two conditioners: a) random-shaped abrasive conditioner (RSC) and b) uniform-shaped abrasive conditioner (USC). Consequently, it is confirmed that the USC is incapable of controlling the pad profile, which is consistent with the simulation results.

• 대한소아치과학회지
• /
• 제43권3호
• /
• pp.275-283
• /
• 2016

본 연구는 복합레진의 연마방법에 따른 표면특성을 평가하기 위해, microhybrid 레진(Filtek$^{TM}$ Z250)과 nanofill 레진(Filtek$^{TM}$ Z350)을 연마 전, abrasive disk(Sof-lex) 연마 후, polishing brush(Occlubrush) 연마 후로 나누어 분석하였다. 그 결과 레진 표면조도는 연마 후 증가하였는데, 미세조도는 연마방법에 따른 차이가 없었으나 거시조도는 Occlubrush를 이용한 경우 현저하게 커졌다(p < 0.05). Sof-lex 연마의 경우 레진의 filler까지 연마되어 표면이 보다 균일한 형상을 보였으나 Occlubrush 연마시편은 기질층이 뜯겨져 나간 불균일한 형상을 보였다. 두 연마방법 간의 미세경도 유의차는 없었으며(p > 0.05), 연마 후 경도 값이 약 25% 상승하였다. 결론적으로, 복합레진의 표면경도 향상을 위하여 적합한 연마가 필요하며, Sof-lex를 이용한 연마가 더 우수한 것으로 사료된다.

• Journal of information and communication convergence engineering
• /
• 제14권1호
• /
• pp.35-39
• /
• 2016

In this paper, we develop a 94-GHz single balanced mixer with low conversion loss using planar Schottky diodes on a GaAs substrate. The GaAs Schottky diode has a nanoscale anode with a T-shaped disk that can yield high cutoff frequency characteristics. The fabricated Schottky diode with an anode diameter of 500 nm has a series resistance of 21 Ω, an ideality factor of 1.32, a junction capacitance of 8.03 fF, and a cutoff frequency of 944 GHz. Based on this technology, a 94-GHz single balanced mixer was constructed. The fabricated mixer shows an average conversion loss of -7.58 dB at an RF frequency of 92.5 GHz to 95 GHz and an IF frequency of 500 MHz with an LO power of 7 dBm. The RF-to-LO isolation characteristics were greater than -32 dB. These values are considered to be attributed to superior Schottky diode characteristics.

• 소음진동
• /
• 제8권2호
• /
• pp.267-273
• /
• 1998

This study aims at performing sensitivity analysis of piezoelectric smart structure for minimizing radiated noise from the structure, The structure consists of a flat plate on which disk shaped piezoelectric actuator is mounted, and finite element modeling is used for the structure. The finite element modeling uses a combination of three dimensional piezoelectric, flat shell and transition elements so thus it can take into account the coupling effects of the piezoelectric device precisely and it can also reduce the degrees of freedom of the finite element model. Electric potential on the piezoelectric actuator is taken as a design variable and total radiated power of the structure is chosen as an objective function. The objective function can be represented as Rayleigh's integral equation and is a function of normal displacements of the structure. For the convenience of computation, all degrees of freedom of the finite element equation is condensed out except the normal displacements of the structure. To perform the design sensitivity analysis, the derivative of the objective function with respect to the normal displacements is found, and the derivative of the norma displacements with respect to the design variable is calculated from the finite element equation by using so called the adjoint variable method. The analysis results are compared with those of the finite difference method, and shows a good agreement. This sensitivity analysis is faster and more accurate than the finite difference method. Once the sensitivity analysis program is used for gradient-based optimizations, one could achieve a better convergence rate than non-derivative methods for optimal design of piezoelectric smart structures.

• 한국분말재료학회지
• /
• 제5권4호
• /
• pp.319-323
• /
• 1998

Powder forging with a back pressure was investigated for production of automobile and compressor parts made of a rapidly solidified Al-Si alloy powder. Disk-shaped green compacts made of a rapidly solidified Al-Si alloy powder were hot forged, and hubs were formed by loading back pressure on their top. The influences of the back pressure and die temperatures on forgeabiliy and properties of parts made of a rapidly solidified Al-Si alloy powder were examined. This method was also applied to the production of a scroll part. The results of these studies are summarized as follows : 1. A back pressure on the hub top is very effective for consolidation and preventing crack formation in the hub. 2. When a back pressure tess than 98 MPa is applied, the forging pressure increases by the same amount of the applied back pressure. With more than 98 MPa, the forging pressure increases further due to an increased friction at the hub side. 3. Die temperatures higher than approximately 670k are needed in order to consolidate well the hub top without cracks.

• 한국전자통신학회논문지
• /
• 제8권2호
• /
• pp.219-226
• /
• 2013

무선 센서 네트워크에 있어서 전역 도청에 대응하는 통신 근원지와 도착치의 위치기밀을 유지하기 위해서는 수많은 속임수용 더미 패킷들이 지속적으로 발행된다. 근원지나 도착지를 포함하는 특정 크기의 보호구역들을 설정한 후, 이 안의 노들들에 대해서만 데이터전송 중에 더미 패킷들을 생성하도록 제한하여 근원지와 도착지의 위치기밀성을 제공하면서도 패킷발생량을 줄이는 접근방안을 고려한다. 제안 프로토콜을 설계하고 형식화한 상세한 프로토콜 명세서를 제시한 후, 주요 특성과 정확성을 검증한다.

• The Journal of Advanced Prosthodontics
• /
• 제10권2호
• /
• pp.132-137
• /
• 2018

PURPOSE. The purpose of this study was to evaluate and compare three polishing systems on the surface roughness and phase transformation of monolithic zirconia. MATERIALS AND METHODS. 100 disk shaped specimens (10 mm diameter, 3 mm thickness) were fabricated from monolithic zirconia blocks. 20 specimens were left as a control group and remaining specimens were grinded by diamond bur to simulate the occlusal adjustments. Grinded specimens were randomly divided into 4 groups: group G (no polishing), group M (Meisinger, zirconia polishing kit), group E (EVE Diacera, zirconia polishing kit), and group P (EVE Diapol, porcelain polishing kit). Surface roughness was measured with profilometer and surface topography was observed with SEM. XRD analysis was performed to investigate the phase transformation. Statistical analysis was performed with one-way ANOVA and Tukey's post hoc tests at a significance level of P=.05. RESULTS. All polishing groups showed a smoother surface than group G. Among 3 polishing systems, group M and group E exhibited a smoother surface than the group P. However, no significant differences were observed between group M and group E (P>.05). Grinding and polishing did not cause phase transformations in zirconia specimens. CONCLUSION. Zirconia polishing systems created a smoother surface on zirconia than the porcelain polishing system. Phase transformation did not occur during the polishing procedure.