• 제목/요약/키워드: Diffusion rate

검색결과 1,754건 처리시간 0.036초

초소성 성형/확산접합 공정의 유한요소 해석 (Finite Element Analysis of Superplastic Forming/Diffusion Bonding Processes)

  • 홍성석;김용환
    • 소성∙가공
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    • 제5권1호
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    • pp.37-46
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    • 1996
  • Superplastic forming/diffusion bonding (SPF/DB) processes were analyzed using a rigid visco-plastic finite element method. The optimum pressure-time relationship for a target strain rate and thickness distributions were predicted by two-node line elements based on the membrane approximation for plane strain. Material behavior during SPF/DB of the integral structures having complicated shapes was investigated. The tying condition is employed for the analysis of inter-sheet contact problems. A movement of rib structure is successfully predicted during the forming.

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A theoretical approach to the preferred orientation formation of MgO protection layer using adatom diffusion

  • Yu, Hak-Ki;Lee, Jong-Lam
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.713-715
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    • 2009
  • Preferred orientation of MgO protection layer is controlled via adjusting diffusion of adatom between (111) plane with highest neighbor atoms and (200) plane with lowest neighbor atoms. The diffusion of adatom could be modulated by the factors such as substrate temperature, deposition rate, and extra energy applied on adatom like ion beam energy.

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염분환경하 콘크리트 경화체의 내구성에 미치는 혼합재의 영향 (I) 시멘트 경화체중에서의 Cl-이온의 확산 (Effect of Blending Materials on the Durability of Concrete (I) Diffusion of Cl-ions through Hardened Cement Paste)

  • 김남중;최상흘;정재동;한기성
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1991년도 가을 학술발표회 논문집
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    • pp.11-14
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    • 1991
  • Apparent diffusion coefficients of Cl-ions through hardened cement paste(HCP), which were partly substituted blending materials, were determined. Also, pore solution was extracted from HCP which were immersed in NaCl solution, and Cl- concentration of the solution were analyzed. Partly substitution of pozzolanic materials considerably reduced the diffusion rate for Cl-ions and Cl- concentration of pore solution. Binding capacity of Cl- is related to the content of Al2O3 and pozzolanic reactivity.

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대향류 확산화염의 소염특성에 미치는 직류전기장의 영향에 관한 실험적 연구 (Experimental Study on the Effect of DC Electric Field on Extinction Characteristics of Counterflow Diffusion Flame)

  • 박익형;김민국;원상희;차민석;정석호
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제33회 KOSCO SYMPOSIUM 논문집
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    • pp.253-259
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    • 2006
  • The effect of DC electric fields on the flame extinction was investigated experimentally in counterflow configurations for the methane/oxygen/nitrogen diffusion flame. The electric fields was applied by connecting the high voltage and ground terminals to the upper and lower burners, respectively. In case of having electric fields, several modes of flame extinction was observed according to the electric field intensity and strain rate defined by the exit velocity. To visualize and characterize the flame structure and intensity, planar LIF technique was adopted for OH radicals. Consequently, several length scales, including the flame width, thickness, and height from the burner tip, were introduced to explain the various flame behaviors and to characterize the flame extinctions. It was found that the variation of flame width and the chemical reaction are strongly related to a critical electric field intensity, thus the various modes of diffusion flame extinction could be observed due to the electric fields.

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Inertial Dynamic Effect on the Rates of Diffusion-Controlled Ligand-Receptor Reactions

  • Lee, Woo-Jin;Kim, Ji-Hyun;Lee, Sang-Youb
    • Bulletin of the Korean Chemical Society
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    • 제32권spc8호
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    • pp.2973-2977
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    • 2011
  • It has been known that the inertial dynamics has a little effect on the reaction rate in solutions. In this work, however, we find that for diffusion-controlled reactions between a ligand and a receptor on the cell surface there is a noticeable inertial dynamic effect on the reaction rate. We estimate the magnitude of the inertial dynamic effect by comparing the approximate analytic results obtained with and without the inertial dynamic effect included. The magnitude of the inertial dynamic effect depends on the friction coefficient of the ligand as well as on the relative scale of the receptor size to the distance traveled by the ligand during its velocity relaxation time.

