• Title/Summary/Keyword: Direct Coupling

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The Study of Steady-State Interaction Between AC and DC Lines on the Same Transmission Tower (AC 및 DC 송전 선로 병렬 연계에 따른 정상상태 커플링 영향 분석)

  • Yoon, Jong-Su
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.59 no.7
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    • pp.1221-1225
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    • 2010
  • The application of the AC and DC lines on the same transmission tower is an economical and practical approaching that increase the power transmission capacity of an existing transmission corridor. But, In this case, Inductive and capacitive coupling between AC and DC lines on the same tower should be investigated in advance. According to the installation plan of 80kV ${\pm}$60MW bipole HVDC in Cheju, KOREA that will be commissioned until 2011, DC lines will parallely operate with 154kV 2 AC lines in existed 154kV AC 4 lines transmission tower. This paper presents the steady state analysis results about the interaction between 154kV AC and 80kV DC lines in the same transmission tower.

Optical Properties of $I^B-AI-VI^B_2$$I^B-AI-VI^B_2 :Co^{2+}$ Crystals ($I^B-AI-VI^B_2$$I^B-AI-VI^B_2 :Co^{2+}$결정의 광학적 특성연구)

  • 김화택;김창대;윤창선;진문석;최성휴
    • Journal of the Korean Vacuum Society
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    • v.4 no.3
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    • pp.334-341
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    • 1995
  • IB-AI-VIB2 및 IB-AI-VIB2 :Co2+ 결정을 고순도 원소를 출발 물질로 하고 iodine을 수송 매체로 사용하여 chemical transport reaction method로 성장시켰다. 성장된 결정의 결정구조는 chalcopyrite 구조였으며, energy gap은 direct band gap으로 3.514~1.814 eV 정도로 주어졌으며, cobalt를 불순물로 첨가할 때 energy gap은 감소하였다. IB-AI-VIB2 :Co2+ 결정에서 첨가된 cobalt가 모체결정의 Td symmetry site에 Co2+ ion으로 위치하여, Co2+ ion의 energy 준위 사이의 전자전이에 기인하는 불순물 광흡수 peaks가 나타났다. 이 불순물 광흡수 peaks에 결정장 이론을 적용하여 구산 1st-order spin-orbit coupling parameter(λ)는 -183~ -189cm-1정도였고, 2nd-order spin-orbit coupling parameter(P)는 225~239 cm-1정도였으며, crystal field parameter(Dq)는 328~395cm-1, Racah parameter(B)는 531~552cm-1정도였다.

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Facile Syntheses and Multi-orthofunctionalizations of Tertiary Benzamides

  • Paek, Kyung-Soo;Kim, Kyung-Mo;Kim, You-Seung
    • Bulletin of the Korean Chemical Society
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    • v.14 no.6
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    • pp.732-739
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    • 1993
  • Good yields were usually obtained in Pd(O)-catalyzed Suzuki aryl-aryl coupling reaction, even when both coupling partners had an ortho tertiary benzamide functional group. The direct ortho functionalization of oligomeric tertiary benzamides at Snieckus condition is dependent on the chain length. Tertiary benzamide 1 can be o,o-dilithiated only by metal-halogen exchange of the 2,6-dihalo-compound. Bis-tertiary benzamide 9 can be o,o'-dilithiated with excess(4.1 equivalents) s-butyllithium/TMEDA as the lithiating agent. Tris-tertiary benzamide 21 is hard to o,o"-difunctionalize due to steric interactions among the tertiary benzamide functional groups, and due to steric interactions between these functional groups and others (if present) on the termini of the terphenyl unit.

Peptide Synthesis with Polymer Bound Active Ester III. The Effect of Spacer Arm in Peptide Synthesis with 1-Phenyl-3-methyl-4-oximino pyrazole Resin (고분자에 결합된 활성 에스테르에 의한 펩티드합성 III. 1-페닐-3-메틸-4-옥시미노피라졸레진을 이용한 펩티드 합성에서 Spacer Arm의 효과)

  • Wang, Young;Lee, Yoon-Sik
    • Applied Chemistry for Engineering
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    • v.4 no.1
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    • pp.132-143
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    • 1993
  • Aminomethyl polystyrene resins were prepared either from chloromethyl-resin(Merrifield resin) or from direct amidoalkylation of polystyrene resin. Two kinds of aminomethlyl resin were lengthened with spacer arms via sequential coupling of five ${\varepsilon}$-aminocaproic acids(ACA) respectively. In case of the resin prepared from the Merrifield resin, the amounts of free amino group of the resin were reduced by 25~30% after each coupling of ACA. But the one from direct amidoalkylation showed 3~5% loss after each coupling of ACA. 4-Nitroso-5-aminopyrazole resin was made by reacting ACA spacer arm resin, which was made from direct amidoalkylated resin, with 5-phenyl-7-methylpyrazole [4,3-c][1,2,4]oxadiazin-3-one. Several polymeric active esters of N-blocked amino acids were prepared from the 4-nitroso-5-aminopyrazole bound resins. In anchoring step of the amino acid derivatives on the resin, no substantial effect of bulkiness was found. 4-Nitroso-5-aminopyrazole bound active ester resins were found to be very reactive in N-acylation, The resulting peptides were obtained with 90~95% yield and characterized by NMR and other physical methods.

