• Title/Summary/Keyword: Diffusion Term

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International Joint Research for the Colloid Formation and Migration in Grimsel Test Site: Current Status and Perspectives

  • Sang-Ho Lee;Jin-Seok Kim;Bong-Ju Kim;Jae-Kwang Lee;Seung Yeop Lee;Jang-Soon Kwon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.20 no.4
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    • pp.455-468
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    • 2022
  • Colloid Formation and Migration (CFM) project is being carried out within the Grimsel Test Site (GTS) Phase Ⅵ. Since 2008, the Korea Atomic Energy Research Institute (KAERI) has joined CFM to investigate the behavior of colloid-facilitated radionuclide transport in a generic Underground Research Laboratory (URL). The CFM project includes a long-term in-situ test (LIT) and an in-rock bentonite erosion test (i-BET) to assess the in-situ colloid-facilitated radionuclide transport through the bentonite erosion in the natural flow field. In the LIT experiment, radionuclide-containing compacted bentonite was equipped with a triple-packer system and then positioned at the borehole in the shear zone. It was observed that colloid transport was limited owing to the low swelling pressure and low hydraulic conductivity. Therefore, a postmortem analysis is being conducted to estimate the partial migration and diffusion of radionuclides. The i-BET experiment, that focuses more on bentonite erosion, was newly designed to assess colloid formation in another flow field. The i-BET experiment started with the placement of compacted bentonite rings in the double-packer system, and the hydraulic parameters and bentonite erosion have been monitored since December 2018.

Numerical analysis of the venturi flowmeter in the liquid lead-bismuth eutectic circuit after long-term operation

  • Zhichao Zhang;Rafael Macian-Juan;Xiang Wang
    • Nuclear Engineering and Technology
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    • v.56 no.3
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    • pp.1081-1090
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    • 2024
  • The liquid Lead-bismuth eutectic is used as the coolant for Gen-IV reactor concepts. However, due to its strong corrosive and high operating temperature, it is difficult to accurately measure the flow rate in long-term operating conditions. Venturi flowmeter is a simple structured flowmeter, which plays a very important role in the flow measurement of high-temperature liquid metals, especially since the existing flowmeters are difficult to be competent. It has the advantages of easy maintenance and stable operation. Therefore, it is necessary to study the operating conditions of the venturi flowmeter under high-temperature conditions. This work performs a series of simulations of the fluid-solid interaction between the flow liquid metal and venturi flowmeter with COMSOL software, including the dimensional sensitivity analysis of the venturi flowmeter to explore the most suitable structure and parameters for liquid heavy metal, the sensitivity analysis of the geometric parameters of the venturi tube on the varying conditions. It shows that when the contraction angle of the venturi flowmeter is 33°, the diffusion angle is 13°, the diameter of the throat is 8 mm, and the temperature of the lead-bismuth eutectic is 733.15 K, it is most suitable for the measurement in the lead-bismuth circuit.

Development and validation of the lead-bismuth cooled reactor system code based on a fully implicit homogeneous flow model

  • Ge Li;Wang Jingxin;Fan Kun;Zhang Jie;Shan Jianqiang
    • Nuclear Engineering and Technology
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    • v.56 no.4
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    • pp.1213-1224
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    • 2024
  • The liquid lead-bismuth cooled fast reactor has been in a single-phase, low-pressure, and high-temperature state for a long time during operation. Considering the requirement of calculation efficiency for long-term transient accident calculation, based on a homogeneous hydrodynamic model, one-dimensional heat conduction model, coolant flow and heat transfer model, neutron kinetics model, coolant and material properties model, this study used the fully implicit difference scheme algorithm of the convection-diffusion term to solve the basic conservation equation, to develop the transient analysis program NUSOL-LMR 2.0 for the lead-bismuth fast reactor system. The steady-state and typical design basis accidents (including reactivity introduction, loss of flow caused by main pump idling, excessive cooling, and plant power outage accidents) for the ABR have been analyzed. The results are compared with the international system analysis software ATHENA. The results indicate that the developed program can stably, accurately, and efficiently predict the transient accident response and safety characteristics of the lead-bismuth fast reactor system.

