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Influence of the Fluorine-doping Concentration on Nanocrystalline ZnO Thin Films Deposited by Sol-gel Process

  • Yoon, Hyunsik;Kim, Ikhyun;Kang, Daeho;Kim, Soaram;Kim, Jin Soo;Son, Jeong-Sik;Leem, Jae-Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.204.2-204.2
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    • 2013
  • Wide band gap II-VI semiconductors have attracted the interest of many research groups during the past few years due to the possibility of their applications in light-emitting diodes and laser diodes. Among the II-VI semiconductors, ZnO is an important optoelectronic device material for use in the violet and blue regions because of its wide direct band gap (Eg ~3.37 eV) and large exciton binding energy (60 meV). F-doped ZnO (FZO) and undoped ZnO thin films were grown onto quartz substrate by the sol-gel spin-coating method. The doping level in the solution, designated by F/Zn atomic ratio of was varied from 0 to 5 in 1 steps. To investigate the effects of the structure and optical properties of FZO thin films were investigated using X-ray diffraction (XRD), UV-visible spectroscopy, and photoluminescence (PL). In the XRD, the residual stress, FWHM, bond length, and average grain size were changed with increasing the doping concentration. For the PL spectra, the high INBE/IDLE ratio of the FZO thin films doping concentration at 1 at.% than the other samples.

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A Study on the Process of Hybrid Welding Using Pulsed Nd:YAG Laser and Dip-transfer DC GMA Heat Sources (펄스형 Nd:YAG 레이저와 단락이행모드의 직류 GMA 열원을 이용한 하이브리드 용접 공정에 대한 연구)

  • Cho, Won-Ik;Na, Suck-Joo
    • Journal of Welding and Joining
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    • v.25 no.6
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    • pp.71-77
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    • 2007
  • Until now, many researches on laser-arc hybrid welding processes have been conducted mainly for high power CW laser and high direct current arc to weld the thick steel plates for shipbuilding. Recently, however the usage of thin steel plates, which tend to be deformed easily by thermal energy, is been increasing because of demand of light structure such as car body in the automobile industry. Accordingly, heat sources having relatively low heat input such as pulsed laser, dip-transfer DC GMA and pulsed GMA seem to be applied more increasingly and the study about those heat sources is needed more intensively. Any heat source mentioned above can not stand alone without weld defects at a relatively high welding speed for increasing the welding productivity. This is main reason to apply the hybrid welding process which uses pulsed laser and low-heat-input GMA heat sources simultaneously to weld the thin steel plate. In this study, parameters of pulsed laser and dip-transfer DC GMA welding are studied firstly through preliminary experiments, and then analyzed in the viewpoint of their physical phenomena. Before conducting the hybrid welding, a pulse control technique is developed based on the parallel port communication and Visual C++ 6.0. Owing to development of this technique, interactions of laser and arc pulses can be controlled consistently. Using the pulse control technique, the hybrid welding is conducted and then its interactive welding phenomenon is analyzed.

Experimental Analysis of Bubble Dynamics Induced by Pulsed-Laser Heating of Absorbing Liquid (흡광 액체의 펄스 레이저 가열에 의해 생성된 기포 거동의 실험적 해석)

  • Jang Deok-Suk;Hong Jong-Gan;Choa Sung-Hoon;Kim Dong-Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.5 s.248
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    • pp.413-421
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    • 2006
  • The bubble dynamics induced by direct laser heating is experimentally analyzed as a first step to assess the technical feasibility of laser-based ink-jet technology. To understand the interaction between laser light and ink, the absorption spectrum is measured for various ink colors and concentrations. The hydrodynamics of laser-generated bubbles is examined by the laser-flash photography. When an Ar ion laser pulse (wavelength 488 nm) with an output power up to 600 mW is incident on the ink solution through a transparent window, a hemispherical bubble with a diameter up to ${\sim}100{\mu}m$ can be formed with a lifetime in a few tens of microsecond depending on the laser power and the focal-spot size. Parametric study has been performed to reveal the effect of laser pulse width, output power, ink concentration, and color on the bubble dynamics. The results show that the bubble generated by a laser pulse is largely similar to that produced by a thin-film heater. Consequently, the present work demonstrates the feasibility of developing a laser-actuated droplet generation mechanism for applications in ink-jet print heads. Furthermore, the results of this work indicate that the droplet generation frequency is likely to be further increased by optimizing the process parameters.

