• 미생물학회지
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• 제28권3호
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• pp.278-282
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• 1990

Diffusion and partition of progesterone into the polyacrylamide gel was examined. Diffusion coefficient of progesterone decreased down to an asymptotic value as the concentration of the organic solvents in the diffusing medium increased. However the partition coefficient diminished steadily. Crosslinking density in the gel didn't affected the diffusion coefficient considerably but lowered the partition coefficient due to the contraction of pore volume of the gel. Progesterone showed higher diffusion coefficient as well as partition coefficient in the polyurethane than in the polyacrylamide gel, which seems to be ascribed to the difference in hydrophobicity, pore volume and pore size of the polymer matrix.

• 한국농공학회논문집
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• 제50권4호
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• pp.27-37
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• 2008

It is most serious problem which is various occurs from the agricultural concrete structure and off shore concrete structure the problem which it comes to think is deterioration of the concrete which is caused with the corrosion of the reinforcing steel which is caused by with permeation of the water and the sea water. Specially the off shore concrete structure has been deteriorated by the steel reinforcement corrosion. The latex modified concrete(LMC) was adds latex in the plain concrete as the latex has increase the durability of concrete. This study were accomplished to the estimate the diffusion coefficient of LMC, and the time dependent constants of diffusion. The average chloride diffusion coefficient was estimated. Also, the average chloride diffusion coefficient was compared with diffusion coefficient test results of 28 curing days. The test results indicated that the average chloride diffusion coefficient could closely estimate the test results of the diffusion coefficient test results of 28 curing days.

• 한국토양환경학회지
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• 제1권2호
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• pp.83-90
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• 1996

토양내에서의 가스나 증기상의 오염물질의 이동은 여러 가지 현상에 의해서 일어나고 있으나 농도차에 의해서 일어나는 확산이 가장 중요하다. 그런데 토양내에서의 확산은 토양 입자들로 인한 확산 부피의 감소, 또 확산경로의 불규칙성, 확산 경로에 있어서 단면적의 변화 등으로 인해 대기중에서 일어나는 확산과는 다른 면을 보인다. 본 논문에서는 이러한 현상을 설명하기 위하여 흔히 사용되는 굴절계수(toruosity), 유효확산계수(effective diffusion coefficient)의 서로 다른 그러나 같은 이름으로 사용되는 많은 정의들과 다양한 수학적 모델들에 대한 비교 검토가 이루어졌다. 굴절계수나 유효확산계수를 사용할 때는 각각의 경우 정의와 각 식의 특징에 대하여 세밀한 검토와 주의가 행하여져야 한다.

• Bulletin of the Korean Chemical Society
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• 제32권3호
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• pp.852-856
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• 2011

The lithium ion diffusion coefficients of bare, carbon-coated and Cr-doped $LiFePO_4$ were obtained by fitting the discharge curves of each half cell with Li metal anode. Diffusion losses at discharge curves were acquired with experiment data and fitted to equations. Theoretically fitted equations showed good agreement with experimental results. Moreover, theoretical equations are able to predict lithium diffusion coefficient and discharge curves at various discharge rates. The obtained diffusion coefficients were similar to the true diffusion coefficient of phase transformation electrodes. Lithium ion diffusion is one of main factors that determine voltage drop in a half cell with $LiFePO_4$ cathode and Li metal anode. The high diffusion coefficient of carbon-coated and Cr-doped $LiFePO_4$ resulted in better performance at the discharge process. The performance at high discharge rate was improved much as diffusion coefficient increased.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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• pp.677-682
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• 2001

In this study, a method to evaluate diffusion coefficient of chloride ion in cracked concrete is proposed. For cracked concrete having either anisotropic or isotropic crack network, each crack of saturated concrete is considered as a V shape crack, and an effective diffusion coefficient is expressed with diffusion coefficients of cracked part and noncracked part and a so-called crack spacing factor. A comparison with experimental results shows that the diffusion coefficient for cracked concrete is accurately predicted by the effective diffusion coefficient. Prediction results also show that the cracks in concrete markedly change the diffusion properties and accelerate penetration of drifting species. The method in this paper can be effectively used to consider the effect of cracks on concrete diffusion coefficient of cracked concrete.

