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http://dx.doi.org/10.5012/jkcs.2012.56.1.058

Solvent Extraction of Platinum (IV) with 4-(4-Ethoxybenzylideneamino)-5-methyl-4H-1,2,4-triazole-3-thiol (EBIMTT) from Hydrochloric Acid Media  

Shaikh, Uzma parveen K. (Department of Chemistry, Dr.Babasaheb Ambedkar Marathwada University)
Dhokte, Aashish O. (Department of Chemistry, Dr.Babasaheb Ambedkar Marathwada University)
Lande, Machhindra K. (Department of Chemistry, Dr.Babasaheb Ambedkar Marathwada University)
Arbad, Balasaheb R. (Department of Chemistry, Dr.Babasaheb Ambedkar Marathwada University)
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Abstract
The solvent extraction of platinum (IV) metal from hydrochloric acid media using 4-(4-ethoxybenzylideneamino)-5-methyl-4H-1,2,4-triazole-3-thiol (EBIMTT) in chloroform was studied as a function of several variables, such as reagent, acid and metal ion concentration, effect of various diluents, and diverse ions. The proposed method was further applied for the separation of platinum (IV) from binary mixtures, synthetic mixtures, alloys and commercially available samples.
Keywords
Solvent extraction; Pt (IV); EBIMTT; Real samples;
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