• Title/Summary/Keyword: Diluents

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Effects of Various Diluents Included in the Resin Matrices on the Characteristics of the Dental Composites (레진 기질에 포함된 희석제들이 치과용 복합 재료의 특성 변화에 미치는 영향)

  • Yoo, Sun-Hwa;Kim, Chang-Keun
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.153-157
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    • 2009
  • The resin matrix in the dental composite is generally composed of 2,2-bis[4-(2-hydroxy-3-methacryloyloxy propoxy) phenyl] propane (Bis-GMA) as a base resin and triethylene glycol dimethacrylate (TEGDMA) as a diluent for the reduction of viscosity. The applications of dental composite were often limited in dentistry due to the relatively large amounts of volumetric shrinkage during polymerization and water uptake caused by the addition of TEGDMA to the resin matrix. In this study, in order to solve problems stemmed from the TEGDMA by reducing amount of diluent added to resin matrix, diethylene glycol dimethacrylate (DEGDMA) and ethylene glycol dimethacrylate (EGDMA) were explored as new diluents. A decrease in the volumetric shrinkage and an increase in the mechanical strength were observed by replacing TEGDMA in the dental composite to DEGDMA (or EGDMA). Reduction in the mechanical strength of the dental composite containing DEGDMA (or EGDMA), was not serious in comparison with that of the dental composite containing TEGDMA after water uptake.

Fabrication of Organic Solvent Resistant Polyketone Hollow Fiber Membranes (유기용매 저항성 Polyketone 중공사 분리막의 제조)

  • Park, Yeji;Jang, Wongi;Choi, Jinwon;Woo, Yunha;Hou, Jian;Jeon, Sungil;Byun, Hongsik
    • Membrane Journal
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    • v.31 no.5
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    • pp.363-370
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    • 2021
  • Organic solvent resistant hollow fiber membranes were fabricated via a thermally induced phase separation (TIPS) method using Polyketone polymer, a material with excellent resistance to organic solvents. The PEG300, DMSO2 and Glycerine called the "green solvents" were used as diluents for TIPS method. The spherulite structure was formed with DMSO2 by S-L phase separation behavior whereas the bicontinuous structures were formed with PEG300 and Glycerine, respectively. The morphology of the PK hollow fiber membranes was investigated using SEM. The pure water permeability and the durability test were conducted to understand the permeation properties of PK hollow fiber membranes. The tensile strength test was conducted for the property of mechanical strength. In this study, the fabrication of PK hollow fiber membranes with various diluents was discussed to understand the correlation between diluent and polymer in detail.

Effect of diluent variation on cryopreservation of large yellow croaker Larimichthys crocea

  • Lim, Han Kyu;Irfan, Zidni;Lee, Hyo Bin;Song, Ji Hoon;Lee, Yun Ho
    • Fisheries and Aquatic Sciences
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    • v.24 no.2
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    • pp.63-77
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    • 2021
  • The aim of this research was to investigate different factors, including cryoprotective agents (CPAs), diluents, dilution ratios, equilibrium times, freezing rates, and thawing methods to optimize cryopreservation protocols for large yellow croaker (Larimichthys crocea). The parameters evaluated were sperm motility, sperm activity index (SAI), survival rate, and DNA damage. Different types of CPAs, such as dimethyl sulfoxide (DMSO), propylene glycol (PG), ethylene glycol (EG), methanol, and glycerol, were tested for sperm preservation. The highest motility, SAI, and survival rate were observed when EG was used. Different diluents such as Stein's solution, Hank's balanced salt solution, marine fish Ringer's solution, artificial seminal plasma (ASP) of small yellow croaker, and Cortland solution were investigated. The highest post-thaw motility was observed upon using ASP as the diluent. Different concentrations of EG were then mixed with ASP to identify the optimal EG concentration. Experimental results showed that the motility (70.33 ± 1.20%), SAI (5), and survival rate (78.30 ± 0.42%) of post-thaw sperm were optimum when 10% EG and ASP were used as the CPA and diluent of cryopreservation, respectively. Post-thaw sperm motility was high at equilibration times below 150 s and at an optimum dilution ratio of 1:1 (sperm: CPA + diluent) and was not significantly different compared with fresh sperm motility. The freezing rate was found to be slow below -10℃/min. The thawing temperature of 45℃ was identified as ideal. The percentage of tail DNA in post-thaw sperm at 10% EG and ASP was also investigated and was found to have more significant DNA damage than that in fresh sperm but significantly lower damage than that in post-thaw sperm at EG concentrations of 5%, 15%, and 20% (p < 0.05). The cryopreservation protocols obtained in this study will be useful in large yellow croaker hatcheries.