Kinetics of Silica Sorption and Desorption in Soil as affected by pH and Temperature (pH 와 온도(溫度)에 따른 토양(土壤)의 규산(硅酸) 흡(吸) · 탈착(脫着)에 대(對)한 역학적(力學的) 연구(硏究))

  • Lee, Sang-Eun;Neue, Heins Ulitz
    • Korean Journal of Soil Science and Fertilizer
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    • v.25 no.4
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    • pp.342-356
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    • 1992
  • Kinetic studies using stirred-flow methods were conducted with the Luisiana soil at three pH levels(pH 5, 6.5, and 8) and three temperature levels(10, 25, and $40^{\circ}C$) to explore effects on the rate of silica retention and release and to find out reaction mechanisms. In this study the maximum silica retention could not be obtained for long enough experimental time. The silica sorption isorption was C type fitted well to Freundlich equation. The pH of the soil suspension increased by the silica release process at low pH treatments(pH 5 and 6.5), while decreased at high pH treatment(pH 8). From the above findings It can be deduced that the mechanism of silica retention is a multilayer forming process to change the ligand form depending on pH condition. In the proposed mechanism the sorbed silica provide new binding sites for additional sorption of silica, while the activation energy for the formation of subsequent layers increases correspondingly. The silica retention and release process were well described by first-order and parabolic diffusion equation. However, clear interpretation for silica sorption mechanism using these equations could not be made. The validity of the fraction term (Fa and Fd) included in first-order and parabolic diffusion equation requires further examinations because the temperature effect on apparent rate constant shows no constant trends among temperature treatments, while there was a good trend in Elovich and modified Freundlich equation where the fraction term was not included.

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Forecasting a Gyeongju's Local Society Change Using Urban Dynamics Model (도시동태모델을 이용한 경주 지역사회변화 예측)

  • Lee, Young-Chan
    • Korean Management Science Review
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    • v.25 no.3
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    • pp.27-43
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    • 2008
  • This study analyzes the changes of Gyeongju local society because of setting up low and intermediate level radioactive waste disposal site by using urban dynamics model. Specifically, after examining 'Gyeongju Long-Term Development Plan' announced in 2007, I establish the number of industries, population, gross local product, residents' income, and the long term employment condition as essential change-causing factors in Gyeongju local society based on the Big3 government project, and forecast it by using 'Gyeongju long-Term Development Plan' and all sorts of statistical data. In this stage, I assume 3 scenarios(basic, optimistic, and pessimistic view) to estimate the changes of local society more exquisitely, and scenarios are composed through mediation about variables of a growth rate and an inflow or outflow rate. The result shows that Gyeonaju local society would have growing changes by 2020. The essential change-causing factors are as follows. The case of population is estimated that it starts going down at the level of approximately 270 thousand by 2009, starts going up continuously after 2009, the year of completion of low and intermediate level radioactive waste disposal site, and increases from the level of about 300 thousand as minimum to 340 thousand as maximum in 2020. The estimates of other cases are made that the number of Industries has about 10 thousand increases, gross local product has almost 6 trillion increases, nominal gross national income doubles, as well as residences have approximately 280 thousand increases, and also made that employment condition also improves continuously, and diffusion ratio of house starts going up but the amount of supplies is a little bit insufficient in the long view.

Long-term Stability of Perovskite Solar Cells with Inhibiting Mass Transport with Buffer Layers (물질이동 억제 버퍼층 형성을 통한 페로브스카이트 태양전지 장기 안정성 확보)

  • Bae, Mi-Seon;Jeong, Min Ji;Chang, Hyo Sik;Yang, Tae-Youl
    • Journal of the Microelectronics and Packaging Society
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    • v.28 no.3
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    • pp.17-24
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    • 2021
  • Perovskite solar cells (PSCs) can be fabricated through solution process economically with variable bandgap that is controlled by composition of precursor solution. Tandem cells in which PSCs combined with silicon solar cells have potential to reach high power conversion efficiency over 30%, however, lack of long-term stability of PSCs is an obstacle to commercialization. Degradation of PSCs is mainly attributed to the mass transport of halide and metal electrode materials. In order to ensure the long-term stability, the mass transport should be inhibited. In this study, we confirmed degradation behaviors due to the mass transport in PSCs and designed buffer layers with LiF and/or SnO2 to improve the long-term stability by suppressing the mass transport. Under high-temperature storage test at 85℃, PSCs without the buffer layers were degraded by forming PbI2, AgI, and the delta phase of the perovskite material, while PSCs with the buffer layers showed improved stability with keeping the original phase of the perovskite. When the LiF buffer and encapsulation were applied to PSCs, superior long-term stability on 85℃-85% RH dump heat test was achieved; efficiency drop was not observed after 200 h. It was also confirmed that 90.6% of the initial efficiency was maintained after 200 hours of maximum power tracking test under AM 1.5G-1SUN illumination. Here, we have demonstrated that the buffer layer is essential to achieve long-term stability of PSCs.

