• Title/Summary/Keyword: Diffusion Ratio

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Experimental Study on CO2 Diffusivity in Cementitious Materials

  • Jung, Sang-Hwa;Lee, Myung-Kue;Kim, Jee-Sang
    • Corrosion Science and Technology
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    • v.4 no.2
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    • pp.69-74
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    • 2005
  • The carbonation of concrete is one of the major factors that cause durability problems in concrete structures. The rate of carbonation depends largely upon the diffusivity of carbon dioxide in concrete. The purpose of this study is to identify the diffusion coefficients of carbon dioxide for various concrete mixtures. To this end, several series of tests have been planned and conducted. The test results indicate that the diffusion coefficient increases with the increase of water-cement ratio. The diffusion coefficient decreases with the increase of relative humidity at the same water-cement ratio. The diffusion of carbon dioxide reached the steady state within about five hours after exposure. The content of aggregates also influences the diffusivity of carbon dioxide in concrete. It was found that the diffusion coefficient of cement paste is larger then that of concrete or mortar. The quantitative values of diffusivity of carbon dioxide in this study will allow more realistic assessment of carbonation depth in concrete structures.

Diffusion of Chloride Ions in Limestone Powder Concrete

  • Moon Han-Young;Jung Ho-Seop;Kim Jong-Pil
    • Journal of the Korea Concrete Institute
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    • v.16 no.6 s.84
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    • pp.859-865
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    • 2004
  • In this study, the diffusion of chloride ions in cement concrete made with and without the limestone powder was investigated. In order to study the effect of the limestone powder, all mixtures were prepared at a fixed water-cementitious ratio (0.45). From the experimental results, the setting time of limestone powder concrete is faster than that of control concrete, and compressive strength of all specimens decreased with increasing replacement ratio of limestone powders. The diffusion properties of limestone powder concretes indicated a trend increasing with curing period. LSA10 and LSA20 concretes, the diffusion coefficient was smaller than that of control concrete. The addition of $10-20\%$ limestone powder reduces the diffusion coefficient of chloride ions, irrespective of fineness levels of limestone powder.

Comparison Study on Electric Acceleration Test Method for Estimation of Chloride Diffusion Coefficient (염화물 확산 평가를 위한 전기적 실험법의 비교 연구)

  • Choi, Yoon-Suk;Choi, Sung-Ha;Kim, Myung-Yu;Yang, Eun-Ik;Yi, Seong-Tae
    • Proceedings of the Korea Concrete Institute Conference
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    • 2005.05b
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    • pp.257-260
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    • 2005
  • A general electric acceleration testing method for estimation of chloride diffusion coefficient is RCPT and CTH. Also, this testing methods have merit that reduce the testing time. In this paper, an experimental study is executed to investigate the effect of testing method on coefficient of chloride diffusion and it is compared with RCPT and CTH. According to this experiment results, W/C ratio and testing method influence chloride diffusion coefficient of concrete. As W/C ratio is increased, diffusion coefficient in concrete is also increased. Diffusion coefficient obtained by each testing method show the different values. However, there is no remarkable difference between the two testing method.

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A Study on Chloride Diffusion in Concrete Containing Lightweight Aggregate Using Crushed Stone-powder (폐석분을 활용한 경량골재 콘크리트의 염화물 확산에 관한 연구)