Some Factors Influencing the Dissolution Rate of Lorazepam Formulations (Lorazepam제제(製劑)의 용출속도(溶出速度)에 미치는 인자(因子))

  • Lee, Chang-Ki;Song, In-Jung;Choi, Jung-Young;Suh, Sung-Won
    • Journal of Pharmaceutical Investigation
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    • v.11 no.2
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    • pp.16-19
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    • 1981
  • The effect of diluents and lubricants on the dissolution rate of lorazepam was studied. The results were as following. 1. An average order of dissolution rate can be stated as; lactose> avicel> starch> kaolin. 2. The effects of lubicants is not significant generally but in the case of starch the dissolution rate is greatly effected by magnesium stearate.

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Solvent Extraction of Platinum (IV) with 4-(4-Ethoxybenzylideneamino)-5-methyl-4H-1,2,4-triazole-3-thiol (EBIMTT) from Hydrochloric Acid Media

  • Shaikh, Uzma parveen K.;Dhokte, Aashish O.;Lande, Machhindra K.;Arbad, Balasaheb R.
    • Journal of the Korean Chemical Society
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    • v.56 no.1
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    • pp.58-61
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    • 2012
  • The solvent extraction of platinum (IV) metal from hydrochloric acid media using 4-(4-ethoxybenzylideneamino)-5-methyl-4H-1,2,4-triazole-3-thiol (EBIMTT) in chloroform was studied as a function of several variables, such as reagent, acid and metal ion concentration, effect of various diluents, and diverse ions. The proposed method was further applied for the separation of platinum (IV) from binary mixtures, synthetic mixtures, alloys and commercially available samples.

Studies on the Effect of Microfine Cellulose upon the Preparation of Prednisolone Tablets by Direct Compression Method (직타법(直打法)에 의(依)한 Prednisolone 정제(錠劑)의 제조(製造)에 있어서 Microfine Cellulose가 미치는 영향(影響)에 관(關)한 연구(硏究))

  • Ok, Su-Jung;Yong, Jae-Ick
    • Journal of Pharmaceutical Investigation
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    • v.5 no.3
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    • pp.58-65
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    • 1975
  • In the preparation of prednisolone tablets, when microfine cellulose$(Elcema^{\circledR})$ was used as diluents, stability and physical characteristics of prednisolone tablets are as follows; 1. Weight of the plain $Elcema^{\circledR}$ tablets increased by 75% of relative humidity and hardness was weakend, but the temperature $(60^{\circ}C)$ caused no change of thickness and decreased the weight and hardness. 2. In experimental tableting of prednisolone tablets, the addition of $Elcema^{\circledR}$ caused no difficulty in direct compression method, and the shortening of the disintegration time and increase of the hardness were satisfactory. 3. Dissolution rate test exhibited the result similiar to disintegration test. 4. In the comparison test of $Elcema^{\circledR}$ and $Avicel^{\circledR}$ as adjuvants the physical constants of prednisolone tablets showed nearly a similar tendency.

