• Title/Summary/Keyword: Discharge temperature

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Electrochemical Properties of Carbon Felt Electrode for Vanadium Redox Flow Batteries by Liquid Ammonia Treatment (암모니아수 처리에 따른 바나듐 레독스 흐름전지용 탄소펠트 전극의 전기화학적 특성)

  • Kim, Yesol;Cho, Seho;Park, Se-Kook;Jeon, Jae-Deok;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.25 no.3
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    • pp.292-299
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    • 2014
  • In this study, nitrogen doped carbon felt (CFt) is prepared using thermal oxidation and liquid phase ammonia treatment to improve the efficiency for vanadium redox flow batteries (VRFB). The electrochemical properties of prepared CFt electrodes are investigated using cyclic voltammetry (CV) and charge/discharge test. The XPS result shows that the increase of liquid phase ammonia treatment temperature leads to the increased nitrogen functional group on the CFt surface. Redox reaction characteristics using CV reveal that the liquid phase ammonia treated CFt electrodes are more reversible than the thermally oxidized CFt. When CFt is treated by the liquid phase ammonia at $300^{\circ}C$, VRFB cell energy efficiency, voltage efficiency, and current efficiency are increased about 6.93%, 1.0%, and 4.5%, respectively, compared to those of the thermally oxidized CFt. These results are because nitrogen functional groups on CFt help to improve the electrochemical properties of redox reaction between electrode and electrolyte interface.

Ecology of Marssonina Blotch Caused by Diplocarpon mali on Apple Tree in Kyungpook, Korea (사과나무 갈색무늬병의 발생생태)

  • Kim, Dong-Ah;Lee, Soon-Won;Lee, Joon-Tak
    • Current Research on Agriculture and Life Sciences
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    • v.16
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    • pp.84-95
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    • 1998
  • Apple Marssonina blotch, caused by Diplocarpon mali, which has been increasing on apple trees and become one of the most serious diseases on apple trees in Korea since the begining of 1990's. In this study, ecology of Marssonina blotch including disease incidence and spore dispersals was surveyed from 1992 to 1995 in Kyungpook, and factors influencing the incidence of the disease were analyzed. Marssonina blotch began to occur on apple leaves in June and was observed commonly in most of apple orchards after August, and increased rapidly in September. The incidence of this disease was high at the year of low temperature and a lot of precipitation. The conidia discharge began to occur in May and continued to October, and the peak period of spore release was in August and usually more than 70% of total spore release of the year released from August to September. The incidence of the disease was high in the northern and mountain are as such as Yeongjoo, Chungsong, Andong, and relatively low in the southern areas such as Kunwi, Yongchon. Jonathan cultivar was the most susceptible to Marssonina blotch, and Jonagold, Sekaiichi was secondly susceptible and the next Fuji was more susceptible than Tsugaru. The incidence of the disease was relatively high in orchards which cultivation management of irrigation, drainage, air circulation, fertilization, and fungicide spraying were poor.

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A study for High Efficiency Dewatering of Sludge Contained Fine Particles (미세입자(微細粒子)를 함유(含有)한 슬러지의 고효율(高效率) 탈수(脫水) 연구)

  • Lee, Jung-Eun;Lee, Jae-Keun
    • Resources Recycling
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    • v.15 no.4 s.72
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    • pp.36-43
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    • 2006
  • There was some difficulty dewatering properties due to small porosity diameter of cake, when pigment sludge contained fine particle was formed by cake under the dewatering. It was difficult to dewater the sludge with fine particles with the conventional mechanical dewatering method. This study was to improve the dewatering rate as discharging the water from porosity of cake easily, supplying the low heat to the cake layer. Thermal dewatering equipment of piston type to keep up constant temperature on the cake was set up and relative experiment was conducted for sludge of 200 g with fine pigment particle. As test results. filtration of 176.8 g, cake weight of 19.4 g, cake thickness of 4.2 mm was measured, and it was analyzed that the water content of cake was 47 wt% and dewatering velocity, which moaned the residual d교 sloid amount per dewatering area, was $2.1DS\;m^{2}{\cdot}cycle$. This results showed that filtration increased, cake weight and thickness decreased and dewatering velocity increased against mechanical dewatering method. And water content of cake decreased about 30%, so the result which dewatering rate improved was drew generally. The reason is that the inner vapor pressure working at the cake porosity increased as applying the low heat to the cake layer, which lead to discharge the water from porosity easily. Therefore, this study was estimated by the useful technology for sludge reduction.

