• 제목/요약/키워드: Dip-coating process

검색결과 131건 처리시간 0.03초

In-Situ SEM Observation and DIC Strain Analysis for Deformation and Cracking of Hot-Dip ZnMgAl Alloy Coating

  • Naoki Takata;Hiroki Yokoi;Dasom Kim;Asuka Suzuki;Makoto Kobashi
    • Corrosion Science and Technology
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    • 제23권2호
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    • pp.113-120
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    • 2024
  • An attempt was made to apply digital image correlation (DIC) strain analysis to in-situ scanning electron microscopy (SEM) observations of bending deformation to quantify local strain distribution inside a ZnMgAl-alloy coating in deformation. Interstitial-free steel sheets were hot-dipped in a Zn-3Mg-6Al (mass%) alloy melt at 400 ℃ for 2 s. The specimens were deformed using a miniature-sized 4-point bending test machine inside the SEM chamber. The observed in situ SEM images were used for DIC strain analysis. The hot-dip ZnMgAl-alloy coating exhibited a solidification microstructure composed of a three-phase eutectic of fine Al (fcc), Zn (hcp), and Zn2Mg phases surrounding the primary solidified Al phases. The relatively coarsened Zn2Mg phases were locally observed inside the ZnMgAl-alloy coating. The DIC strain analysis revealed that the strain was localized in the primary solidified Al phases and fine eutectic microstructure around the Zn2Mg phase. The results indicated high deformability of the multi-phase microstructure of the ZnMgAl-alloy coating.

코팅 방법에 따른 SnO2/Ti 전극의 제조 및 전기화학적 특성 (Preparation and Electrochemical Characterization of SnO2/Ti Electrode by Coating Method)

  • 김한주;손원근;홍지숙;김태일;박수길
    • 전기화학회지
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    • 제9권2호
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    • pp.59-63
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    • 2006
  • 전해코팅 법과 dip-coating 법을 이용해 산화주석(IV)을 티타늄 지지체에 코팅하여, 코팅 방법에 따른 코팅 전극의 물성과 전기화학적 특성에 대해여 연구하였다. HCl 로 전극 에칭 후, nitrate 용액에 $SnCl_2{\cdot}2H_2O$을 용해시켜 pulse technique를 이용하여 전해코팅 하였으며, dip-coating 법 또한 $SnCl_2{\cdot}2H_2O$를 사용하여 1:1V% HCl 용액에 용해시켜 코팅 소결 후 산화주석(IV)코팅 전극을 제작하였다. 두 가지 코팅 방법을 통해 제작된 산화주석(IV)코팅 전극은 전극의 물성을 비교하기 위해 x-ray diffraction (XRD), scanning election microscopy (SEM)를 관찰해보았고, 전기화학적 특성을 평가하기 위해 cyclic voltammetry (CV)를 측정하여 전위창을 비교해 보았다.

플라즈마 표면 개질과 CNT 함침공정을 통한 고전도성의 재생PET사 전자섬유 (Manufacture of Recycled PET E-Textile by Plasma Surface Modification and CNT Dip-Coating)

  • 장준혁;김상운;김주용
    • 감성과학
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    • 제26권1호
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    • pp.79-86
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    • 2023
  • 본 연구의 목적은 PET를 재활용하여 만든 물질재생 PET사를 함침공정을 통해 고전도성의 E-textile로 제작하는 것이다. 소수성의 성질을 가지고 있는 PET사는 virgin과 recycled 모두 함침공정을 통해 전자섬유로 제작되었을 때에 높은 전도성을 부여하기 힘들다는 특징이 있다. 함침공정의 효율성 향상을 위해 FEMTO SCIENCE사의 Covance-2mprfq 모델을 사용하여 재생 PET사로 이루어진 시료를 50w 5분, 10분간 플라즈마로 표면 개질하였다. 이 후 SWCNT 분산액(.1wt%, cobon 사)에 5분간 시료를 담근 후 패딩기(Padder, DAELIM lab)를 통해 시료 안쪽으로 용액이 잘 스며들도록 Dip-coating 진행하였다. 공정이 완료된 후 저항측정을 양끝점에서 멀티미터를 통해 측정하고 좀 더 넓은 전극을 통해 정밀하게 다시 측정하였다. 고찰한 결과 플라즈마 표면 개질을 통해 함침공정을 통한 고전도성 부여가 가능해졌음을 확인할 수 있었다. 10분간 표면 개질한 경우 저항이 최대 2.880배 감소하였다. 본 연구결과를 기반으로 스마트 웨어러블 분야에서 활용되는 E-textile 또한 recycle 소재로 제작함으로써 석유자원을 절약하고 탄소배출량을 감소시킬 수 있는 스마트 웨어러블 제품을 개발하고자 한다.

