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A Study on Tensile Properties of Laminated Nanocomposite Fabricated by Selective Dip-Coating of Carbon Nanotubes

탄소나노튜브의 선택적 딥코팅을 이용해 제작된 적층 복합재료의 인장 물성에 대한 연구

  • 강태준 (서울대학교 기계항공공학부) ;
  • 김동일 (한국표준과학연구원 환경안전계측센터 강도평가그룹) ;
  • 허용학 (한국표준과학연구원 환경안전계측센터 강도평가그룹) ;
  • 김용협 (서울대학교 기계항공공학부 항공우주신기술 연구소)
  • Published : 2006.06.01

Abstract

Carbon nanotubes reinforced copper matrix laminated nanocomposites were developed and the mechanical properties were evaluated by using micro-tensile testing system. Sandwich-type laminated structure constituted with carbon nanotube layers as a reinforcement and electroplated copper matrix were fabricated by a new processing approach based on selective dip-coating of carbon nanotubes. The mechanical properties of nanocomposites were improved due to an enhanced load sharing capacity of carbon nanotubes homogeneously distributed within the in-plane direction, as well as a bridging effect of carbon nanotubes along the out-of-plane direction between the upper and lower matrices. The universality of the layering approach is applicable to a wide range of functional materials, and here we demonstrate its potential use in reinforcing composite materials.

탄소나노튜브로 강화된 구리기지 적층 나노 복합재료를 제작하였고, 마이크로 인장 시험기를 이용하여 기계적 물성을 평가하였다. 탄소나노튜브 층이 강화제로 사용된 샌드위치 형태의 적층 구조는 탄소나노튜브의 선택적인 딥코팅 방법과 전해도금 방법을 이용하여 제작되었다. 본 연구에서 정립한 공정을 사용하여 제작된 나노 복합재료는 구리 기지만을 사용한 재료에 비해 기계적 물성이 향상되었다. 이는 평면내 방향으로 균일하게 분산된 탄소나노튜브에 의해 하중 분산 용량이 증가되었기 때문이며, 두께 방향으로 적층된 구리 기지를 탄소나노튜브 층이 상호 지지하여 인장물성이 강화됨을 확인하였다. 기능적 재료의 제작에 있어 적층 구조는 다양한 분야에 적용될 수 있으며, 본 연구에서는 입자강화복합재료 강화제의 적용 가능성을 확인하였다.

Keywords

References

  1. Ajayan P. M., 'Nanotubes from carbon,' Chemical Reviews, Vol. 99, No.7, 1999, pp. 1787-1800 https://doi.org/10.1021/cr970102g
  2. Peigney A., 'Tougher ceramics with nanotubes,' Nature Materials. Vol. 2, 2003, pp. 15-16 https://doi.org/10.1038/nmat794
  3. Zhan G.-D., Mukherjee A. K., 'Carbon Nanotube Reinforced Alumina-Based Ceramics with Novel Mechanical, Electrical, and Thermal Properties,' International Journal of Applied Ceramic Technology, Vol. 1, No.2, 2004, pp. 161-171 https://doi.org/10.1111/j.1744-7402.2004.tb00166.x
  4. Wang X., Padture N. P., Tanaka H., 'Contact-damageresistant ceramic/single-wall carbon nanotubes and ceramic/ graphite composites,' Nature materials, Vol. 3, 2004, pp. 539-544 https://doi.org/10.1038/nmat1161
  5. Gao X., Liu L., Guo Q., Shi J., Zhai G., 'Fabrication and mechanical/conductive properties of multi-walled carbon nanotube (MWNT) reinforced carbon matrix composites,' Materials Letters, Vol. 59, No. 24-25, 2005, pp. 3062-3065
  6. Cha S. I., Kim K. T., Arshad S. N., Mo C. B., Hong S. H., 'Extraordinary Strengthening Effect of Carbon Nanotubes in Metal-Matrix Nanocomposites Processed by Molecular-Level Mixing,' Advanced Materials, Vol. 17, No. 11, 2005, pp. 1377-1381 https://doi.org/10.1002/adma.200401933
  7. Jiang L., Gao L. and Sun J., 'Production of aqueous colloidal dispersions of carbon nanotubes,' Journal of Colloid and Interface Science, Vol. 260, 2003, pp. 89-94 https://doi.org/10.1016/S0021-9797(02)00176-5
  8. Chen X. H., Chen C S., Xiao H. N., Cheng F. Q., Zhang G., Yi G. J., 'Corrosion behavior of carbon nanotubes-Ni composite coating,' Surface and Coatings Technology, Vol. 191, 2005, pp. 351-356 https://doi.org/10.1016/j.surfcoat.2004.04.055
  9. Mamedov A. A., Kotov N. A., Prato M., GuIdi D. M., Wicksted J. P., Hirsch A., 'Molecular design of strong single-wall carbon nanotube/polyelectrolyte multilayer composites,' Nature Materials, Vol. 1, 2002, pp.190-194 https://doi.org/10.1038/nmat747
  10. Mayoral R., Requena J., Moya J. S., Lopez C, Cintas A., Miguez A., Meseguer F., Vasquez L., Holgado M., Blanco M., '3D Long-range ordering in ein SiO2 submicrometer-sphere sintered superstructure,' Advanced Materials, Vol. 9, No.3, 1997, pp. 257-260 https://doi.org/10.1002/adma.19970090318
  11. Gu Z., Fujishima A., Sato O., 'Fabrication of High-Quality Opal Films with Controllable Thickness,' Chemistry of Materials, Vol. 14, 2002, pp. 760-765 https://doi.org/10.1021/cm0108435
  12. Kumacheva E., Golding R. K., Allard M., Sargent E. H., 'Colloid Crystal Growth on Mesoscopically Patterned Surfaces: Effect of Confinement,' Advanced Materials, Vol. 14, No.3, 2002, pp. 221-224 https://doi.org/10.1002/1521-4095(20020205)14:3<221::AID-ADMA221>3.0.CO;2-V
  13. Liu J., Casavant M. J., Cox M., Walters D. A., Boul P., Lu W., Rimberg A. J., Smith K. A., Colbert D. T., Smalley R. E., 'Controlled deposition of individual single-walled carbon nanotubes on chemically functionalized templates,' Chemical Physics Letters, Vol. 303, 1999, pp. 125-129 https://doi.org/10.1016/S0009-2614(99)00209-2
  14. Landau L., Levich B., 'Dragging of a liquid by a moving plate,' Acta Physicochim, URSS 17. 1942, pp. 42-54