Frequency Dependency of Electrical Property Stabilization during Vulcanization of Modified NR/IR Blends (개질된 NR/IR 블랜드의 가황 반응에서 나타나는 전기적 특성 안정화의 주파수 의존성)

  • Ahn, Won-Sool
    • Elastomers and Composites
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    • v.39 no.3
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    • pp.179-185
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    • 2004
  • Frequency dependency or electrical property stabilization during vulcanization of modified NR/IR composite materials was studied using in-situ electrical property measuring technique. Volume resistivity(p) before and after vulcanization reaction of the sample was measured as the function or frequency in the range or 1Hz to 10kHz at reaction temperatures of 130, 140, 150, and $160^{\circ}C$, respectively. A double stabilization mode of frequency dependency was observed, in which a slow stabilization process of p to a value of ca. $1.0{\times}10^7\;{\Omega}-cm$ occurred after a drastic initial decrease from ca. $9.0{\times}10^7\;{\Omega}-cm$. In addition, notable temperature dependencies of p values were also observed before and after vulcanization reaction, that is, p values at 130 and $140^{\circ}C$ after vulcanization were observed as about 1/3 of those values before vulcanization. All the observed facts were considered as the results from the interaction between the electrode and the bulk sample materials, i.e., electronic charge-discharge, and from the structure change of samples including CB rearrangement by the vulcanization.

Semidiurnal Tidal Variation in Water Quality in Asan Bay during four Seasons (계절별로 조사한 조석에 따른 아산만의 수질 변동)

  • Kim, Se Hee;Shin, Yong Sik
    • Journal of Marine Life Science
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    • v.5 no.1
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    • pp.25-33
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    • 2020
  • The Asan Bay, which has semi-diurnal tide with macro-tidal range, is affected by both freshwater discharge from the sluice gates in the sea dikes and tidal seawater inputs from the Yellow sea. Understanding water quality change in response to tides is important since tides can impact the short-term variations in physical and chemical water properties as well as the response of biological properties. The diel variations in water quality were seasonally investigated at 2 hour intervals from a fixed station in the Asan Bay. In the results, water temperature and salinity consistently fluctuated in phase or out of phase with tidal height. Especially salinity was positively correlated with tidal height. The concentrations of total suspended solids were higher in the bottom water than in the surface and fluctuated greatly over the tidal cycle recording higher values at low tide than at high tide. Nitrite+nitrate levels also fluctuated out of phase with tidal height and correlated negatively with tidal height. Other nutrients also showed a similar pattern. The pattern was distinct in July when freshwater was discharged before the field sampling. The concentrations of organic materials, total nitrogen and total phosphorus greatly fluctuated over the tidal cycle and were generally out of phase with tidal height. Most materials except particulate organic forms were correlated with salinity indicating that freshwater inputs were sources for the materials similarly to the dissolved inorganic nutrients. The results suggest that water quality (except dissolved oxygen and pH) and nutrients including organic materials was largely affected by tides in the Asan Bay.