Philanthropic Experience and Giving Intention: The Mediating Role of the Trust and Positive Attitude towards NGOs (나눔 경험과 기부의도: 신뢰 및 긍정 태도의 매개효과 연구)

  • Lee, Seonho;Park, Woosung
    • The Journal of the Korea Contents Association
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    • v.17 no.5
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    • pp.56-67
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    • 2017
  • This study aims to examine the influence of the philanthropic experience on the giving intention. There are many precedent studies arguing this influence but the empirical results are mixed or sometimes contradictory. We stipulate that this could be resolved by introducing the mediating variables such as trust and positive attitudes towards NGOs. Results of the empirical analysis based on the 189 person living in Seoul area show that philanthropic experience directly influence the giving intention, and it exert an influence on the giving intention directly through the trust and positive attitudes towards NGOs. And it is shown that the indirect effect produced by the mediating variables and process in less than the direct effect. Results support precedent studies emphasizing the important role of the philanthropic experience in the giving intention, and shed light on the process through which philanthropic experience determines the giving intention. A practical implication might be that we have to do a great effort to experience philanthropic activities in one's early age, and a theoretical implication be that researchers need to pay attention to find another mediating variables having explanatory power.

Methodologies for Inhalation Exposure Assessment of Engineered Nanomaterial-containing Consumer Spray Products (분사형 소비자 제품 중 나노 물질의 흡입 노출 평가 방법)

  • Park, Jihoon;Park, Mijin;Yoon, Chungsik
    • Journal of Environmental Health Sciences
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    • v.45 no.5
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    • pp.405-425
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    • 2019
  • Objective: This study aimed to review the methodologies for evaluation of consumer spray products containing engineered nanomaterials (ENM), particularly focusing on inhalation exposure. Method: Literature on the evaluation methods for aerosolized ENM exposure from consumer spray products were collected through academic web searching. Common methodologies used in the literature, including research reports and academic articles, were also introduced. Results: The number of ENM-containing products have shown a considerable increase over recent years, from 54 in 2005 to 1,827 in 2018. Currently there is still discussion over the existing regulations with regard to product safety. Analysis of both ENM suspensions in the products and their aerosols is important for risk assessment. Comparison between the phases suggests how the size and concentration of particles change during the spray process. To analyze the ENM suspensions, dynamic light scattering, electron microscopy techniques, and inductively coupled plasma with mass spectrometry were used. In the aerosol monitoring, direct-reading instruments have been used to monitor the aerosols and conventional active sampling is used together to supplement the lack of real-time monitoring. There are also some models for estimating inhalation exposure. These models may be used to estimate mass exposure to nanomaterials contained in consumer products. Conclusion: Although there is no standardized method to evaluate ENM exposure from consumer products, many concerns about ENM have emerged. Every potential measure to reduce exposure to ENM from spray product use should be implemented through a precautionary recognition.

Wind tunnel investigation of correlation and coherence of wind loading on generic tall twin buildings in close proximity

  • Lim, Juntack;Bienkiewicz, Bogusz
    • Wind and Structures
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    • v.18 no.4
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    • pp.443-456
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    • 2014
  • A popular modern architectural form for tall buildings is two (or more) towers which are structurally linked through such features as a shared podium or sky-bridges. The fundamental features of the wind loading and the structural links of such buildings can be studied by measuring load components on the individual unlinked towers along with their correlations. This paper describes application of dual high frequency force balance (DHFFB) in a wind tunnel study of the base wind loading exerted on generic tall twin buildings in close proximity. Light models of two identical generic tall buildings of square plan were mounted on DHFFB and the base wind loading exerted on the buildings was simultaneously acquired. The effects of the relative positions of the buildings on the correlations and coherences involving loading components on each building and on the two buildings were investigated. For some relative positions, the effects of the building proximity on the wind loading were significant and the loading was markedly different from that exerted on single buildings. In addition, the correlations between the loadings on the two buildings were high. These effects have potential to significantly impact, for example, the modally-coupled resonant responses of the buildings to the aerodynamic excitations. The presented results were not meant to be recommended for direct application in wind resistant design of tall twin buildings. They were intended to show that wind loading on tall buildings in close proximity is significantly different from that on single buildings and that it can be conveniently mapped using DHFFB.

Comparison and Consideration on Foreign Guidances for Establishing Risk Assessment Method of Total Petroleum Hydrocarbons in Korea (국내 석유계총탄화수소 위해성평가 방법 마련을 위한 국외 지침 비교 및 고찰)

  • Yun, Sung-Mi;Noh, Hoe-Jung;Kim, Ji-In;Yoon, Jeong-Ki;Lim, Ga-Hee;Lee, Hong-gil;Jo, Hun-Je;Kim, In-Ja;Hwang, Ji-Ae;Kim, Hyun-Koo
    • Journal of Soil and Groundwater Environment
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    • v.23 no.6
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    • pp.54-72
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    • 2018
  • This study reviewed standard operation procedures for fractionation and analytical methods of total petroleum hydrocarbons (TPH) in north america and european countries to aid proper establishment of risk assessment protocols associated with TPH exposure in Korea. In current, the TPH fraction methods established by Massachusetts Department of Environmental Protection (MassDEP) and Total Petroleum Hydrocarbon Criteria Working Group (TPHCWG) are most frequently employed worldwide. Both methods were developed on the basis of direct exposure of TPH from soil, although the method by TPHCWG also took into account the mobility of TPH. Volatile and extractable fractions of petroleum hydrocarbons were analyzed either separately or together. TPH fractionation methods were evaluated based on conservative toxicity values considering the uncertainty of risk assessment in light of current standard protocol for analyzing soil contaminants in Korea, and it was concluded that the method developed by MassDEP is more appropriate.