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Study for the separation and comparison of azo dyes and their diazo components (아조염료와 디아조 성분의 분리 및 비교에 관한 연구)

  • Jeong, Hyuk
    • Analytical Science and Technology
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    • v.19 no.1
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    • pp.50-57
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    • 2006
  • Well known environmental wastes from dye industry were separated by the micellar electrokinetic capillary chromatography(MECC). These wastes include H-acid modifier and 2-naphthylamine-1,5-disulfonic acid, and are known to be the diazo components of the azo dye. The results of the separation were compared with the result obtained by the HPLC using ion-pairing mechnism. MECC method was also applied to separate a few direct dyes including Direct Blue 2, Direct Blue 6 and Direct Blue 15, and reactive dye such as Reactive Orange 4. Informations about the diazo components of any azo dye could be obtained by comparison of electropherogram of the reduction solution of given dye with those obtained from standard materials such as H-acid, J-acid, ${\gamma}$-acid, orthanilic acid, sulfanilic acid and 2-naphthylamine-1,5-disulfonic acid which are used as diazo components of the typical azo dyes. It has been concluded that MECC and HPLC with ion-pairing mechanism could be successfully applied for the analysis of unknown dyes and their diazo components.

Direct Syntheses of $\beta-Mannopyranosyl$ Disaccharides from 4,6-O-Benzylidene Derivatives of Ethylthio $\alpha-D-Mannopyranosides$ Donors

  • Yun, Mi Gyeong;Sin, Yeong Suk;Cheon, Geun Ho
    • Bulletin of the Korean Chemical Society
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    • v.21 no.6
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    • pp.562-566
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    • 2000
  • $\beta-D-Mannopyranosyl$ disaccharides have been obtained from the coupling of 4,6-O-benzylidene derivatives of ethylthio $\alpha-D-mannopyranoside$ employing NIS-TfOH promoter. NIS-TfOH promoted couplings of the corresponding ethylthio $\beta-D-glucopyranoside$ and produced $\alpha-D-glucopyranosyl$ disaccharides. IDCP (iodonium dicollidine perchlorate) was inactive toward the 4,6-O-benzylidenated ethylthio glucopyranosyl donor. However,lDCP coupled the 4,6-O-benzylidenated $ethylthio-\beta-D-galactopyranoside$ to give a-D-galactopyranosyl disaccharides.

Operating Characteristics on Coupling of Fuel-Cell System with Natural Gas Reformer (휴대전원용 직접알코올 연료전지의 OCV특성 연구)

  • Park, Se-Joon;Choi, Yong-Sung;Lee, Kyung-Sup
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.4
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    • pp.592-596
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    • 2009
  • DAFC(direct alcohol fuel cell) takes the same structure and operational principle with PEMFC(Proton exchange membrane fuel cell). However, DAFC, which uses liquid alcohol instead of hydrogen as fuel, is able to be used as a portable power for small-scaled electronic devices such as MP3, PMP, and mobile phone because alcohol is quite convenient steady-state compound to carry and store it. This paper presents the OCV(open circuit voltage) characteristics of the cases which are alcohol species and different weight rate of ethanol, respectively. The OCV of methanol fuel cell is slightly higher 0.2V than ethanol one, and 8% wt. rate ethanol is rated as the most appropriate fuel for DAFC.

Numerical Modeling of Soot Formation in $C_2H_4$/Air Turbulent Non-premixed Flames ($C_2H_4$/Air 비예혼합 난류화염의 매연생성 모델링)

  • Kim, Tae-Hoon;Woo, Min-O;Kim, Yong-Mo
    • Journal of the Korean Society of Combustion
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    • v.15 no.4
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    • pp.22-28
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    • 2010
  • The Direct Quadrature Method of Moments (DQMOM) has been presented for the solution of population balance equation in the wide range of the multi-phase flows. This method has the inherently interesting features which can be easily applied to the multi-inner variable equation. In addition, DQMOM is capable of easily coupling the gas phase with the discrete phases while it requires the relatively low computational cost. Soot inception, subsequent aggregation, surface growth and oxidation are described through a population balance model solved with the DQMOM for soot formation. This approach is also able to represent the evolution of the soot particle size distribution. The turbulence-chemistry interaction is represented by the laminar flamelet model together with the presumed PDF approach and the spherical harmonic P-1 approximation is adopted to account for the radiative heat transfer.

A Design of Low Frequency Noise Figure Improvement of RF Circuit for Direct Conversion Receiver (직접 변환 방식의 저주파 잡음 특성 개선을 위한 RF 전치부 설계 연구)

  • Choi, Hyuk-Jae;Choi, Jin-Kyu;Kim, Tae-Seong;Park, Do-Hyeon;Kim, Hyeong-Seok
    • 한국정보통신설비학회:학술대회논문집
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    • 2009.08a
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    • pp.305-308
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    • 2009
  • This paper presents the design and analysis of RF Front End for Wireless Heartbeat measurement System. In this work LNA, an inductor connected at the gate of the cascode transistor and capacitive cross-coupling are strategically combined to reduce the noise and the nonlinearity influences of the cascode transistors in a differential LNA. The Mixer is implemented by using the Gilbert-type configuration, cross pmos injection technique and the resonating technique for the tail capacitance. The resulting LNA achieves 1.26 dB NF, better than 1.88dB NF Typical Also Mixer resulting achieves 9.8dB at 100KHz.

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