• 콘크리트학회논문집
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• 제24권6호
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• pp.715-726
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• 2012

콘크리트의 대표적 물성치인 강도 및 염화물 확산계수는 재령에 따라 변화하며, 염화물 침투 해석시 이러한 영향들이 고려되고 있다. 이 연구는 다양한 혼화재료 (고로슬래그 미분말, 플라이애쉬, 실리카 퓸)을 포함하는 고성능콘크리트의 촉진염화물 확산계수, 겉보기 염화물 확산계수, 강도 특성을 재령에 따라 실험적으로 도출하고 그 상관성을 분석하는데 목적이 있다. 이를 위해 30개의 배합을 가지는 고성능 콘크리트가 제작되었고, 재령 28일, 91일, 180일, 270일에 대한 촉진확산계수를 실험적으로 도출하였으며, 또한 동일배합에 대하여 침지 6개월 이후의 겉보기 확산계수가 도출되었다. 재령에 대한 강도 특성을 평가하기 위해, 재령 7일, 28일, 91일, 180일에 대한 강도시험이 수행되었다. 시간 의존적인 촉진확산계수의 변화가 겉보기 확산계수 및 강도와 비교되었으며, 각각의 상관관계가 재령에 대하여 분석되었다. 이 연구를 통하여 겉보기 확산계수와 촉진확산계수는 재령에 큰 영향을 받지 않으면서 선형적인 상관성이 도출되었다. 또한 강도와 촉진확산계수 그리고 강도와 겉보기 확산계수에서도 재령에 큰 영향을 받지 않는 선형적인 관계가 도출되었다.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 봄 학술발표회 논문집
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• pp.705-710
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• 2003

In this study, to confirm the diffusion coefficient of chloride ion is affected by the concentration of NaCl solution, capacity of voltage, time of an electric current, the diffusion coefficient of chloride ion in concrete was investigated through an electrochemical accelerated test. and the results of these test were compared with the diffusion coefficient of chloride ion by test of sodium chloride solution digestion. As the results of this study, the diffusion coefficient of chloride ion wasn't affected by the concentration of NaCl solution, capacity of voltage, time of an electric current within the range of this study and was similar to the diffusion coefficient of chloride ion by test of sodium chloride solution digestion.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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• pp.257-260
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• 2005

A general electric acceleration testing method for estimation of chloride diffusion coefficient is RCPT and CTH. Also, this testing methods have merit that reduce the testing time. In this paper, an experimental study is executed to investigate the effect of testing method on coefficient of chloride diffusion and it is compared with RCPT and CTH. According to this experiment results, W/C ratio and testing method influence chloride diffusion coefficient of concrete. As W/C ratio is increased, diffusion coefficient in concrete is also increased. Diffusion coefficient obtained by each testing method show the different values. However, there is no remarkable difference between the two testing method.

• Nuclear Engineering and Technology
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• 제49권5호
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• pp.1019-1030
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• 2017

Diffusion is a crucial mechanism that regulates the migration of radioactive nuclides. In this study, an innovative numerical method was developed to simultaneously calculate the diffusion coefficient of both parent and, afterward, series daughter nuclides in a sequentially reactive through-diffusion model. Two constructed scenarios, a serial reaction (RN_1 ${\rightarrow}$ RN_2 ${\rightarrow}$ RN_3) and a parallel reaction (RN_1 ${\rightarrow}$ RN_2A + RN_2B), were proposed and calculated for verification. First, the accuracy of the proposed three-member reaction equations was validated using several default numerical experiments. Second, by applying the validated numerical experimental concentration variation data, the as-determined diffusion coefficient of the product nuclide was observed to be identical to the default data. The results demonstrate the validity of the proposed method. The significance of the proposed numerical method will be particularly powerful in determining the diffusion coefficients of systems with extremely thin specimens, long periods of diffusion time, and parent nuclides with fast decay constants.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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• pp.62-65
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• 2003

In this study, to confirm corrosion of reinforced concrete affected by carbonation, chloride ion diffusion, absorption ratio, air permeability, measured carbonation velocity coefficient, chloride ion diffusion coefficient, absorption coefficient, air permeability coefficient. Corrosion velocity under environment of complex deterioration. And than compared corrosion velocity with these coefficients. As the results of this study, the correlation coefficient between chloride ion diffusion coefficients and absorption coefficient was revealed that it is very high. As well, an increase in carbonation, chloride ion diffusion also increases corrosion velocity. It showed that corrosion velocity was affected by the carbonation, chloride ion diffusion, absorption ratio, air permeability. Generally, data on the development of these coefficient made with none, organic B, organic A, inorganic B, and inorganic A is shown. It showed that coating of surface prevent steel bar from deteriorating.