Analysis of Proper Linked Treatment Load Using GPS-X Simulation (GPS-X 시뮬레이션을 이용한 적정 연계처리부하량 분석)

  • Kim, Sungji;Lee, Jiwon;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.21 no.3
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    • pp.244-250
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    • 2019
  • Due to the industrial development and population growth, it has recently been shown that there are many problems caused by the rinked treatment water in local goverments and sewage treatment plants. The rinked treatment water has a characteristic of low flow rate and high concentration unlike general sewage. These characteristics increase sewage treatment difficulty and sewage treatment fee of sewage treatment facilities. Among the many influencing factors that increase sewage treatment unit cost, 'linked treatment load/design inflow load (%)' was derived as the most correlated factor. Through the selection and modeling of sewage treatment plants, the excess scope of design discharge water quality was investigated under the conditions of temperature and the conditions of 'linked treatment load/design inflow load (%)' taking into account the effects of the four seasons. The study found that for TN, 'linked treatment load/design inflow load (%)' was 19.7%, 22.6%, 25.1%and 27.7%, respectively, under conditions of $5^{\circ}C$, $10^{\circ}C$, $20^{\circ}C$ and $25^{\circ}C$. In case of TP, 'rinked treatment load/design inflow load (%)' was 10.7%, 12.2%, 15.6% and 17.5% at $5^{\circ}C$, $10^{\circ}C$, $20^{\circ}C$, and $25^{\circ}C$, respectively, under conditions of $5^{\circ}C$, $10^{\circ}C$, $20^{\circ}C$ and $25^{\circ}C$.

Evaluation of Absorption and Release, Survival Efficiency and Recovery Rate of Transport Medium according to the CLSI M40-A2 Standard (CLSI M40-A2 기준에 따른 수송배지의 흡수 및 배출, 생존 효율, 회수율 평가)

  • Ha, Sung-Il;Suk, Hyun-Soo;Shin, Jeong-Seob;Heo, Woong;Park, Kang-Gyun;Park, Yeon-Joon
    • Korean Journal of Clinical Laboratory Science
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    • v.51 no.2
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    • pp.164-170
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    • 2019
  • The absorption and release capacities, survival efficiency, and recovery rates of five kinds of transport media were evaluated based on the swab elution method (Quantitative) of CLSI (Clinical and Laboratory Standards Institute) M40-A2. Liquid media showed mostly better results than semi-solid media in the three evaluations. The flocked swabs had better ability to absorption and discharge bacteria than the standard swabs. The liquid medium (S4) had the best survival efficiency. Pneumococcal strains with poor growth had a higher survival efficiency and recovery rate in liquid media (S4, S5). The results of microbial recovery showed that S. pyogenes met all the CLSI standards in all media. S. pneumoniae was inadequate in the semi- solid media (S2, S3) and all the remaining media met the criteria. H. influenzae was unsuitable in semi-solid media (S1, S3) and met the criteria in semi-solid medium (S2) and liquid medium (S4, S5). The viability of the H. influenzae, pneumococcal strain causing respiratory disease, was poor in most media. Overgrowth of P. aeruginosa was observed at room temperature. The combination of liquid medium and flocked swab confirmed the best results in the three evaluation methods.

Repair of Plasma Damaged Low-k Film in Supercritical Carbon Dioxide (초임계이산화탄소를 이용한 플라즈마 손상된 다공성 저유전 막질의 복원)

  • Jung, Jae-Mok;Lim, Kwon-Taek
    • Clean Technology
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    • v.16 no.3
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    • pp.191-197
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    • 2010
  • Repair reaction of plasma damaged porous methyl doped SiOCH films was carried out with silylation agents dissolved in supercritical carbon dioxide ($scCO_2$) at various reaction time, pressure, and temperature. While a decrease in the characteristic bands at $3150{\sim}3560cm^{-1}$ was detectable, the difference of methyl peaks was not identified apparently in the FT-IR spectra. The surface hydrophobicity was rapidly recovered by the silylation. In order to induce effective repair in bulk phase, the wafer was heat treated before reaction under vacuum or ambient condition. The contact angle was slightly increased after the treatment and completely recovered after the subsequent silylation. Methyl groups were decreased after the plasma damage, but their recovery was not identified apparently from the FT-IR, spectroscopic ellipsometry, and secondary ion mass spectroscopy analyses. Furthermore, Ti evaporator was performed in a vacuum chamber to evaluate the pore sealing effect. The GDS analysis revealed that the open pores in the plasma damaged films were efficiently sealed with the silylation in $scCO_2$.