A Study on Changes and Challenges in Operation of Urban Regeneration Project in Gangwon-do Due to COVID-19 (코로나19 사태에 따른 강원도 도시재생사업 운영 변화와 과제)

  • Ham, Kwang-Min
    • Journal of Environmental Science International
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    • v.30 no.2
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    • pp.153-159
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    • 2021
  • This study aims to suggest the direction of urban regeneration policies of Gangwon-do in accordance with COVID-19 outbreak, and the results are as follows. First, it is inevitable to urgently execute the project from the perspective of cities and counties in Gangwon-do, where the promotion of urban regeneration projects has been delayed due to COVID-19 incident. As a result, it is highly likely to cause the employees overloaded and have negative effect on achieving the goals of urban regeneration, so, it is necessary to provide support measures at the government and provincial level, such as the actual execution index and the adjusting time of start and completion of particular business. Second, as the uncertainty of COVID-19 continues, it needs to strengthen the operation and monitoring of urban regeneration support centers in Gangwon-do and examine the changes in business operation plans in advance. In particular, the decrease in visitors to traditional markets and restaurants is expected to have a direct effect on small business owners engaged in the service industry. Therefore, it is necessary to actively consider the utilization plans of smart city regeneration, such as online shopping and non-contact payment. Third, it is necessary to phase in smart urban regeneration training focused on information weakness to narrow the digital gap, in preparation for general lifestyle changes such as contactless and non-face-to-face interactions. At a time when new light is being shed on local areas, which are quieter than heavily populated cities, a project that reflects the regional characteristics and culture of Gangwon-do is necessary.

Effects of adolescents' parental intimacy, parental supervision, peer pressure, and TV alcohol advertising on drinking (청소년의 부모친밀도, 부모감독, 또래압력, TV술광고가 음주행위에 미치는 영향)

  • Ju, Hyeon-Jeong
    • Journal of Digital Convergence
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    • v.18 no.12
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    • pp.363-375
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    • 2020
  • This study attempted to verify the structural model of the influence of parental intimacy, parental supervision, peer pressure, and TV alcohol advertising on drinking behavior for adolescents. It was conducted through a self-written questionnaire from May 1 to 28, 2019, targeting 602 students in grades 1 to 3 of 8 middle schools in G city. Results First, The direct effect on drinking behavior was in the order of peer pressure and TV alcohol advertisement, and they explained the degree of drinking behavior by 14.4%. second, Parental intimacy has an indirect effect on peer pressure and drinking behavior through TV alcohol advertising. Parental supervision has an indirect effect on drinking alcohol through TV alcohol advertisements. In multiple groups, there is a difference between the groups in the parental supervision and peer pressure, and the parental supervision and the channel coefficient of TV alcohol advertisement. In order to reduce drinking behavior, a realistic light that can cope with peer pressure is needed.

A review of 3D printing technology for piezoresistive strain/loadcell sensors (3D 프린팅 센서 연구 동향 소개-전왜성 변형/로드셀 센서 중심으로)

  • Cho, Jeong Hun;Moon, Raymond Hyun Woo;Kim, Sung Yong;Choi, Baek Gyu;Oh, Gwang Won;Joung, Kwan Young;Kang, In Pil
    • Journal of Sensor Science and Technology
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    • v.30 no.6
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    • pp.388-394
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    • 2021
  • The conventional microelectromechanical system (MEMS) process has been used to fabricate sensors with high costs and high-volume productions. Emerging 3D printing can utilize various materials and quickly fabricate a product using low-cost equipment rather than traditional manufacturing processes. 3D printing also can produce the sensor using various materials and design its sensing structure with freely optimized shapes. Hence, 3D printing is expected to be a new technology that can produce sensors on-site and respond to on-demand demand by combining it with open platform technology. Therefore, this paper reviews three standard 3D printing technologies, such as Fused Deposition Modeling (FDM), Direct Ink Writing (DIW), and Digital Light Processing (DLP), which can apply to the sensor fabrication process. The review focuses on strain/load sensors having both sensing material features and structural features as well. NCPC (Nano Carbon Piezoresistive Composite) is also introduced as a promising 3D material due to its favorable sensing characteristics.