• Title/Summary/Keyword: Dipole-dipole Interaction

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Gelation Behavior of Acrylonitrile Copolymer/Dimethylformamide Solution and Mechanical Properties of Films Obtained from It′s Solution (아크릴로니트릴공중합체-디메틸포름아마이드 용액의 겔화 거동 및 겔필름의 물성)

  • 오영세;한삼숙;송기원
    • Polymer(Korea)
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    • v.24 no.6
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    • pp.787-793
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    • 2000
  • The acrylonitrile copolymer/dimethylformamide (DMF) solutions were prepared to investigate the gelation behavior and critical gel concentration (c*). Gelation is rapidly progressed with the increase of molecular weight of copolymer, but significantly delayed with supercooling temperature and comonomer contents. The c* behavior showed contrary trend against gelation behavior. In dynamic viscoelastic test, two glass-transition region were observed in film obtained from gelled solution whereas one glass-transition in film obtained from true solution. This result supports the idea that an ordered junction zone is formed by the dipole-dipole interaction of intermolecularly neighboring stereo-regular parts of atactic acrylonitrile copolymer chains due to a nucleation process in the solution.

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Adsorption of Pentachlorophenol (PCP) on Clay Minerals from Hexane Solution (Hexane 용액중(溶液中)에서 점토용물(粘土鏞物)에 의(依)한 PCP 흡착(吸着))

  • Choi, Jyung
    • Korean Journal of Soil Science and Fertilizer
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    • v.7 no.3
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    • pp.141-145
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    • 1974
  • Adsorption experiments were carried out with several clay minerals and PCP hexane solution in order to clarify the status of adsorbed PCP on the clay surface. The amount of PCP adsorption on clay minerals was much greater in the clay-hexane system than in the clay water system. Among the clay minerals, allophane and imogolite ($SiO_2/Al_2O_3$ ratio of about 1) were the most efficient adsorbents of PCP. The PCP adsorption from hexane solution was greatly hindered by the presence of water, suggesting the occurrence of adsorption by a dipole-dipole interaction. PCP adsorption is dependent upon the nature of the clay surface and the exchangeable cations rather than the total surface area.

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Surface Reconstruction on Hydrogen Covered W(011) (수소가 흡착된 W(011) 표면의 재구성)

  • 김희봉;최원국;홍사용;황정남;정광호
    • Journal of the Korean Vacuum Society
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    • v.1 no.1
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    • pp.83-87
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    • 1992
  • Rencently, angle-resolved ultraviolet photoemission measurements of the Fermi surface contours for Mo(011) and W(011) are reported. The electron contour of W(011) is expanded upon hydrogen adsorption, which implies that the surface states consisting of electron pockets are shifted to higher binding energy. This phenomena can be explained by the band flattening. We explained here the reconstruction of W(011) surface induced by adsorption of hydrogen in terms of band flattening of surface states with a combination of S. E. Trullinger long range dipole-dipole interaction force and Kohn anomaly.

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A Study on the Energy Transfer of YAlO3:Tbx3+ using Decay Curves (YAlO3:Tbx3+에서 발광소멸 곡선을 이용한 에너지 전달에 관한 연구)

  • Kim, Gwang Chul;Choi, Jin Soo
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.1
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    • pp.13-17
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    • 2015
  • $YAlO_3:Tb{_x}^{3+}$ has been synthesized by a combustion process and the concentration x of Tb was varied from 0.001 and 0.05 mol% per mole of YAlO3. The energy transfer of $^5D_3{\rightarrow}^7F_6$(385nm) and $^5D_4{\rightarrow}^7F_5$(544nm) transitions on the $YAlO_3:Tb{_x}^{3+}$(x =0.001, 0.05) have been investigated by using decay curves. The energy transfer mechanism was explained by Inokuti and Hirayama model. The results of calculation and fitting showed that values of n are 6.11(x=0.01) and 6.13(x=0.005). These indicate that the energy transfer mechanism between $Tb^{3+}$ ions is dipole-dipole interaction.

Jet-Edge Interaction and Sound Radiation in Edgetones (쐐기소리에서 분류-쐐기의 상호작용과 소리의 방사)

  • ;Powell A.
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.3
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    • pp.584-590
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    • 1994
  • A theoretical model has been developed to analyze the jet-edge interaction and the sound radiation. The edge responding to the sinuous impinging jet is regarded as an array of dipoles and their strength is determined by the boundary condition on the edge surface. The surface pressure distribution and the edgeforce are estimated using these dipoles. Then the pressure amplitude and directivity of the sound field is obtained by summing the radiating sounds from the dipole sources. It is found that the effective source is located a little distance downstream from the edge tip. And the directivity of the sound radiation is cardioid pattern near the edge but dipole pattern far from the edge. The theoretical model is confirmed by comparing the theoretical prediction of the edgeforce and sound pressure level with available experimental data.

