• Title/Summary/Keyword: Dip Coating

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NO and $SO_2$ Removal by Dielectric Barrier Discharge-Photocatalysts Hybrid Process (유전체 장벽 방전-광촉매 복합공정에 의한 NO와 $SO_2$ 제거)

  • Kim, Dong-Joo;Nasonova, Anna;Kim, Kyo-Seon
    • Clean Technology
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    • v.13 no.2
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    • pp.115-121
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    • 2007
  • In this study, we analyzed experimently the NO and $SO_2$ removal by the dielectric barrier discharge-photocatalysts hybrid process. The glass spheres were used as a dielectric material for dielectric barrier discharge and the $TiO_2$ photocatalysts were coated onto those spheres by the dip-coating method. The $TiO_2$ particles were coated in the sponge-shape, which has the larger surface area. As the voltage applied to the plasma reactor, the pulse frequency of applied voltage, or the residence time increases, the NO and $SO_2$ removal efficiencies increase. The increase in the supplied concentrations of NO and $SO_2$ leads to the higher energy for NO and $SO_2$ removal and the NO and $SO_2$ removal efficiencies decrease. These experimental results can be used as a basis to design the dielectric barrier discharge-photocatalysts hybrid process to remove NO and $SO_2$.

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A Study on Tensile Properties of Laminated Nanocomposite Fabricated by Selective Dip-Coating of Carbon Nanotubes (탄소나노튜브의 선택적 딥코팅을 이용해 제작된 적층 복합재료의 인장 물성에 대한 연구)

  • Kang Tae-June;Kim Dong-Iel;Huh Yong-Hak;Kim Yong-Hyup
    • Composites Research
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    • v.19 no.3
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    • pp.23-28
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    • 2006
  • Carbon nanotubes reinforced copper matrix laminated nanocomposites were developed and the mechanical properties were evaluated by using micro-tensile testing system. Sandwich-type laminated structure constituted with carbon nanotube layers as a reinforcement and electroplated copper matrix were fabricated by a new processing approach based on selective dip-coating of carbon nanotubes. The mechanical properties of nanocomposites were improved due to an enhanced load sharing capacity of carbon nanotubes homogeneously distributed within the in-plane direction, as well as a bridging effect of carbon nanotubes along the out-of-plane direction between the upper and lower matrices. The universality of the layering approach is applicable to a wide range of functional materials, and here we demonstrate its potential use in reinforcing composite materials.

Chromate-free Hybrid Coating for Corrosion Protection of Electrogalvanized Steel Sheets

  • Jo, Du-Hwan;Kwon, Moonjae;Kim, Jong-Sang
    • Corrosion Science and Technology
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    • v.11 no.1
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    • pp.15-19
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    • 2012
  • Both electrogalvanized and hot-dip galvanized steel sheets have been finally produced via organic-inorganic surface coating process on the zinc surface to enhance corrosion resistance and afford additional functional properties. Recently, POSCO has been developed a variety of chromate-free coated steels that are widely used in household, construction and automotive applications. New organic-inorganic hybrid coating solutions as chromate alternatives are comprised of surface modified silicate with silane coupling agent and inorganic corrosion inhibitors as an aqueous formulation. In this paper we have prepared new type of hybrid coatings and evaluated quality performances such as corrosion resistance, spot weldability, thermal tolerance, and paint adhesion property etc. The electrogalvanized steels with these coating solutions exhibit good anti-corrosion property compared to those of chromate coated steels. Detailed components composition of coating solutions and experimental results suggest that strong binding between organic-inorganic hybrid coating layer and zinc surface plays a key role in the advanced quality performances.