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Heterogeneous Ignition of $H_2/O_2/CO_2$ Mixture Over Platinum Catalyst (수소/산소/이산화탄소 혼합기의 백금촉매반응특성 : 비균일 반응의 점화 온도)

  • Nam, Chang-Ho;Shin, Hyun-Dong
    • 한국연소학회:학술대회논문집
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    • 2001.11a
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    • pp.90-96
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    • 2001
  • Catalytic ignition of $H_2/O_2/CO_2$ mixtures over platinum catalyst is experimentally investigated by using microcalorimetry. For comparison, $N_2$ and Ar is also used as diluent gas. The gas mixture flows toward platinum foil heated by electric current at atmosphere pressure and ambient temperature. The ignition temperature range 350-445K according to the fuel ratio, dilution ratio and diluent gas. It increases as the fuel ratio and dilution ratio increase. $H_2/O_2$ mixture with $CO_2$ ignites at higher temperature than with other diluents by 30-50K. Several experimental evidences show the inhibition effects of $CO_2$ in $H_2-O_2$ heterogeneous reaction is considerable

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Effect of H2/CO Ratio, Dilution Ratio, and Methane/Syngas Ratio on Combustion Characteristics of Syngas Turbine (H2/CO비, 희석량, 메탄/석탄가스비가 합성가스용 가스터빈의 연소특성에 미치는 영향)

  • Lee, Min Chul;Yoon, Youngbin
    • 한국연소학회:학술대회논문집
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    • 2012.11a
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    • pp.59-60
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    • 2012
  • This paper describes gas turbine combustion characteristics of synthetic gas which is mainly composed of hydrogen and carbon monoxide. The combustion characteristics such as combustion instability, NOx and CO emission, temperatures at turbine inlet, liner and dump plane, and flame structure were investigated when changing when changing $H_2:CO$ ratio, dilution ratio, and $CH_4:syngas$ ratio. From the results, quantitative relationships are derived between key aspects of combustion performance, notably NOx emission. It is concluded that NOx emission of syngas is strongly influenced by the diluent heat capacity and combustion instability. Moreover, NOx control method using diluents such as $N_2$, $CO_2$, steam is verified.

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Acoustic Studies on Different Binary Liquid Mixtures of LIX Reagents with Different Diluents

  • Kamila, Susmita
    • Journal of the Korean Chemical Society
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    • v.56 no.5
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    • pp.548-555
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    • 2012
  • Ultrasonic velocity and density measurements have been undertaken for a number of binary liquid mixtures involving different commercial solvent extractants, LIX reagents. The binary mixtures under investigation have been classified under two categories such as polar-polar, and polar-non-polar types. Different theories and relations such as Schaaff's Collision Factor Theory (CFT), Nomoto's relation (NOM), and Van Dael & Vangeel ideal mixing relation (IMR) have been used to evaluate the velocity theoretically for all these binary systems. The relative merits of afore-mentioned theories and relations compared to experimental values of velocity have been discussed in terms of percentage variations. However, the CFT and Nomoto's relation show better agreement with the experimental findings than the ideal mixing relation for all the systems under investigation.

Investigation on Flame Characteristics′ Variation by Flue Gas Recirculation and Fuel Injection Recirculation (산화제류 및 연료류 희석에 의한 화염특성변화에 대한 연구)

  • Han, Ji-Woong;Kum, Sung-Min;Lee, Chang-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1625-1631
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    • 2004
  • Investigation on Flue Gas Recirculation(FGR) flame and Fuel Injection Recirculation(FIR) flame was performed with numerical method. Quantitative Reaction Path Diagram(QRPD) is utilized to compare the different chemistry effects between FGR flame and FIR flame. In order to compare flamelets in various oxygen-enrichment conditions reasonably, the adiabatic flame temperature and Damkohler number were held fixed by modulating the amount of diluents to fuel and oxidizer stream and by varying global strain rate of flame respectively. Basic flame structures were compared and characteristics of CH$_4$ decomposition and NO formation were analyzed based on QRPD analysis between FGR flame and FIR flame.