The Relationships among Perceived Value, Use-Diffusion, Loyalty of Mobile Instant Messaging Service (모바일 메신저 서비스의 지각된 가치, 사용-확산 그리고 충성도 간의 관계에 대한 연구)

  • Jo, Dong-Hyuk;Park, Jong-Woo;Chun, Hyun-Jae
    • Journal of Intelligence and Information Systems
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    • v.17 no.4
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    • pp.193-212
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    • 2011
  • Mobile instant messaging service is surfacing to an important keyword in the mobile market together with popularization of Smart phones. Mobile instant messaging service in Korea has become popular to the degree of 87.9% usages from total Smartphone holders, and it is expected that using populations will be more enlarged afterwards if considering a fact that its populations of Smartphone is continuously being increased after exceeding 10 million persons (Trend Monitor, June 2011). In the instant messaging market where competitions have been deepened day by day, raising customer's royalties will be the key for company's business survivals and goals of corporate marketing strategies. It could be said that understanding on which factors affect to customer retentions and royalties is very important. Specially, as changing status is being progressed very quickly in case of innovative mobile services like the instant messaging service, research necessities on how many do consumers use the services after accepting them, how much do consumers use them variously, and whether does it connect to long-term relations have been increased, but studies on such matters are in insufficient situations actually. Therefore, this study examined on which effects were affected to use-diffusion and loyalty factors from perceived customer vales' factors having been occurred after accepting the mobile instant messaging service, namely 'functional value', 'monetary value', 'emotional value', and 'social value'. Also, the study looked into what kind of roles do the service usage and using variety play to service's continued using intents as a loyalty index, recommending intents to others, and brand switching intents. And then the study laid the main purpose in trying to provide implications for enhancing customer securities and royalties on the mobile instant messaging service through research's results. The research hypotheses are as follows; H1: Perceived values will affect influences to royalties. H2: Use-Diffusion will affect influences to loyalty. H3: Perceived value will affect influences to loyalty. H4: The use-diffusion will play intermediating roles between perceived values and loyalty. Total 276 cases among collected 284 ones were used for the statistical analysis by SPSS ver. 15 package. Reliability, Factor analysis, regression were done. As the result of research, 'monetary value' and 'emotional value' affected to 'usage' among perceived value factors, and 'emotional value' was appeared as affecting the largest influence. Besides, the usage affected to constant-using intents and recommending intents to others, and using varieties were displayed as affecting to recommending intents to others. On the other hand, 'Using' and 'Using diversity' were appeared as not affecting to 'brand switching intentions'. Meanwhile, as the result of recognizing about effects of perceived values on the loyalty, it was appeared such like 'continued using intents' affected to'functional value', 'monetary value', and 'social value' first, and also 'monetary value', 'emotional value', and 'social value' affected to 'recommending intents to others'. On the other hand, it was shown such like only 'social value' affected influences to 'brand switching intents', and thus contrary results with the factor 'constant-using intents' were displayed. So, it seems that there are many applications to service provides who are worrying about marketing strategies for making consumer retains (constant-using) and new consumer's inductions (brand-switching intents). Finally, as a result of looking into intermediating roles of the use-diffusion factor in relations between conceived values and royalties at hypothesis 4, 'using' and 'using diversity' were displayed as affecting significant influences all together. Regarding to research result's implications, for expanding and promoting continued uses of the mobile instant messaging service by service providers: First, encouraging recognitions on the perceived value connected to users' service usage are necessary. Second, setting up user's use-diffusion strategies are required so as to enhance the loyalty after understanding a fact that use-diffusion patterns affecting to the service's loyalty are different. Finally, methods of raising customer loyalties and making constant relationships have to be grouped by analyzing on what are the customer value's factors that can satisfy users in competitive alterations.