Development of Continuous Galvanization-compatible Martensitic Steel

  • Gong, Y.F.;Song, T.J.;Kim, Han S.;Kwak, J.H.;De Cooman, B.C.
    • Corrosion Science and Technology
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    • v.11 no.1
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    • pp.1-8
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    • 2012
  • The development of martensitic grades which can be processed in continuous galvanizing lines requires the reduction of the oxides formed on the steel during the hot dip process. This reduction mechanism was investigated in detail by means of High Resolution Transmission Electron Microscopy (HR-TEM) of cross-sectional samples. Annealing of a martensitic steel in a 10% $H_2+N_2$ atmosphere with the dew point of $-35^{\circ}C$ resulted in the formation of a thin $_{C-X}MnO.SiO_{2}$ (x>1) oxide film and amorphous $_{a-X}MnO.SiO_{2}$ oxide particles on the surface. During the hot dip galvanizing in Zn-0.13%Al, the thin $_{C-X}MnO.SiO_{2}$ (x>1) oxide film was reduced by the Al. The $_{a-X}MnO.SiO_{2}$ (x<0.9) and $a-SiO_{2}$ oxides however remained embedded in the Zn coating close to the steel/coating interface. No $Fe_{2}Al_{5-X}Zn_{X}$ inhibition layer formation was observed. During hot dip galvanizing in Zn-0.20%Al, the $_{C-X}MnO.SiO_{2}$ (x>1) oxide film was also reduced and the amorphous $_{a-X}MnO.SiO_{2}$ and $a-SiO_{2}$ particles were embedded in the $Fe_{2}Al_{5-X}Zn_{X}$ inhibition layer formed at the steel/coating interface during hot dipping. The results clearly show that Al in the liquid Zn bath can reduce the crystalline $_{C-X}MnO.SiO_{2}$ (x>1) oxides but not the amorphous $_{a-X}MnO.SiO_{2}$ (x<0.9) and $a-SiO_{2}$ oxides. These oxides remain embedded in the Zn layer or in the inhibition layer, making it possible to apply a Zn or Zn-alloy coating on martensitic steel by hot dipping. The hot dipping process was also found to deteriorate the mechanical properties, independently of the Zn bath composition.

Optimization of anode and electrolyte microstructure for Solid Oxide Fuel Cells (고체산화물 연료전지 연료극 및 전해질 미세구조 최적화)

  • Noh, Jong Hyeok;Myung, Jae-ha
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.525-530
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    • 2019
  • The performance and stability of solid oxide fuel cells (SOFCs) depend on the microstructure of the electrode and electrolyte. In anode, porosity and pore distribution affect the active site and fuel gas transfer. In an electrolyte, density and thickness determine the ohmic resistance. To optimizing these conditions, using costly method cannot be a suitable research plan for aiming at commercialization. To solve these drawbacks, we made high performance unit cells with low cost and highly efficient ceramic processes. We selected the NiO-YSZ cermet that is a commercial anode material and used facile methods like die pressing and dip coating process. The porosity of anode was controlled by the amount of carbon black (CB) pore former from 10 wt% to 20 wt% and final sintering temperature from $1350^{\circ}C$ to $1450^{\circ}C$. To achieve a dense thin film electrolyte, the thickness and microstructure of electrolyte were controlled by changing the YSZ loading (vol%) of the slurry from 1 vol% to 5 vol. From results, we achieved the 40% porosity that is well known as an optimum value in Ni-YSZ anode, by adding 15wt% of CB and sintering at $1350^{\circ}C$. YSZ electrolyte thickness was controllable from $2{\mu}m$ to $28{\mu}m$ and dense microstructure is formed at 3vol% of YSZ loading via dip coating process. Finally, a unit cell composed of Ni-YSZ anode with 40% porosity, YSZ electrolyte with a $22{\mu}m$ thickness and LSM-YSZ cathode had a maximum power density of $1.426Wcm^{-2}$ at $800^{\circ}C$.

Enhancement of Penetration by Using Mechenical Micro Needle in Textile Strain Sensor (텍스타일 스트레인 센서에 마이크로 니들을 이용한 전도성입자 침투력 향상)

  • Hayeong Yun;Wonjin Kim;Jooyong Kim
    • Science of Emotion and Sensibility
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    • v.25 no.4
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    • pp.45-52
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    • 2022
  • Recently, interest in and demand for sensors that recognize physical activity and their products are increasing. In particular, the development of wearable materials that are flexible, stretchable, and able to detect the user's biological signals is drawing attention. In this study, an experiment was conducted to improve the dip-coating efficiency of a single-walled carbon nanotube dispersion solution after fine holes were made in a hydrophobic material with a micro needle. In this study, dip-coating was performed with a material that was not penetrated, and comparative analysis was performed. The electrical conductivity of the sensor was measured when the sensor was stretched using a strain universal testing machine (Dacell Co. Ltd., Seoul, Korea) and a multimeter (Keysight Technologies, Santa Rosa, CA, USA) was used to measure resistance. It was found that the electrical conductivity of a sensor that was subjected to needling was at least 16 times better than that of a sensor that was not. In addition, the gauge factor was excellent, relative to the initial resistance of the sensor, so good performance as a sensor could be confirmed. Here, the dip-coating efficiency of hydrophobic materials, which have superior physical properties to hydrophilic materials but are not suitable due to their high surface tension, can be adopted to more effectively detect body movements and manufacture sensors with excellent durability and usability.