Determining Groundwater-surface Water Interaction at Coastal Lagoons using Hydrogeochemical Tracers (수리화학적 환경 추적자를 이용한 강원도 석호지역에서의 지하수-지표수 상호작용에 대한 연구)

  • Dong-Hun Kim;Jung-Yun Lee;Soo Young Cho;Hee Sun Moon;Youn-Young Jung;Yejin Park;Yong Hwa Oh
    • Journal of Soil and Groundwater Environment
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    • v.28 no.2
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    • pp.1-11
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    • 2023
  • Groundwater-surface water interaction was evaluated using water quality parameters (temperature and electrical conductivity), distributions of stable water isotopes (δ2H and δ 18O), and Rn-222 in lagoon water, groundwater, and seawater at three coastal lagoons (Songji (SJ), Youngrang (YR), and Sunpo (SP) Lagoon) in South Korea. From the results of composition and distributions of δ2H and δ18O, it was found that groundwater fraction of lagoon water in YR Lagoon (76%) was slightly higher than those of SJ (42%), and SP (63%) Lagoon. Based on Rn-222 mass balance model, groundwater discharge into SJ Lagoon in summer 2020 was estimated to be (3.2±1.1)×103 m3 day-1, which showed a similar or an order of magnitude higher than the results of previous studies conducted in coastal lagoons. This study can provide advanced techniques to evaluate groundwater-surface water interaction in coastal lagoons, wetlands, and lakes, and help to determine the effects of groundwater on coastal ecosystems.

Improvement of lower hybrid current drive systems for high-power and long-pulse operation on EAST

  • M. Wang;L. Liu;L.M. Zhao;M.H. Li ;W.D. Ma;H.C. Hu ;Z.G. Wu;J.Q. Feng ;Y. Yang ;L. Zhu ;M. Chen ;T.A. Zhou;H. Jia;J. Zhang ;L. Cao ;L. Zhang ;R.R. Liang;B.J. Ding ;X.J. Zhang ;J.F. Shan;F.K. Liu ;A. Ekedahl ;M. Goniche ;J. Hillairet;L. Delpech
    • Nuclear Engineering and Technology
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    • v.54 no.11
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    • pp.4102-4110
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    • 2022
  • Aiming at high-power and long-pulse operation up to 1000 s, some improvements have been made for both 2.45 GHz and 4.6 GHz lower hybrid (LH) systems during the recent 5 years. At first, the guard limiters of the LH antennas with graphite tiles were upgraded to tungsten, the most promising material for plasma facing components in nuclear fusion devices. These new guard limiters can operate at a peak power density of 12.9 MW/m2. Strong hot spots were usually observed on the old graphite limiters when 4.6 GHz system operated with power >2.0 MW [B. N. Wan et al., Nucl. Fusion 57 (2017) 102019], leading to a reduction of the maximum power capability. With the new limiters, 4.6 GHz LH system, the main current drive (CD) and electron heating tool for EAST, can be operated with power >2.5 MW routinely. Long-pulse operation up to 100 s with 4.6 GHz LH power of 2.4 MW was achieved in 2021 and the maximal temperature on the guard limiters measured by an infrared (IR) camera was about 540 ℃, much below the permissible value of tungsten material (~1200 ℃). A discharge with a duration of 1056 s was achieved and the 4.6 GHz LH energy injected into the plasma was up to 1.05 GJ. Secondly, the fully-active-multijunction (FAM) launcher of 2.45 GHz system was upgraded to a passive-active-multijunction (PAM), for which the density of optimum coupling was relatively low (below the cut-off value). Good coupling with reflection coefficient ~3% has been achieved with plasma-antenna distance up to 11 cm for the new PAM. Finally, in order to eliminate the effect of ion cyclotron range of frequencies (ICRF) wave on 4.6 GHz LH wave coupling, the location of the ICRF launcher was changed to a port that is located 157.5° toroidally from the 4.6 GHz LH system and is not magnetically connected.