진공 슬러리 담금 코팅 공정에 의한 고체 산화물 연료전지용 박막 전해질막 제조에 관한 연구 (Fabrication Of Thin Electrolyte Layer For Solid Oxide Fuel Cell by Vacuum Slurry Dip-coating Process)

  • 손희정;임탁형;이승복;신동열;송락현;김성현
    • 한국수소및신에너지학회논문집
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    • 제17권2호
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    • pp.204-211
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    • 2006
  • The electrolyte in the solid oxide fuel cell must be dense enough to avoid gas leakage and thin enough to reduce the ohmic resistance. In order to manufacture the thin and dense electrolyte layer, 8 mol% $Y_2O_3$ stabilized-$ZrO_2$ (8YSZ) electrolyte layers were coated on the porous tubular substrate by the novel vacuum slurry dip-coating process. The effects of the slurry concentration, presintering temperature, and vacuum pressure on the thickness and the gas permeability of the coated electrolyte layers have been examined in the vacuum slurry coating process. The vacuum-coated electrolyte layers showed very low gas permeabilities and had thin thicknesses. The single cell with the vacuum-coated electrolyte layer indicated a good performance of $495\;mW/cm^2$, 0.7 V at $700^{\circ}C$. The experimental results show that the vacuum dip-coating process is an effective method to fabricate dense thin film on the porous tubular substrate.

염료감응형 태양전지 투명전도성 막의 표면처리를 통한 계면 접촉 향상 및 재결합 방지 연구 (A Study on the Improvement of the Interface Contact and the Prevention of the Charge Recombination by the Surface Treatment of Transparent Conductive Oxide in Dye-sensitized Solar Cell)

  • 서현웅;홍지태;손민규;김진경;신인영;김희제
    • 전기학회논문지
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    • 제58권11호
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    • pp.2214-2218
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    • 2009
  • Dye-sensitized solar cell (DSC) has been considered as a possible alternative to current silicon based p-n junction photovoltaic devices due to its advantages of high efficiency, simple fabrication process and low production cost. Numerous researches for high efficient DSC in the various fields are under way even now. Among them, the compact layer, which prevents the back electron transfer between transparent conductive oxides and the redox electrolyte, is fabricated by various methods such as a ZnO dip-coating, $TiCl_4$ dip-coating, and Ti sputtering. In this study, we tried to fabricate the $TiO_2$ compact layer by the spin-coating method using aqueous $TiCl_4$ solution. The effect of the spin-coating method was checked as compared with conventional dip-coating method. As a result, DSC with a spin-coated compact layer had 33.4% and 6% better efficiency than standard DSC and DSC with a dip-coated compact layer.

Hydrogen Permeation of SiC-CeO2 Composite Membrane by Dip-coating Process

  • Park, Jihye;Jung, Miewon
    • 한국세라믹학회지
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    • 제50권6호
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    • pp.485-488
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    • 2013
  • A SiC-$CeO_2$ composite membrane was successfully fabricated using an ally-hydridopolycarbosilane (AHPCS) binder and treated by dip-coating at 60 times with a $CeO_2$ sol solution. The dip-coated SiC membrane was calcined at 773 K and then sintered at 1173 K under an air atmosphere. The coated membrane was characterized by X-ray diffraction (XRD), field-emission scanning electron microscopy (FE-SEM) and a BET surface analysis. The difference in permeation performance between $H_2$ and CO gases was measured by varying the temperature. The permeation flux of $H_2$ on the SiC membrane with layered $CeO_2$ was obtained as $8.45{\times}10^{-6}\;mol/m^2sPa$ at room temperature. The CO permeation flux was $2.64{\times}10^{-6}\;mol/m^2sPa$ at room temperature. The reaction enthalpy (${\Delta}H^{\circ}$) for the hydrogen permeation process was calculated as -7.82 J/mol by Arrhenius plots.