  • Lee, Dae-Hyuk;Yoon, Sang-Chen;Jeong, Yong;Shin, Jae-Kyung;Jee, Nam-Yong
    • Journal of the Korea Concrete Institute
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    • v.22 no.2
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    • pp.255-262
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    • 2010
  • The purpose of this study is to provide preliminary data on chloride diffusion of lightweight aggregate concrete containing crushed stone-powder. Accordingly, the study performed experiments using concrete aggregates of Crushed Aggregate (CG), Single-sized Lightweight Aggregate (SLG), Continuous Graded Lightweight Aggregate (CLG), and using water-binder ratio of 0.4, 0.5, 0.6, and using binder of FA and BFS. The chloride diffusion coefficient is calculated according to the NT BUILD 492. Diffusion coefficient of SLG and CLG were higher than that of CG concrete, but the difference was not significant. Also, chloride diffusion coefficient data indicated that it was highly affected by water-binder ratio, and it decreased with the decrease in waterbinder ratio. The admixture substitution of FA15% was effective in decreasing the diffusion coefficient only with water-binder ratio of 0.4 while admixture substitution of FA10+BFS20% was effective with all levels of water-binder ratio. The result of study shows lightweight aggregate concrete containing crushed stone-powder has slightly higher chloride diffusion coefficient than CG concrete, but the difference is not significant such that it can be overcome by adjusting water-binder ratio and admixture substitution. In addition, the data indicate the chloride diffusion coefficient of lightweight aggregate concrete can be estimated from the strength of lightweight aggregate.

The effect of diffusers on the measurement of sound absorption in a reverberation room (잔향실법 흡음률 측정에 미치는 확산체의 영향)

  • Han, Hee-Kab;Kim, Kyung-Ho
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.05a
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    • pp.1194-1197
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    • 2006
  • Recently, international standard for measurement of sound absorption in a reverberation room has been amended. In the revised version, temperature, humidity and air pressure conditions are strictly restricted and also the concrete procedures are presented to reduce the differences in test results by adding inspection of diffusion, measurement uncertainty etc. In this paper, the systematic tests are conducted based on the inspection guide of diffusion defined by ISO 354 and the effects of diffusers on the measurement of sound absorption ratio are considered. As a result, we perceived that the averaged sound absorption ratio in mid and high frequency range is expected to measure around $0.05{\sim}0.1$ higher in high sound absorption material. Therefore, as for the reverberation room for measurement of sound absorption, we need to take into consideration not only the spatial standard deviation of sound pressure mandated by ISO 3741, but also, inspection regulation of diffusion showed by ISO 354.

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Influence of Water-Cement Ratios and Curing Conditions on the Diffusion Characteristics of Chloride Ion in Concrete (콘크리트의 염소이온 확산특성에 미치는 물-시멘트비 및 양생조건의 영향)

  • Bae, Su-Ho;Lee, Kwang-Myong;Kim, Jee-Sang;Jung, Sang-Hwa
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4A
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    • pp.753-759
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    • 2006
  • To predict service life of concrete structures exposed to chloride attack, surface chloride concentration, diffusion coefficient of chloride ion, and chloride corrosion threshold value in concrete, are used as important factors. Of these, as the diffusion coefficient of chloride ion for concrete is strongly influenced by concrete quality and environmental conditions of structures and may significantly change the service life of structures, it is considered as the most important factor for service life prediction. The qualitative factors affecting the penetration and diffusion of chloride ion into concrete are water-cement (W/C) ratio, age, curing conditions, chloride ion concentration of given environment, wet and dry conditions, etc. In this paper the influence of W/C ratio and curing conditions on the diffusion characteristics of chloride ion in concrete was investigated through the chloride ion diffusion test. In the test, the voltages passing through the diffusion cell were measured by accelerated test method using potential difference, and then with the consideration of IR drop ratio the diffusion coefficient of chloride ion for concrete with different W/C ratios were estimated by Andrade's model. Furthermore, under different curing conditions formulas for the estimation of the diffusion coefficient of chloride ion have been proposed by the regression analysis considering the effect of W/C ratio and age.