Characterization of a Functional Coating Film Synthesized on the Ceramic Substrate for Electrical Insulator Application according to Coating Method

  • Shan, Bowen;Kang, Hyunil;Choi, Wonseok;Kim, Jung Hyun
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.3
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    • pp.148-150
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    • 2017
  • For the improvement of the anti-fouling features of porcelain electrical insulators, in this study, the surface of an insulator was coated with a functional material to expand the insulator's self-cleanness. The anti-fouling and mechanical features of the functional film coating of ceramic substrates made from components like an electrical insulator were analyzed. The coating methods that were used were spray coating, dip coating, and fabric coating. Following the coating, the contact angle of the coated surface was measured, revealing that the spray coating method offered the lowest angle ($13.7^{\circ}$) and a strong hydrophilic feature. The anti-fouling analysis showed that the anti-fouling features improved as the contact angle decreased. The mechanical properties - hardness and adhesion - were both excellent at 9H and 5B, respectively, regardless of the coating method that was used.

A Study on the Preparation of CdS Doped $SiO_2$ Glass Coating Films by Sol-Gel Method (졸-겔법에 의한 CdS 분산 $SiO_2$ Glass 코팅막의 제조에 관한 연구)

  • 박한수;김경문;문종수
    • Journal of the Korean Ceramic Society
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    • v.30 no.11
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    • pp.897-904
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    • 1993
  • CdS doped SiO2 glass coating films which are good candidates for the nonlinear optical materials were prepared by the Sol-Gel method. TEOS, C2H5OH, H2O and HCl were used as starting materials to obtain SiO2 matrix solutions. Then Cd(NO3)2.2H2O and CS(NH2)2 were dissolved into the SiO2 matrix solutions. Coating was performed several times in order to increase the thickness of coated film by the dip-coating method. Then heat treatments were carried out to control the size of CdS microcrystals doped in SiO2 glass matrix with respect to temperatures and times. CdS-doped SiO2 transparent coating films were successfully obtained. CdS crystals were changed from cubic to hexagonal type about $600^{\circ}C$.

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Selective Wetting Technique for Fabrication of Color Filters

  • Hong, Jong-Ho;Li, Hongmei;Na, Yu-Jin;Lee, Sin-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.1386-1388
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    • 2009
  • We report on a new method of fabricating color filters based on selective wetting of color inks. The reversible formation of a hydrophobic layer provides sequential generation and protection of successive color filter patterns through a simple coating process. The transmittance and geometrical properties of the fabricated color filter were described.

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Fortification of Rice with Soy Hydrosylate Containing CHP (Cyclo Histidine-Proline) (CHP(Cyclo His-Pro) 함유 대두가수분해물을 이용한 코팅 쌀의 제조)

  • Lee, Hyun Jung;Park, Hyein;Park, Yooheon;Suh, Hyung Joo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.3
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    • pp.415-420
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    • 2013
  • A method for coating rice with a novel substance, SHC [soybean hydrolysate with Cyclo Histidine-Proline (CHP)], was developed to produce functional rice for food production. The dip coating and spray coating method was tested to reduce the loss of functionality during the manufacturing of enriched rice. The dip coating method showed a very low absorption rate ($0.079min^{-1}$) of the functional substance compared to control ($0.150min^{-1}$), while the spray-coating method with protective coating materials [a methyl cellulose solution (l%, w/v) containing 5% (w/v) of the SHC] showed relatively adequate absorption characteristics. A light yellowish stain was observed in the rice samples processed by the spray-coating method (b value; surface1 0.69, flour 4.91) compared to raw rice (b value; surface 9.67, flour 4.86). The microscopic appearance of whole kernels and longitudinal sections revealed that cracks formed in all rice samples, regardless of the coating method. In conclusion, spray coating is a potential method for producing SHC-fortified rice with excellent physical characteristics.