Investigation of Streaky Mark Defect on Hot Dip Galvannealed IF Steel

  • Xinyan, Jin;Li, Wang;Xin, Liu
    • Corrosion Science and Technology
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    • 제9권3호
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    • pp.109-115
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    • 2010
  • Interstitial-free (IF) steels are widely used for car body material. However, a few types of streaky mark defect are commonly found on hot dip galvannealed (GA) IF steel sheets. In the present study, both the phase structure of a streaky mark defect and the microstructure of the substrate just below it were characterized by optical microscopy (OM) and scanning electron microscopy (SEM). It was found that the bright streaky mark area was composed of ${\delta}$ phase while the dark normal area was full of craters. More than half of the grains at the uppermost surface of the substrate just below the streaky mark defect are unrecrystallized grains which could result from lower finish rolling temperature during hot rolling and be kept stable during the annealing process, while almost all the grains in the normal area are equiaxed grains. In order to confirm the effect of the unrecrystallized grains on the coating morphology, hot dip galvannealing simulation experiments were carried out in IWATANI HDPS. It is proved that the unrecrystallized grains accelerate the Fe-Zn reaction rate during galvannealing and result in a flatter coating surface and an even coating thickness. Finally, a formation mechanism of the streaky mark defect on the hot dip galvannealed IF steel sheet was discussed.

연속 아연 도금 코-팅 두께에 관한 수치 해석적 연구 (A Numerical Analysis on the Coating Thickness in Continuous Hot-Dip Galvanizing)

  • 이동원;신승영;김병지;권영두;권순범
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2955-2960
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    • 2007
  • To control the coating thickness of zinc in the process of continuous hot-dip galvanizing, it is known from early day that the gas wiping through an air knife system is the most effective because of the obtainable of uniformity of coating thickness, possibility of thin coating, working ability in high speed and simplicity of control. But, the gas wiping using in the galvanizing process brings about a problem of splashing from the strip edge for a certain high speed of coating. And, it is known that the problem of splashing is caused mainly by the existence of separation bubble at the neighbor of the strip surface. In theses connections, in the present study, we proposed two kinds of air knife systems having the same expansion rate of nozzle, and the jet structures and coating thicknesses from a conventional and new proposed nozzles are compared. In numerical analysis, the governing equations consisted of two-dimensional time dependent Navier-Stokes equations, standard ${\kappa}-{\varepsilon}$ turbulence model to solve turbulence stress and so on are employed. As a result, it is found that it had better to use the constant rate nozzle from the point view of the energy saving to obtain the same coating thickness. Also, to reduce the size of separation bubble and to enhance the cutting ability at the strip, it is recommendable to use an air knife having the constant expansion rate nozzle.

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연속 아연 도금 두께에 관한 수치 해석적 연구 (A NUMERICAL STUDY ON THE COATING THICKNESS IN CONTINUOUS HOT-DIP GALVANIZING)

  • 이동원;신승영;조태석;권영두;권순범
    • 한국전산유체공학회지
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    • 제14권1호
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    • pp.1-8
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    • 2009
  • To control the coating thickness of zinc in the process of continuous hot-dip galvanizing, it is known from early days that the gas wiping through an air knife system is the most effective because of the obtainable of uniformity of coating thickness, possibility of thin coating, working ability in high speed and simplicity of control. But, the gas wiping using in the galvanizing process brings about a problem of splashing from the strip edge for a certain high speed of coating. Also, it is known that the problem of splashing directly depends upon the galvanizing speed and nozzle stagnation pressure. In theses connections, in the present study, we proposed two kinds of air knife systems having the same expansion rate of nozzle, and the jet structures and coating thicknesses from a conventional and new proposed nozzles are compared. In numerical analysis, the governing equations consisted of two-dimensional time dependent Navier-Stokes equations, standard k-e turbulence model to solve turbulence stress and so on are employed. As a result, it is found that it had better to use the constant rate nozzle from the point view of the energy saving to obtain the same coating thickness. Also, to enhance the cutting ability at the strip, it is advisable to use an air knife with the constant expansion rate nozzle.