Finite Element Analysis of Laser-Generated Ultrasound for Characterizing Surface-Breaking Cracks

  • Jeong Hyun Jo
    • Journal of Mechanical Science and Technology
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    • v.19 no.5
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    • pp.1116-1122
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    • 2005
  • A finite element method was used to simulate the wave propagation of laser-generated ultrasound and its interaction with surface breaking cracks in an elastic material. Thermoelastic laser line source on the material surface was approximated as a shear dipole and loaded as nodal forces in the plane-strain finite element (FE) model. The shear dipole- FE model was tested for the generation of ultrasound on the surface with no defect. The model was found to generate the Rayleigh surface wave. The model was then extended to examine the interaction of laser generated ultrasound with surface-breaking cracks of various depths. The crack-scattered waves were monitored to size the crack depth. The proposed model clearly reproduced the experimentally observed features that can be used to characterize the presence of surface-breaking cracks.

Effect of local field on atomic systems I : Derivation of interaction hamiltonian in electric dipole systems (국소장이 원자계에 미치는 영향에 대한 이론 I : 전기 쌍극자계에서의 상호작용 해밀토니안의 유도)

  • 안성혁
    • Korean Journal of Optics and Photonics
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    • v.11 no.1
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    • pp.1-5
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    • 2000
  • We define the basic minimal coupling Hamiltonian of the atomic systems in the Coulomb guage and show that this Hamiltonian yields the correct equations of motion for the operators of interest. Using the unitary transformation and making the dipole approximation, we calculate the effect of polarization of the dipoles on the interaction Hamiltonian of the system. ystem.

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Analysis of the Phase Change Temperatures and the Latent Heat Characteristics of $H_2O$-NaCl Mixtures for the Cold thermal Energy Storage (냉축열을 위한 $H_2O$-NaCl 혼합물의 상변화 온도와 잠열 특성분석)

  • Song, H.K.;Ro, J.G.
    • Solar Energy
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    • v.19 no.2
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    • pp.57-65
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    • 1999
  • In this study $H_2O$-NaCl mixture was selected as a cold thermal storage material and its phase change temperature($liquid{\Leftrightarrow}solid$) was controlled with the molar concentration of NaCl. Ion dipole interaction mechanism and the fusion and crystallization structure of $H_2O$-NaCl were visualized with the low and high concentration of NaCl in the heating and cooling processes. In this study, the original cause of the appearance of two steps phase change period in heating and cooing processes were found by the visualization of the ion dipole interaction mechanism of $H_2O$-NaCl, and the theoretical equation of the phase change temperature variation in the NaCl high molar concentration was rearranged.

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Directional Radiation of Surface Plasmon Polaritons at Visible Wavelengths through a Nanohole Dimer Optical Antenna Milled in a Gold Film

  • Janipour, Mohsen;Hodjat-Kashani, Farrokh
    • Journal of the Optical Society of Korea
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    • v.18 no.6
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    • pp.799-808
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    • 2014
  • The mechanism of optical interaction of two nanoholes, milled in an opaque gold film, by means of surface plasmon polariton (SPP) propagation is investigated. The interaction depends on the polarization direction of the incident light when the nanohole pair is illuminated through uniform single antenna excitations. It is shown that by illuminating one of the nanoholes, under single antenna excitation, the other nanohole can be excited indirectly via propagated SPPs from the excited nanohole. In addition, it is found that the spectrum of electromagnetic power above the surface of the metallic film at an arbitrary point along the axis of the nanohole pair presents two resonant peaks. These peaks are due to the optical interaction between nanoholes, where the short- and long-wavelength peaks can be assigned to in-phase and antiphase interactions of magnetic dipoles relative to each nanohole, respectively. The magnetic coupled dipole approximation (MCDA) method confirms the simulation results.

Nano-Optical Investigation of Enhanced Field at Gold Nanosphere-Gold Plane Junctions

  • Ahn, Sung-Hyun;Park, Won-Hwa;Kim, Zee-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.28 no.12
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    • pp.2200-2202
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    • 2007
  • The local field distribution around gold nanosphere-gold plane junction has been studied using the finitedifference time-domain (FDTD) electrodynamics calculation procedure. We find that both the in-plane and out-of-plane polarized excitation produce enhanced field strong enough to explain the observed SERS activities of the junctions. Comparison with a simple dipole-image dipole model shows that the enhanced field primarily originates from the multipole-image multipole interaction, which indicates that the detailed fine-structures of the nanoparticles also play a significant role in the SERS activities as well.