DOI QR코드

DOI QR Code

Preparation and Electrochemical Characterization of SnO2/Ti Electrode by Coating Method

코팅 방법에 따른 SnO2/Ti 전극의 제조 및 전기화학적 특성

  • Kim Han-Joo (Dept. of Industrial Chemical Engineering, Chungbuk Nat'l Univ.) ;
  • Son Won-Keun (Research Center of Advanced Material, Chungnam Nat'l Univ.) ;
  • Hong Ji-Sook (Chemical Engineering Process Center, KRICT) ;
  • Kim Tae-Il (Siontech. Co. Ltd.) ;
  • Park Soo-Gil (Dept. of Industrial Chemical Engineering, Chungbuk Nat'l Univ.)
  • Published : 2006.05.01

Abstract

The study is coated tin(IV) oxide coated on the titanium substrate electrodes by electrodepositon and dip-coating method and studied about that physical and electrochemical characterization by coating methods. After titanium substrate is etched in HCl, electrodespotion is coated $SnCl_2{\cdot}2H_2O$ in nitrate solution by pulse technique, dip-coating method is also used $SnCl_2{\cdot}2H_2O$ in 1;1V% HCl and coated by dipping and annealing process. tin(IV) oxide coated on titanium substrate electrodes by two coating methods are studied x-ray diffraction (XRD), scanning electron microscopy (SEM) to compare physical characterization of electrode and potential window by cyclic voltammetry (CV) to observe electrochemical characterization.

전해코팅 법과 dip-coating 법을 이용해 산화주석(IV)을 티타늄 지지체에 코팅하여, 코팅 방법에 따른 코팅 전극의 물성과 전기화학적 특성에 대해여 연구하였다. HCl 로 전극 에칭 후, nitrate 용액에 $SnCl_2{\cdot}2H_2O$을 용해시켜 pulse technique를 이용하여 전해코팅 하였으며, dip-coating 법 또한 $SnCl_2{\cdot}2H_2O$를 사용하여 1:1V% HCl 용액에 용해시켜 코팅 소결 후 산화주석(IV)코팅 전극을 제작하였다. 두 가지 코팅 방법을 통해 제작된 산화주석(IV)코팅 전극은 전극의 물성을 비교하기 위해 x-ray diffraction (XRD), scanning election microscopy (SEM)를 관찰해보았고, 전기화학적 특성을 평가하기 위해 cyclic voltammetry (CV)를 측정하여 전위창을 비교해 보았다.

Keywords

References

  1. A. Fujishima, K. Hashimoto, and T. Watanabe, '$TiO_2$ photocatalysis fundamentals and applications' BKC, Inc., 128 (1999)
  2. M. Zheng, G. Li, X. Zhang, S. Huang, Y. Lei, and L. Zhang, Chem. Master., 13,3859 (2001) https://doi.org/10.1021/cm002007l
  3. T. A. F. Lassali and L. O. S. Bulhoes, 'Surface characterization of thermally prepared, Ti-supported, Ir-based electrocatalysts containing Ti and Sn' J. of the Electrochemical Society, 144 (1997)
  4. S. T. Chang, I. C. Leu, and M. H. Hon, 'Novel methods for preparing nanocrystalline $SnO_2$ and $Sn/SnO_2$ composite by electrodeposition' J. of Alloys and Compounds, 403, 336 (2005)
  5. K. W. Kim, 'Study on the electro-activity and non-stochiometry of Ru-based mixed oxide electrode' Electrochimica Acta, 46, 915 (2001) https://doi.org/10.1016/S0013-4686(00)00674-5
  6. S. S. Park and J. D. Mackenzie, 'Sol-gel-derived tin oxide thin films' Thin solid films, 258, 268 (1995) https://doi.org/10.1016/0040-6090(94)06404-0
  7. Fujishima, Einaga, 'Diamond electrochemistry' BKC, Inc. 221 (2005)
  8. M. E. Makgae and A. M. Crouch 'Preparation and surface characterization of $Ti/SnO_2-RuO_2-IrO_2$ thin films as electrode material for the oxidation of phenol' Materials Chemistry and Physics, 92, 561 (2005)
  9. A. Chandra Bose, P. Thangadurai, and S, Ramasamy, 'Grain size dependent electrical studieds on nanocrystalline $SnO_2$' Materials Chemistry and Physics, (2005)