Evaluation of Fine Dust Diffusion and Contamination Degree : Focused on the Operation Status of Donghae Port (항만 인근 미세먼지 노출 영향권 및 오염도 분석 :동해항 운영현황을 중심으로)

  • Hwang, Je-Ho;Kim, Si-Hyun;Kang, Dal-Won
    • Journal of Navigation and Port Research
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    • v.46 no.3
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    • pp.251-258
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    • 2022
  • Donghae Port is adjacently located to a residential area wherein 26,933 generations are creating a living environment. The areas comprise Song-jeong village (5,754 generations) and Bukp-yeong village (21,179 generations). Major cargoes handled in Donghae Port are dusty limestone, cement, anthracite, and bituminous coal, etc. In the process of handling such cargoes, air pollutants including oxide dust and fine dust which adversely impact the living conditions and health of residents are generated, causing air pollution in the vicinity of the port. Currently, Donghae Port is making an effort to improve the operation environment of the infrastructure and equipment in stages, for the purpose of reducing air pollutant emissions caused by the port industries in a long-term perspective. In this study, the sphere of influence of fine dust exposure and the degree of air pollution in the surrounding area were analyzed such as the state of fine dust concentration and diffusion in the vicinity of Donghae Port, fine dust diffusion pattern and spatial distribution of high-concentration considering wind direction and speed characteristics during the day and seasonal cycles. A more effective plan to reduce the concentration of fine dust in nearby areas by combining reduction plan, is being developed in terms of improvement regarding port infrastructure and equipment, and reduction measures considering the characteristics of the atmosphere environment according to the daytime, nighttime and season.

Evaluation on Long-term Mechanical Performance and Durability of Recycled Coarse Aggregate Concrete Produced by Two-stage Mixing Approach (2단계 배합방법으로 제조된 순환굵은골재 콘크리트의 장기재령 역학적 성능 및 내구성 평가)

  • Seong-Uk, Heo;Jeong Jin, Son;Chul-Woo, Chung;Young Chan, Kim
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.10 no.4
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    • pp.475-481
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    • 2022
  • Recycled aggregates show high water absorption rate compared to natural aggregates due to microcrack developed during production process and adhered cement pastes at the surface of recycled aggregates. This leads to the deterioration of mechanical properties and slow work flow. Currently it is getting hard to satisfy high demand for natural aggregates. Utilizing recycled aggregate more widely may be a substitutable countermeasure for the shortage of natural resources. In this study, two-stage mixing approach(TSMA) suggested by Tam et al. is used to produce recycled aggregate concrete(RAC) with 100 % replacement of coarse natural aggregate and tests for compressive strength, elastic modulus, and chloride ion diffusion coefficient are conducted to find out the effect of TSMA compared to normal mixing method. According to experimental result compressive strength and elastic modulus of RAC with TSMA was superior to those of RAC with normal mixing irrespective of water-cement ratio, and in some cases mechanical properties of RAC with TSMA approached to those of natural aggregate concrete(NAC). However, chloride ion diffusion coefficient of RAC was higher than that of NAC. This illustrates that TSMA is not an appropriate method in reducing chloride ion diffusion coefficient, resulting in inconsequential contribution of TSMA to the durability of RAC.

A Study on the Initial Behavior of Dredged Material Disposal in the Coastal Water (연안수역에서 투기준설토의 초기거동에 관한 연구)

    • Journal of Korean Port Research
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    • v.9 no.1
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    • pp.45-56
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    • 1995
  • Investigation of the physical behavior of dredged material disposal in coastal water includes estimations of water column concentration in the receiving water, exposure time, the initial deposition pattern as well as thickness of material at the dumping fields near the estuary area. Calculation based on vertical setting and horizontal advection of single particles ignore the effects of bulk properties of the disposed material, vertical and horizontal diffusion, and material dilution due to the entrainment of ambient water during descent. This paper focuses on the spatial and temporal changes in the dumping fields for the water column and bottom at a hypothetically confined coastal water, where the ambient time-invariant velocity and density profiles are applied, within the initial time period following the instantaneous release of the dredged material. This model accounts the behavior of material after release divided into three phases: convective descent, dynamic collapse and long-term passive dispersion

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