연소공기의 산소부화농도에 따른 난류확산 평면화염의 연소특성 (Combustion Characteristics of a Turbulent Diffusion Flat Flame According to Oxygen Enriched Concentration of Combustion Air)

  • 곽지현;전충환;장영준
    • 대한기계학회논문집B
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    • 제28권3호
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    • pp.281-288
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    • 2004
  • Combustion using oxygen enriched air is an energy saving technology that can increase thermal efficiency by improving the burning rate and by increasing the flame temperature. Flame figures, OH radical intensities, temperature distributions and emissions concentration were examined according to oxygen enriched concentration(OEC) in a turbulent diffusion flat flame. As long as the oxygen enriched concentration was increased, the length and volume of the flat flame was decreased while OH radical intensity was raised and the flame temperature was increased. However, RMS of the fluctuating temperature was decreased, and more homogeneous temperature field was formed. Thermal NO also was increased with increase of oxygen enriched concentration, but CO was decreased due to the increase of chemical reaction rate.

$CO_2$ 첨가가 $CH_4$-공기 대향류 확산화염의 구조 및 NOx 생성에 미치는 영향 (Effect of $CO_2$ Addition on Flame Structure and NOx Formation of $CH_4-Air$ Counterflow Diffusion Flames)

  • 이승로;한지웅;이창언
    • 한국연소학회지
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    • 제4권2호
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    • pp.97-108
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    • 1999
  • This numerical study was to investigate the effect of $CO_2$ addition on the structures and NOx formation characteristics in $CH_4$ counterflow diffusion flame. The importance of radiation effect was identified and $CO_2$ addition effect was investigated in terms of thermal and chemical reaction effect. Also the causes of NOx reduction were clarified by separation method of each formation mechanisms. The results were as follows : The radiation effect was intensified by $CO_2$ addition. Thermal effect mainly contributed to the changes in flame structure and the amount of NO formation but the chemical reaction effect also cannot be neglected. The reduction of thermal NO was dominant with respect to reduction rate, but that of prompt NO was dominant with respect to total amount.

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Diffusion-Controlled Reactions Involving a Reactant with Two Reaction Sites: Evaluation of the Utility of Wilemski-Fixman Closure Approximation

  • Uhm, Je-sik;Lee, Jin-uk;Eun, Chang-sun;Lee, Sang-youb
    • Bulletin of the Korean Chemical Society
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    • 제27권8호
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    • pp.1181-1185
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    • 2006
  • By using two different computer simulation methods, of which one produces exact results while the other is based on the Wilemski-Fixman closure approximation, we evaluate the utility of closure approximation in calculating the rates of diffusion-controlled reactions involving a reactant with multiple reaction sites. We find that errors in the estimates of steady-state rate constants due to closure approximation are not so large. We thus propose an approximate analytic expression for the rate constant based on the closure approximation.

FINITE ELEMENT MODEL TO STUDY TWO DIMENSIONAL UNSTEADY STATE CYTOSOLIC CALCIUM DIFFUSION

  • Tewari, Shivendra Gajraj;Pardasani, Kamal Raj
    • Journal of applied mathematics & informatics
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    • 제29권1_2호
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    • pp.427-442
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    • 2011
  • Calcium is a vital second messenger for signal transduction in neurons. Calcium plays an important role in almost every part of the human body but in neuronal cytosol, it is of utmost importance. In order to understand the calcium signaling mechanism in a better way a finite element model has been developed to study the flow of calcium in two dimensions with time. This model assumes EBA (Excess Buffering Approximation), incorporating all the important parameters like time, association rate, influx, buffer concentration, diffusion constant etc. Finite element method is used to obtain calcium concentration in two dimensions and numerical integration is used to compute effect of time over 2-D Calcium profile. Comparative study of calcium signaling in two dimensions with time is done with other important physiological parameters. A MATLAB program has been developed for the entire problem and simulated on an x64 machine to compute the numerical results.

희석된 수소/공기 확산화염의 비정상 음향파 응답특성 해석 (Unsteady Analysis of Acoustic-Pressure Responses of $N_{2}$ Diluted $H_{2}$ and Air Diffusion Flames)

  • 손채훈
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2003년도 추계학술대회
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    • pp.320-325
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    • 2003
  • Acoustic-Pressure Response of diluted hydrogen-air diffusion flames is investigated numerically by adopting a fully unsteady analysis of flame structures. In the low-pressure regime, the amplification index remains low and constant at low frequencies. As acoustic frequency increases, finite-rate chemistry is enhanced through a nonlinear accumulation of heat release rate, leading to a high amplification index. Finally, the flame responses decrease at high frequency due to the response lag of the transport zone. For a medium-pressure operation and low-frequency excitation, the amplification index is low and constant. It then decreases at moderate frequencies. As frequency increases further, the amplification index increases appreciably due to an intense accumulation effect.

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