A Study on the Dry Shrinkage and Moisture Diffusion Coefficient of Polymer-Modified Mortars by the Moisture Diffusion (수분확산에 의한 폴리머 시멘트 모르터의 건조수축과 확산계수에 관한 연구)

  • 조영국;소양섭
    • Magazine of the Korea Concrete Institute
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    • v.8 no.5
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    • pp.145-154
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    • 1996
  • Polymer-modified mortars have an excellent water proofness and water retentivity. Therefore, the study on the moisture diffusion behavior- is very important. The purpose of' this study is to investigate the effects of relative humidity and moisture content in mortars on the moisture diffusion, and the relationship between the shrinkage and moisture diffusion coefficient of polymer-modified mortars cured at $20{\circ}C$ 50% R.H and 80% R.H. The pore size distribution of the polymer-modified mortars was also measured. From the test results, the relative humidity and moisture content in mortars influenced on the moisture diffusion of polymer-modified mortars. The shrinkage and moisture diffusion coefficient of polymer-modified mortars cured at $20{\circ}C$ 50% R.H. was bigger than that cured at $20{\circ}C$ 80% R.H.. and decreased with increasing polymer-cement ratio regardless of polymer type.

Analysis of Correlation between Compressive Strength, Void Ratio and Chloride Diffusion Coefficient of Concrete Using Various Kinds of Cement (시멘트의 종류별 콘크리트외 강도 및 공극률과 염화물 확산계수의 상관관계 분석)

  • Yoon Eui-Sik;Lee Taek-Woo;Park Seung-Bum
    • Journal of the Korea Concrete Institute
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    • v.17 no.5 s.89
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    • pp.735-742
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    • 2005
  • The purpose of this study was to evaluate the salt water resistance of concrete depending on various types of cement. In this regard, 5 types of concrete were selected and their strength, void ratio and chloride ion diffusion characteristics were tested, and mutual correlation were analyzed. From the test results, the compressive strength and void ratio of concrete which using Type V cement was as good as Type I cement at long-term ages but the chloride diffusion coefficient of Type V cement was larger than Type I cement. And the concrete replacing some portion of the Type I cement with fly ash was superior in the cases of compressive strength, void ratio and the resistance of chloride ion permeation compared to the Type I cement with the lapse of ages. On the other hand, the compressive strength, the void ratio and the chloride diffusion coefficient of the concrete all indicated high levels of the correlation coefficient and the coefficient of determination regardless of the type of cement.

An experimental study on Influence of Permeability on corrosion of reinforced Concrete (철근콘크리트의 부식에 영향을 미치는 물질 투과성능에 관한 실험적 연구)

  • 김용로;김영덕;조봉석;장종호;권영진;김무한
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.11a
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    • pp.62-65
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    • 2003
  • In this study, to confirm corrosion of reinforced concrete affected by carbonation, chloride ion diffusion, absorption ratio, air permeability, measured carbonation velocity coefficient, chloride ion diffusion coefficient, absorption coefficient, air permeability coefficient. Corrosion velocity under environment of complex deterioration. And than compared corrosion velocity with these coefficients. As the results of this study, the correlation coefficient between chloride ion diffusion coefficients and absorption coefficient was revealed that it is very high. As well, an increase in carbonation, chloride ion diffusion also increases corrosion velocity. It showed that corrosion velocity was affected by the carbonation, chloride ion diffusion, absorption ratio, air permeability. Generally, data on the development of these coefficient made with none, organic B, organic A, inorganic B, and inorganic A is shown. It showed that coating of surface prevent steel bar from deteriorating.

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The Effects of Heat Diffusion Fin on the Thermal Behavior and Performance of Radiant Heatomg Panel (방열핀이 난방용 패널의 열적거동 및 성능에 미치는 영향)

  • 이태원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.18 no.9
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    • pp.2486-2493
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    • 1994
  • Transient heat transfer characteristics in th radiant heating panel with heat diffusion fin were predicted by numerical analysis. Thermal behaviors of panel, such as temperature distributions in panel and convective and radiative heat fluxes in panel surface with advance of time, were obtained for several important parameters. The performance and thermal comfort of heating panel were studied and compared for various design conditions, such as pipe pitch, area ratio and thermal conductivity of optimal design of the new heating panels with heat diffusion fin. It was concluded that the efficient area ratio of heat diffusion fin is about 0.5, and the greater the thermal conductivity of fin is, the better the performance of panel is.